Version2.2
2021-02-05T13:41:59Z
10.1021/jm300687e
Gaussian16
RevisionB.01
PWARBURT
16-Jan-2021
#N HF/6-31G(d) OPT=(MaxStep=1) FREQ IOp(6/10=2,6/11=2,6/12=2)
DUDE C[C@@H](C(=O)Nc1ccc(c(c1)Cl)C#N)[NH+]2CCC(CC2)C(=O)c3ccc4c(c3)OCCO4 C14329273
RHF
6-31G(d)
(6D,7F)
C[C@@H](C(=O)Nc1ccc(c(c1)Cl)C#N)[NH+]2CCC(CC2)C(=O)c3ccc4c(c3)OCCO4
C01[X(C24H25Cl1N3O4)]
165
C1
534
N#Cc1ccc(cc1Cl)NC(=O)[C@@H]([NH+]1CCC(CC1)C(=O)c1ccc2c(c1)OCCO2)C
N#Cc1ccc(cc1Cl)NC(=O)[C@@H]([NH+]1CCC(CC1)C(=O)c1ccc2c(c1)OCCO2)C
C[C@H]([NH+]1CCC(CC1)C(=O)c2ccc3OCCOc3c2)C(=O)Nc4ccc(C#N)c(Cl)c4
InChIKey=IIPZGWMLVASEOB-HNNXBMFYSA-O
InChI=1S/C24H24ClN3O4/c1-15(24(30)27-19-4-2-18(14-26)20(25)13-19)28-8-6-16(7-9-28)23(29)17-3-5-21-22(12-17)32-11-10-31-21/h2-5,12-13,15-16H,6-11H2,1H3,(H,27,30)/p+1/t15-/m0/s1
InChI=1/C24H24ClN3O4/c1-15(24(30)27-19-4-2-18(14-26)20(25)13-19)28-8-6-16(7-9-28)23(29)17-3-5-21-22(12-17)32-11-10-31-21/h2-5,12-13,15-16H,6-11H2,1H3,(H,27,30)/p+1/t15-/m0/s1/fC24H25ClN3O4/h27-28H/q+1
C[C@@H](C(=O)Nc1ccc(c(c1)Cl)C#N)[NH+]2CCC(CC2)C(=O)c3ccc4c(c3)OCCO4
C01[X(C24H25Cl1N3O4)]
165
C01
534
N#Cc1ccc(cc1Cl)NC(=O)[C@@H]([NH+]1CCC(CC1)C(=O)c1ccc2c(c1)OCCO2)C
N#C[C]1[CH][CH][C]([CH][C]1[Cl])NC(=O)[C@@H]([NH]1CC[C@H](CC1)C(=O)[C]1[CH][CH][C]2[C]([CH]1)OCCO2)C
C[C@H]([NH]1CC[C@H](CC1)C(=O)[C]2[CH][CH][C]3OCCO[C]3[CH]2)C(=O)N[C]4[CH][CH][C](C#N)[C](Cl)[CH]4
InChIKey=VRKQKLHYYJZJJT-HNNXBMFYSA-N
InChI=1S/C24H25ClN3O4/c1-15(24(30)27-19-4-2-18(14-26)20(25)13-19)28-8-6-16(7-9-28)23(29)17-3-5-21-22(12-17)32-11-10-31-21/h2-5,12-13,15-16,28H,6-11H2,1H3,(H,27,30)/t15-/m0/s1
InChI=1/C24H25ClN3O4/c1-15(24(30)27-19-4-2-18(14-26)20(25)13-19)28-8-6-16(7-9-28)23(29)17-3-5-21-22(12-17)32-11-10-31-21/h2-5,12-13,15-16,28H,6-11H2,1H3,(H,27,30)/t15-/m0/s1/f/h27H
3081.8485047926
-1845.4826893
1-A
30151.3825
119
415
534
|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|
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10.18650
-3.1287 11.7730 -6.8177
13.9597
|XX|YY|ZZ|XY|XZ|YZ|
-146.3562 -160.6900 -187.3499 59.8692 -9.6636 -6.7467
|XX|YY|ZZ|XY|XZ|YZ|
18.4425 4.1087 -22.5513 59.8692 -9.6636 -6.7467
|XXX|YYY|ZZZ|XYY|XXY|XXZ|XZZ|YZZ|YYZ|XYZ|
-1122.1491 128.3060 -20.3254 -131.6103 99.4274 -123.7146 63.4442 14.4365 8.8092 -27.1883
|XXXX|YYYY|ZZZZ|XXXY|XXXZ|YYYX|YYYZ|ZZZX|ZZZY|XXYY|XXZZ|YYZZ|XXYZ|YYXZ|ZZXY|
