Version2.2 2021-02-07T03:36:47Z 10.1021/jm300687e Gaussian16 RevisionB.01 PWARBURT 01-Jan-2021 #N HF/6-31G(d) OPT=(MaxStep=1) FREQ IOp(6/10=2,6/11=2,6/12=2) DUDE C[C@@H](C(=O)NCCC1=c2ccccc2=[NH+]C1)NC(=O)[C@H]3Cc4c(ccc(c4OC)OC)N3 C63328937 RHF 6-31G(d) (6D,7F) C[C@@H](C(=O)NCCC1=c2ccccc2=[NH+]C1)NC(=O)[C@H]3Cc4c(ccc(c4OC)OC)N3 C01[X(C24H29N4O4)] 177 C1 538 COc1c(OC)ccc2c1C[C@@H](N2)C(=O)N[C@H](C(=O)NCCC1=c2ccccc2=[NH+]C1)C COc1c(OC)ccc2c1C[C@@H](N2)C(=O)N[C@H](C(=O)NCCC1=c2ccccc2=[NH+]C1)C COc1ccc2N[C@H](Cc2c1OC)C(=O)N[C@@H](C)C(=O)NCCC3=C4C=CC=CC4=[NH+]C3 InChIKey=MOBYVNYAQTWXHT-VBKZILBWSA-O InChI=1S/C24H28N4O4/c1-14(23(29)25-11-10-15-13-26-18-7-5-4-6-16(15)18)27-24(30)20-12-17-19(28-20)8-9-21(31-2)22(17)32-3/h4-9,14,20,28H,10-13H2,1-3H3,(H,25,29)(H,27,30)/p+1/t14-,20+/m0/s1 InChI=1/C24H28N4O4/c1-14(23(29)25-11-10-15-13-26-18-7-5-4-6-16(15)18)27-24(30)20-12-17-19(28-20)8-9-21(31-2)22(17)32-3/h4-9,14,20,28H,10-13H2,1-3H3,(H,25,29)(H,27,30)/p+1/t14-,20+/m0/s1/fC24H29N4O4/h25-27H/q+1 C[C@@H](C(=O)NCCC1=c2ccccc2=[NH+]C1)NC(=O)[C@H]3Cc4c(ccc(c4OC)OC)N3 C01[X(C24H29N4O4)] 177 C01 538 COc1c(OC)ccc2c1C[C@@H](N2)C(=O)N[C@H](C(=O)NCCC1=c2ccccc2=[NH+]C1)C CO[C]1[C]([CH][CH][C]2[C]1C[C@@H](N2)C(=O)N[C@H](C(=O)NCCC1=[C]2[CH]=[CH][CH]=[CH][C]2[NH]C1)C)OC CO[C]1[CH][CH][C]2N[C@H](C[C]2[C]1OC)C(=O)N[C@@H](C)C(=O)NCCC3=C4C=CC=C[C]4NC3 InChIKey=IARIFWFZBFLZIJ-VBKZILBWSA-N InChI=1S/C24H29N4O4/c1-14(23(29)25-11-10-15-13-26-18-7-5-4-6-16(15)18)27-24(30)20-12-17-19(28-20)8-9-21(31-2)22(17)32-3/h4-9,14,20,26,28H,10-13H2,1-3H3,(H,25,29)(H,27,30)/t14-,20+/m0/s1 InChI=1/C24H29N4O4/c1-14(23(29)25-11-10-15-13-26-18-7-5-4-6-16(15)18)27-24(30)20-12-17-19(28-20)8-9-21(31-2)22(17)32-3/h4-9,14,20,26,28H,10-13H2,1-3H3,(H,25,29)(H,27,30)/t14-,20+/m0/s1/f/h25,27H 3034.5813213369 -1442.773673 1-A 26622.3160 116 422 538 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|8.873702|17.614414|0.500000| |7.625905|12.540891|0.247029|36.858105| |5.897401|7.954676|0.165176|15.744725|73.516695| |5.959223|7.804813|0.205029|14.137869|15.207147|53.358707| |4.240287|5.021957|0.132468|7.860946|12.486421|17.963120|36.858105| |3.972421|4.227711|0.106634|6.085875|11.037474|10.369713|12.224667|36.858105| |3.252759|3.497349|0.087902|4.793153|9.783828|7.112282|7.496244|12.727411|36.858105| |2.650285|2.811201|0.072526|3.601750|7.089802|5.362412|5.355520|7.393857|14.040558|36.858105| |2.360840|2.466912|0.065179|3.041261|5.693510|4.667149|4.540747|5.805864|7.423608|13.197113|36.858105| |2.031278|2.115790|0.056236|2.531791|4.752885|3.784430|3.486183|4.141234|5.134290|7.953460|14.205993|36.858105| |1.914736|2.004072|0.052886|2.380672|4.574703|3.443524|3.087288|3.586952|4.646159|6.878718|7.863803|13.163178|36.858105| |2.033994|2.146595|0.055908|2.579276|5.108619|3.638679|3.249311|3.796798|5.284797|7.647878|6.609275|7.709330|14.066977|36.858105| |2.394621|2.550323|0.065437|3.180219|6.477477|4.476591|4.138387|5.099019|8.411917|13.190869|7.642544|6.815312|8.073960|13.437501|36.858105| |2.605678|2.808148|0.070560|3.546133