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|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|
8.4547 10.4517 19.0080 24.4764 44.8557 46.4380 58.6633 83.8713 91.7687 101.5713 122.4106 133.5636 144.2469 154.6503 160.1198 184.8464 208.1265 216.4677 221.5008 248.5809 258.7302 262.5490 292.9256 314.2674 326.2713 349.8677 358.8553 374.1255 380.8116 395.6459 409.2815 439.2043 443.0834 467.8255 481.8589 492.3109 507.0222 513.3572 519.0060 523.4969 562.2828 567.9039 577.3485 610.4828 626.4794 632.4535 655.1432 665.9205 677.5398 726.8101 747.4147 762.7974 783.9253 799.3376 807.5688 808.3480 822.7754 832.0942 858.9448 876.5417 879.9426 920.8362 931.9524 946.5358 968.5101 973.6992 987.9551 1003.5775 1011.5992 1024.3409 1032.0566 1039.0894 1045.7368 1059.4905 1068.3631 1087.0237 1097.0210 1119.7504 1132.5377 1138.9865 1165.6269 1175.5038 1179.9295 1196.3724 1203.1029 1207.3090 1219.6398 1224.1448 1237.3427 1249.1407 1255.4682 1278.8833 1287.8124 1307.7207 1315.8087 1324.4842 1327.6400 1352.0785 1380.3852 1387.0456 1397.7380 1406.5667 1414.3673 1415.4004 1428.6126 1434.0721 1455.7143 1458.1310 1469.9279 1478.8414 1501.2903 1523.2074 1534.7397 1540.4222 1555.9222 1561.1588 1565.7425 1570.5236 1574.1808 1583.0126 1596.3162 1611.3406 1627.1791 1637.1369 1637.5238 1645.6668 1650.8574 1654.1254 1657.9472 1661.3331 1668.4490 1694.0090 1720.1051 1776.6643 1789.3272 1796.5892 1809.8203 1950.3087 1966.1311 2619.4433 3225.8910 3234.7825 3235.3519 3242.5970 3246.3541 3252.2599 3265.1189 3270.2191 3282.3884 3288.4941 3300.3114 3310.8101 3326.4573 3327.6567 3328.8586 3344.5887 3360.2992 3367.6857 3385.0323 3404.8094 3408.8341 3423.3985 3476.5581 3625.3857 3856.1932
7.9190 8.1896 5.4192 7.5417 4.9870 4.3858 6.5639 4.6405 4.9840 5.3516 5.7314 4.8461 8.8956 4.9904 6.3102 4.8248 5.2977 4.1559 4.3689 4.0450 1.9947 4.0375 1.9684 3.5228 3.4552 2.2828 2.2863 4.0795 4.8427 5.7738 8.1303 3.4249 8.8329 3.2516 3.2536 3.0276 3.2268 5.3766 3.9795 4.2662 3.4605 6.3195 5.2965 1.2723 3.0300 3.9662 7.7279 5.1634 3.6906 2.8228 4.8501 6.7736 4.7757 5.8837 4.6250 4.3373 6.1640 4.1361 2.6014 1.6509 3.5106 1.5522 1.4570 2.0758 3.6311 3.1731 2.7731 4.2587 1.8160 1.4385 3.5682 1.9172 1.6077 1.8385 1.3749 2.1364 1.3623 2.1314 2.6524 2.5455 3.5355 2.5775 2.3258 2.3795 2.5075 1.8551 3.8299 1.7839 1.9566 1.7438 1.9186 1.7978 2.1068 3.2944 3.3313 2.9685 2.0365 1.7737 1.7938 1.3452 1.4450 1.4188 1.4037 1.4822 1.4240 1.4122 2.2105 1.3123 1.5894 1.3896 1.3049 1.3349 1.4191 1.4238 2.3846 1.5279 1.4967 1.4967 1.2556 1.3627 3.3837 1.1875 1.0946 1.0803 1.0913 1.0857 1.0929 1.1295 1.1375 1.0910 2.4546 3.0032 3.0794 7.0044 3.4363 5.8629 4.5747 8.5982 12.1176 12.6962 1.0694 1.0708 1.0371 1.0830 1.0652 1.0630 1.0680 1.0706 1.0890 1.0970 1.1029 1.1031 1.0992 1.1051 1.1052 1.1064 1.1029 1.0921 1.0885 1.0959 1.0959 1.0928 1.0935 1.0773 1.0786
0.0003 0.0005 0.0012 0.0027 0.0059 0.0056 0.0133 0.0192 0.0247 0.0325 0.0506 0.0509 0.1091 0.0703 0.0953 0.0971 0.1352 0.1147 0.1263 0.1473 0.0787 0.1640 0.0995 0.2050 0.2167 0.1646 0.1735 0.3364 0.4138 0.5325 0.8024 0.3893 1.0217 0.4193 0.4451 0.4323 0.4887 0.8348 0.6316 0.6888 0.6446 1.2008 1.0402 0.2794 0.7007 0.9347 1.9543 1.3491 0.9982 0.8786 1.5963 2.3221 1.7291 2.2149 1.7771 1.6698 2.4585 1.6873 1.1308 0.7473 1.6015 0.7755 0.7456 1.0958 2.0068 1.7725 1.5948 2.5271 1.0949 0.8893 2.2393 1.2196 1.0358 1.2159 0.9246 1.4874 0.9659 1.5745 2.0044 1.9457 2.8302 2.0984 1.9078 2.0067 2.1384 1.5931 3.3566 1.5751 1.7649 1.6031 1.7817 1.7325 2.0586 3.3193 3.3982 3.0682 2.1150 1.9104 2.0139 1.5248 1.6633 1.6539 1.6545 1.7495 1.7123 1.7112 2.7598 1.6440 2.0233 1.7905 1.7329 1.8248 1.9694 1.9905 3.4013 2.1941 2.1619 2.1751 1.8332 2.0119 5.0802 1.8167 1.7076 1.7060 1.7242 1.7324 1.7550 1.8208 1.8422 1.7742 4.0258 5.0777 5.3683 13.0265 6.4822 11.1496 8.8284 19.2691 27.5989 51.3264 6.5567 6.6016 6.3961 6.7089 6.6141 6.6243 6.7087 6.7458 6.9127 6.9896 7.0780 7.1240 7.1664 7.2099 7.2157 7.2920 7.3376 7.2975 7.3488 7.4851 7.5027 7.5458 7.7869 8.3426 9.4502
0.7384 0.1608 0.8942 2.4851 2.8937 2.4071 2.4956 1.5598 1.7706 1.8006 0.9864 12.7396 4.6116 7.5294 3.3620 7.7992 0.9582 0.4986 0.6821 2.3130 3.2299 4.1538 0.8784 2.2508 8.4913 6.4891 5.9605 9.6764 36.7917 5.0463 11.6179 2.8832 7.6251 1.3793 2.6924 8.7556 3.1547 2.5096 1.7401 9.6526 3.1986 2.2545 6.1805 82.6759 5.5595 2.4092 0.9892 11.6636 2.8944 25.2946 0.6162 10.9503 4.2982 1.6141 15.5339 0.5378 23.1566 2.7104 8.5473 6.6589 29.9318 28.4333 46.6570 3.5310 31.4599 9.9362 74.4959 31.6234 4.0480 26.2710 18.0926 20.1782 27.7875 26.8162 9.2903 83.9504 0.4202 12.9569 10.7426 6.6404 