|7.644941|4.746542|4.232238|5.085920|8.272954|8.449703|5.294867|4.658009|5.260585|7.719983|14.518827|53.358707| |2.424540|2.610437|0.065647|3.197563|6.901771|4.176932|3.564548|4.077789|5.825223|5.921225|4.235221|3.951528|4.643951|6.816363|9.282827|26.013388|0.500000| |3.245881|3.550375|0.086743|4.808926|11.105439|6.294727|5.708546|7.257352|12.708592|8.208810|5.077265|4.101625|4.150704|5.192170|8.360832|17.897772|0.243933|36.858105| |7.683553|13.218968|0.258348|7.955709|12.501416|7.239338|3.994397|3.480622|3.103611|2.552765|2.225165|1.948288|1.886255|2.045891|2.404957|3.680003|0.071694|3.332996|53.358707| |5.925359|7.820225|0.205146|5.214801|8.354274|5.511098|3.192676|2.813520|2.547303|2.165711|1.929464|1.717180|1.667787|1.792385|2.059942|3.104005|0.061223|2.702544|19.123964|36.858105| |5.735581|6.951182|0.215020|4.597955|7.039305|5.231087|3.012930|2.639026|2.350549|2.022194|1.834227|1.635489|1.574523|1.671059|1.902901|2.814616|0.055208|2.423942|11.606455|15.860009|73.516695| |4.185381|5.001776|0.130353|3.971805|6.931023|4.353662|2.688678|2.429466|2.285733|1.980826|1.763668|1.593751|1.571668|1.700333|1.930620|2.932108|0.059004|2.485531|10.577311|12.425268|14.111829|36.858105| |3.734402|4.665811|0.123348|3.964199|7.077363|4.379476|2.755262|2.452724|2.341214|2.035521|1.804545|1.634773|1.620491|1.761117|1.999212|3.050416|0.061679|2.570683|9.546295|9.014772|11.246520|17.547355|0.500000| |3.965317|4.333757|0.106909|3.627045|6.667806|3.960985|2.509232|2.360243|2.261664|1.963965|1.736286|1.576261|1.568714|1.710731|1.940808|2.983134|0.060751|2.513484|8.516422|7.369651|9.556912|12.265624|0.241499|36.858105| |3.558533|3.627818|0.092938|3.004226|5.358006|3.417999|2.177673|2.070433|1.969724|1.735255|1.559485|1.425032|1.412988|1.524224|1.707188|2.579430|0.052433|2.140989|6.391877|5.809015|8.802764|8.034780|0.162196|12.647617|36.858105| |3.342993|3.484987|0.093675|2.841741|4.924384|3.306857|2.096402|1.957301|1.846069|1.636777|1.486467|1.360548|1.342067|1.435994|1.599367|2.387863|0.048295|1.972722|5.998591|5.972541|9.947978|8.261636|0.165928|8.083398|13.713241|36.858105| |2.894921|2.918908|0.079988|2.423418|4.170162|2.900561|1.859707|1.750307|1.649645|1.478810|1.358062|1.250106|1.230961|1.307581|1.443020|2.131533|0.043094|1.741844|4.697642|4.396959|7.953098|5.238951|0.117695|5.199885|7.946521|13.879780|36.858105| |2.692761|2.621097|0.070710|2.218833|3.858523|2.671476|1.731727|1.659454|1.571617|1.415516|1.302615|1.203324|1.187454|1.260705|1.385844|2.044618|0.041453|1.660885|4.105673|3.608278|6.419122|4.118348|0.095437|4.504039|6.950138|8.010040|13.641918|36.858105| |2.798473|2.676610|0.070315|2.290735|4.050801|2.726486|1.775124|1.725254|1.644267|1.476519|1.349967|1.246409|1.234819|1.318024|1.452874|2.158681|0.043931|1.755564|4.216739|3.562890|6.068125|4.074830|0.094432|4.957373|7.973524|6.868929|7.853880|13.781988|36.858105| |3.196972|3.097636|0.079185|2.639284|4.742870|3.060297|1.980662|1.925076|1.841595|1.636227|1.477808|1.357556|1.349042|1.452286|1.615684|2.431228|0.049