22.3979 16.8964 14.0905 3.3498 120.1384 5.0960 5.9761 16.5806 8.9391 27.6629 3.4325 34.9102 16.8043 141.3368 9.7953 22.5830 5.6636 57.1909 82.4574 25.1379 38.3894 28.3276 115.1605 33.5818 20.1763 62.9772 567.6491 12.7111 96.9411 43.7551 76.5864 1.3087 1.5982 20.2762 214.3584 99.9892 40.4742 34.1091 23.9946 9.2806 197.1588 98.3762 2.5073 15.6384 7.8767 20.1872 39.2635 13.6702 2.8420 0.7644 67.5375 216.6883 393.1638 47.4909 409.2012 118.7010 25.9621 248.4902 242.8122 23.8205 2.9869 37.1739 2.6468 12.1596 46.8098 4.2940 0.7443 9.2952 4.0104 11.8518 9.6260 10.5021 40.8439 10.6218 25.2958 7.5374 6.0878 9.5271 19.0594 7.8952 0.4033 3.0348 9.3734 92.1393 48.2861
4.4564 5.3534 3.4452 0.8797 0.5446 0.4120 2.6635 0.0712 0.5365 0.3096 0.1476 2.2342 2.0849 0.6526 2.9746 0.7794 1.6407 1.2153 1.8749 0.3789 0.1959 0.5941 0.4948 0.2319 0.5792 0.5624 0.2145 2.4179 1.6541 0.7114 4.6834 0.9896 3.9336 2.6213 2.5855 3.7720 3.1804 2.1196 1.7001 2.1524 1.8388 7.1321 4.1540 2.8383 1.7876 0.8634 1.7600 4.8236 0.3226 3.2911 5.3680 6.7753 1.4302 12.4684 9.6681 5.3498 19.1947 2.8557 12.9610 1.7207 9.2508 1.3453 1.3785 0.7774 1.3500 3.0564 2.8145 4.9217 2.0578 2.3897 2.8081 1.6733 1.9839 1.0065 0.4209 6.1049 1.9791 17.0336 3.5436 4.2321 11.8845 11.8634 4.0522 1.6873 7.1504 11.5239 3.4984 4.3563 0.6665 14.1997 15.2748 30.1130 8.0293 11.6613 7.3112 34.1919 2.2593 15.3567 84.1001 19.7715 21.2235 11.9485 14.3565 5.6646 2.8603 44.5617 74.6923 16.6883 10.9429 6.1926 3.3337 2.9659 2.4101 6.8146 2.4029 3.2544 3.2695 2.6231 2.3099 8.6622 30.9575 27.4119 9.3571 2.8424 9.3055 6.2421 10.7540 17.5465 9.3701 3.0774 0.5341 5.1959 15.9014 17.3971 113.7799 282.2818 232.2873 52.0043 94.0422 427.1039 60.3700 141.3389 104.6383 18.6053 57.6565 85.8611 17.4506 60.4063 52.6110 67.5313 61.5242 66.8544 169.7156 79.3506 120.4602 69.0305 70.3309 67.7534 52.1700 111.5758 111.6420 46.2366 35.4517 22.1518 55.2703
0.7468 0.7493 0.7497 0.7484 0.7276 0.7414 0.7479 0.7216 0.5893 0.7393 0.7415 0.7283 0.5848 0.6638 0.2677 0.5774 0.7491 0.7423 0.7213 0.6775 0.5905 0.3875 0.4491 0.3436 0.2785 0.1216 0.5854 0.4697 0.6208 0.7295 0.7198 0.5640 0.2303 0.5923 0.7483 0.0530 0.3478 0.7071 0.7003 0.6152 0.6596 0.7384 0.2879 0.6916 0.6566 0.2867 0.3257 0.7084 0.6293 0.1938 0.2479 0.2592 0.0417 0.0764 0.1738 0.7499 0.1376 0.7495 