592|1.996888|5.097085|4.273114|6.836254|5.128584|0.115166|7.314063|13.890782|7.909791|6.800430|7.921582|13.562099|36.858105| |3.145580|2.995708|0.074855|2.636196|4.857873|3.044902|1.996585|1.980618|1.916713|1.702166|1.527150|1.404455|1.403505|1.520377|1.694185|2.569787|0.052733|2.105669|4.837202|3.765854|5.913907|4.323904|0.102123|6.349760|8.082204|5.234834|4.581398|5.208048|7.895881|14.031220|73.516695| |2.586699|2.512414|0.063572|2.287213|4.269375|2.687306|1.800195|1.796291|1.768714|1.592365|1.432528|1.330706|1.341733|1.456414|1.605716|2.434492|0.050540|1.954983|3.988122|3.060852|4.860328|3.558675|0.088623|4.918905|5.711101|4.186759|3.828055|4.373397|6.165025|8.098087|24.009955|36.858105| |2.502674|2.351382|0.061653|2.059475|3.665317|2.482596|1.637483|1.614367|1.547090|1.399775|1.285356|1.192522|1.183772|1.261000|1.381700|2.044801|0.041714|1.648196|3.592908|2.913320|4.991884|3.211595|0.077222|3.855774|5.301544|4.617755|5.159855|7.854689|14.067735|8.146772|12.494967|6.270737|73.516695| |2.213201|2.077499|0.055352|1.831783|3.232191|2.246486|1.490221|1.468327|1.404674|1.281119|1.187195|1.106018|1.095456|1.159298|1.261538|1.849829|0.037668|1.480714|3.103196|2.513053|4.421899|2.709856|0.066367|3.075563|3.998775|3.803058|4.504732|6.723363|8.012139|5.242655|8.247184|4.390953|24.212727|36.858105| |3.472825|3.892288|0.107164|3.147498|5.400311|3.639314|2.286192|2.081280|1.958370|1.728860|1.565477|1.428029|1.406532|1.506640|1.684997|2.519044|0.050796|2.092326|7.024630|7.744791|12.456998|13.111192|0.252574|8.012909|8.276808|13.522901|7.594375|5.103452|4.570253|5.291069|7.281353|3.436798|6.141470|2.968809|53.358707| |17.565533|8.783086|0.173544|6.942277|10.982890|7.164695|4.038407|4.036179|3.400153|2.747963|2.408837|2.075560|1.974975|2.120619|2.513481|3.783429|0.072157|3.495508|9.425539|5.256014|8.474534|4.034714|0.100175|4.116052|3.648789|3.272277|2.823520|2.688911|2.882482|3.364919|6.130372|2.813827|4.644643|2.277405|4.501331|0.500000| |17.547584|8.733625|0.212011|6.893807|9.305711|8.649087|4.509774|4.283955|3.349426|2.738302|2.482259|2.115422|1.961280|2.055715|2.415940|3.501067|0.065652|3.191499|7.589523|4.574422|8.259841|3.419126|0.087096|3.235302|2.972773|2.844250|2.536933|2.384654|2.457002|2.732378|4.805160|2.278137|3.982197|2.019154|4.012533|0.299931|0.500000| |17.615542|8.874202|0.214930|5.551956|8.130124|6.274877|3.469100|3.247289|2.746914|2.303970|2.083743|1.822100|1.727204|1.825933|2.111953|3.109223|0.059825|2.759468|9.532259|6.385624|11.966101|4.432749|0.105354|4.156131|3.930977|3.767928|3.293827|3.050033|3.131252|3.526370|5.973508|2.704579|4.907648|2.442582|5.200948|0.300517|0.301179|0.500000| |5.887093|7.400692|0.227500|9.368473|10.886208|26.067441|9.008447|5.911163|4.237322|3.396632|3.091636|2.552300|2.307119|2.394413|2.860667|4.043555|0.073702|3.742631|6.729192|3.987993|7.080364|3.097374|0.085651|2.763754|2.439604|2.407223|2.135626|1.957804|1.973562|2.184580|3.811207|1.887928|3.190003|1.637360|3.612709|0.135524|0.184973|0.131632|0.500000| |3.776715|4.653993|0.122478|7.160233|12.865213|12.541509|17.603562|8.711376|7.488753|5.498494|4.466193|3.520392|3.218064|3.473536|4.478124|6.405743|0.110233|6.320154|5.413604|3.186537|5.241452|2.751058|0.080220|2.557410|2.185261|2.102356|1.852037|1.716256|1.758726|1.972787|3.535733|1.808829|2.875027|1.467908|3.156759|0.101415|0.106441|0.087940|0.188631|0.500000| |3.700808|4.251682|0.118729|5.803020|9.035564|12.649549|17.635732|8.774703|5.988079|4.877032|4.551121|3.515853|3.020815|3.065001|3.740100|4.964491|0.086589|4.521257|4.667282|2.862261|4.935207|2.427753|0.069043|2.247339|1.986658|1.938879|1.741891|1.622357|1.648824|1.815520|3.230039|1.647135|2.713382|1.402113|2.875429|0.096046|0.112101|0.086954|0.233753|0.304126|0.500000| |3.545362|3.630749|0.094616|4.778548|8.276410|8.279866|8.726077|17.605548|8.980301|6.965815|6.462747|4.451851|3.638819|3.656739|4.649223|5.890891|0.098433|5.457645|4.084802|2.504999|4.265228|2.174440|0.060622|2.111435|1.888252|1.799260|1.629793|1.553051|1.608074|1.772034|3.232119|1.656264|2.693493|1.390146|2.585601|0.098770|0.109606|0.082520|0.146526|0.179002|0.229825|0.500000| |4.735354|4.768368|0.114880|6.843326|12.499273|10.399402|8.800971|17.614649|9.063541|5.764409|4.623342|3.521279|3.156809|3.386938|4.441550|6.376002|0.107963|6.834351|5.222591|3.039385|5.029183|2.593476|0.071519|2.559271|2.243645|2.094633|1.866132|1.778639|1.865487|2.096168|3.865891|1.949857|3.105415|1.578701|2.998982|0.139088|0.142824|0.103820|0.163816|0.186095|0.180822|0.303713|0.500000| |2.441181|2.529404|0.067580|3.100451|5.612491|4.928785|4.824902|6.138749|6.560763|8.705547|17.747599|9.034589|5.587766|4.815843|5.495135|5.837441|0.098113|4.424844|3.045039|1.945095|3.323418|1.756875|0.049653|1.716132|1.551278|1.487323|1.363575|1.306327|1.348177|1.469079|2.683594|1.407631|2.280060|1.188395|2.132192|0.068326|0.072647|0.059775|0.092451|0.124710|0.141941|0.215142|0.133376|0.500000| |1.880122|1.945117|0.052219|2.284564|4.215010|3.432280|3.090334|3.560089|4.102484|5.625699|9.047414|17.756419|8.768554|5.587411|4.927518|5.022551|0.089957|3.354884|2.435830|1.594593|2.722932|1.480799|0.042083|1.460205|1.331358|1.277894|1.181385|1.138698|1.175335|1.271735|2.330534|1.243850|2.003921|1.050845|1.821980|0.053007|0.054683|0.047252|0.065537|0.085530|0.088771|0.108843|0.085604|0.215806|0.500000| |1.728161|1.801626|0.047821|2.100947|4.005095|3.020259|2.641817|2.988237|3.681475|4.956428|5.656359|8.796551|17.723062|9.095841|5.701166|5.716360|0.108517|3.397001|2.325678|1.527985|2.574621|1.450271|0.041528|1.449256|1.314128|1.251582|1.153787|1.115630|1.158434|1.259289|2.326992|1.258576|1.980880|1.035164|1.780690|0.049405|0.049082|0.043720|0.056918|0.076289|0.072520|0.084615|0.074531|0.124072|0.215617|0.500000| |1.898502|2.003351|0.052153|2.367570|4.713692|3.276088|2.839456|3.224348|4.289217|5.491813|4.816408|5.520724|8.950260|17.753032|8.751334|9.236631|0.192711|4.539068|2.642545|1.715168|2.833738|1.648775|0.047571|1.670557|1.489636|1.400116|1.276179|1.233419|1.292161|1.423797|2.658777|1.445393|2.203403|1.139336|1.994601|0.055168|0.052801|0.047743|0.060232|0.084843|0.074200|0.085455|0.082152|0.105231|0.123162|0.216814|0.500000| |3.488564|3.672730|0.087446|4.830500|11.391460|5.999540|4.980171|6.491624|8.890117|6.234393|4.299779|3.566508|3.604438|4.385699|6.318055|12.325931|0.204796|17.560531|4.723647|2.793178|4.419727|2.571674|0.072679|2.668345|2.272940|2.060460|1.815970|1.746344|1.867835|2.141326|4.078477|2.119648|3.131182|1.571698|2.932556|0.108626|0.094217|0.081843|0.100047|0.142843|0.110664|0.139756|0.197166|0.107718|0.083237|0.084217|0.110366|0.500000| |3.421368|3.952606|0.096004|5.543377|13.839063|6.920783|6.092346|6.480363|8.843328|6.197050|4.277877|3.551429|3.591150|4.370174|6.286413|12.283699|0.204977|17.598802|5.172324|3.021680|4.735004|2.781587|0.081399|2.772295|2.308413|2.131649|1.858879|1.752505|1.844457|2.115271|3.929646|2.043716|3.043817|1.531175|3.128946|0.100809|0.091260|0.080703|0.111937|0.207551|0.130160|0.134290|0.169625|0.107197|0.082920|0.083955|0.110090|0.303040|0.500000| |6.359918|9.102377|0.182799|7.595183|14.446251|6.777996|3.967288|3.564100|3.293453|2.687901|2.297853|2.015906|1.975720|2.175123|2.579180|4.046897|0.079631|3.701954|26.068317|9.278494|10.845663|7.333150|0.196200|6.822054|4.713579|4.174855|3.258209|2.908357|3.066333|3.806689|6.677276|3.130126|4.692678|2.254467|6.475954|0.181116|0.134308|0.156329|0.122599|0.112820|0.092713|0.083901|0.109684|0.063262|0.051016|0.049570|0.057650|0.108736|0.119642|0.500000| |3.330425|3.675058|0.091877|3.262401|6.171290|3.627812|2.362200|2.233345|2.187266|1.919380|1.693031|1.549476|1.557573|1.708601|1.926235|2.978977|0.061500|2.466919|6.857543|5.540995|7.604718|8.754481|0.224735|17.549546|8.855455|6.410667|4.509173|4.009612|4.421589|6.224898|10.329946|5.054742|6.353123|2.881714|8.937133|0.096644|0.077844|0.094497|0.069817|0.067919|0.058916|0.055516|0.066467|0.046118|0.039824|0.040105|0.046745|0.072327|0.075905|0.158798|0.500000| |4.593433|4.887469|0.113983|4.116217|7.768813|4.352626|2.739680|2.619985|2.505323|2.143744|1.874042|1.688675|1.679135|1.841697|2.113976|3.285095|0.066660|2.819149|9.658053|7.087476|9.098973|8.572563|0.188941|17.601542|8.778238|5.940418|4.292040|3.941638|4.496439|6.560080|11.728947|4.927939|6.557962|2.941811|7.888654|0.139737|0.101316|0.129864|0.082833|0.076990|0.067072|0.064425|0.080466|0.051358|0.043216|0.042840|0.049778|0.084949|0.086118|0.235071|0.302631|0.500000| |2.678035|2.727975|0.076560|2.278672|3.882755|2.772874|1.783030|1.665810|1.566278|1.411662|1.305166|1.204030|1.182681|1.250118|1.373698|2.015024|0.040655|1.639395|4.289026|4.003433|7.579896|4.582911|0.107622|4.236719|5.633862|8.896600|17.725862|8.876577|5.615379|4.914983|6.472021|3.162275|7.416690|3.910835|9.178805|0.071362|0.066306|0.084341|0.057285|0.049327|0.046822|0.043328|0.048940|0.036509|0.031721|0.030862|0.033864|0.047084|0.048582|0.081636|0.105085|0.099507|0.500000| |2.411184|2.332695|0.063615|1.999044|3.464303|2.444551|1.596524|1.534064|1.453287|1.318237|1.221679|1.132906|1.116793|1.180083|1.289610|1.889700|0.038294|1.524737|3.559406|3.066954|5.573858|3.388444|0.081037|3.594776|4.995532|5.699062|8.956992|17.761784|8.935718|5.634628|7.463609|3.719565|12.549742|7.506053|5.612350|0.066564|0.060421|0.075529|0.050046|0.043848|0.041863|0.040177|0.045477|0.034099|0.029899|0.029243|0.032088|0.044385|0.044440|0.069883|0.091161|0.089776|0.216574|0.500000| |2.538411|2.444502|0.061318|2.271238|4.296236|2.673853|1.809115|1.831335|1.819216|1.640737|1.470789|1.368494|1.385772|1.510340|1.664761|2.534819|0.052878|2.026053|3.814029|2.832564|4.490589|3.191854|0.081008|4.300565|4.593274|3.495445|3.193456|3.560488|4.719762|5.892921|16.892483|17.628521|8.836992|3.741983|4.080015|0.078048|0.062567|0.072470|0.051809|0.050464|0.045832|0.046891|0.055437|0.039983|0.035455|0.036102|0.041757|0.061663|0.058306|0.084276|0.123278|0.126426|0.075303|0.086642|0.500000| |2.349374|2.265308|0.058165|2.059650|3.797252|2.457018|1.651007|1.646822|1.616676|1.466798|1.331510|1.241941|1.249890|1.347932|1.475265|2.214528|0.045876|1.765859|3.526070|2.738706|4.465682|3.134428|0.078341|4.064762|4.925928|3.886149|3.781547|4.570933|6.562917|7.103627|16.412364|17.638462|13.743842|5.308106|4.286170|0.070061|0.058250|0.068876|0.048361|0.045918|0.042324|0.042541|0.049425|0.036455|0.032405|0.032701|0.037169|0.052843|0.050998|0.075372|0.114260|0.110656|0.087627|0.111527|0.299791|0.500000| |2.482489|2.481864|0.063104|2.276472|4.278311|2.670505|1.796445|1.776382|1.761735|1.589415|1.426551|1.328354|1.345099|1.464856|1.612546|2.454176|0.051244|1.961021|4.010722|3.101569|4.863845|3.763256|0.095783|5.269873|5.831584|4.324072|3.848533|4.192725|5.480517|7.222374|16.428428|17.547730|9.166729|3.843238|4.948715|0.074143|0.060714|0.071499|0.051992|0.050650|0.045649|0.045328|0.053102|0.038808|0.034450|0.035080|0.040530|0.058537|0.057513|0.088304|0.163769|0.139205|0.088942|0.098723|0.299491|0.299010|0.500000| |2.294773|2.129084|0.057179|1.857942|3.240236|2.290516|1.510282|1.483973|1.407435|1.281884|1.192309|1.108006|1.091764|1.150834|1.253779|1.830398|0.037077|1.471134|3.139714|2.558966|4.599241|2.690818|0.065475|2.968669|3.834720|3.779634|4.596415|6.745749|7.077520|4.783761|7.377116|3.743215|16.448682|17.558567|4.041920|0.064898|0.058437|0.071379|0.046716|0.041085|0.039613|0.039167|0.044365|0.033304|0.029299|0.028634|0.031298|0.043298|0.042207|0.062465|0.075797|0.079291|0.113509|0.224307|0.090834|0.118365|0.092263|0.500000| |2.045952|1.955450|0.052506|1.733261|3.060857|2.134142|1.421556|1.392848|1.337551|1.224754|1.137012|1.062625|1.054517|1.115332|1.209370|1.771058|0.036147|1.410569|2.935102|2.395239|4.223253|2.626347|0.065065|2.932711|3.783285|3.734230|4.558333|6.715601|7.002902|4.721132|7.266200|4.030679|16.431838|17.555603|4.002389|0.057999|0.052004|0.062315|0.043262|0.039092|0.037268|0.036642|0.041315|0.031581|0.028079|0.027741|0.030514|0.041329|0.040654|0.059245|0.077733|0.076351|0.112927|0.227117|0.094835|0.135059|0.102790|0.298944|0.500000| 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