0.1458 0.5757 0.0711 0.6304 0.7498 0.0401 0.5812 0.7190 0.3559 0.1768 0.5829 0.7462 0.2761 0.7107 0.7109 0.7403 0.7489 0.4826 0.7493 0.5974 0.5772 0.7491 0.1638 0.4324 0.7156 0.6792 0.7110 0.6890 0.6062 0.3573 0.1027 0.1001 0.0415 0.2518 0.5093 0.7089 0.3688 0.1760 0.5908 0.2086 0.2992 0.2255 0.4495 0.5088 0.2424 0.1284 0.4381 0.4612 0.2802 0.6128 0.6221 0.1374 0.4973 0.7497 0.6552 0.7422 0.5073 0.7497 0.6393 0.4761 0.6621 0.5649 0.4029 0.5695 0.7412 0.6806 0.6321 0.7166 0.7469 0.6888 0.4218 0.6662 0.7486 0.2976 0.5527 0.3806 0.3223 0.4826 0.4746 0.2898 0.2867 0.3048 0.1334 0.1370 0.0094 0.5872 0.2680 0.1126 0.7386 0.0970 0.3771 0.2240 0.3833 0.5530 0.3153 0.6257 0.5918 0.4646 0.3418 0.3752 0.6468 0.1607 0.2411 0.2745 0.2413 0.1291 0.1412
0.8550 0.8567 0.8569 0.8561 0.8424 0.8515 0.8557 0.8383 0.7416 0.8501 0.8516 0.8428 0.7380 0.7979 0.4224 0.7321 0.8566 0.8521 0.8381 0.8077 0.7425 0.5585 0.6199 0.5115 0.4356 0.2168 0.7385 0.6392 0.7661 0.8436 0.8371 0.7212 0.3743 0.7440 0.8560 0.1007 0.5161 0.8284 0.8238 0.7617 0.7949 0.8495 0.4471 0.8177 0.7927 0.4456 0.4914 0.8293 0.7725 0.3246 0.3973 0.4116 0.0801 0.1420 0.2961 0.8571 0.2419 0.8568 0.2546 0.7308 0.1327 0.7733 0.8570 0.0771 0.7351 0.8366 0.5250 0.3004 0.7365 0.8547 0.4327 0.8309 0.8310 0.8507 0.8564 0.6510 0.8567 0.7480 0.7320 0.8565 0.2815 0.6038 0.8342 0.8090 0.8311 0.8159 0.7548 0.5265 0.1863 0.1820 0.0796 0.4023 0.6749 0.8297 0.5389 0.2994 0.7428 0.3452 0.4606 0.3680 0.6202 0.6745 0.3902 0.2275 0.6093 0.6313 0.4377 0.7599 0.7670 0.2417 0.6643 0.8569 0.7917 0.8520 0.6731 0.8570 0.7799 0.6451 0.7967 0.7220 0.5744 0.7257 0.8514 0.8100 0.7746 0.8349 0.8551 0.8157 0.5934 0.7997 0.8562 0.4587 0.7119 0.5514 0.4875 0.6511 0.6437 0.4494 0.4457 0.4672 0.2353 0.2410 0.0187 0.7399 0.4227 0.2023 0.8496 0.1769 0.5477 0.3659 0.5541 0.7122 0.4795 0.7698 0.7436 0.6345 0.5095 0.5457 0.7855 0.2770 0.3885 0.4307 0.3887 0.2286 0.2474
298.150
1.00000
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57
6 6 1 6 8 7 6 6 6 6 6 6 17 6 7 7 1 6 6 6 6 6 6 8 6 6 6 6 6 6 8 6 6 8 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1
12.00000 12.00000 1.00783 12.00000 15.99491 14.00307 12.00000 12.00000 12.00000 12.00000 12.00000 12.00000 34.96885 12.00000 14.00307 14.00307 1.00783 12.00000 12.00000 12.00000 12.00000 12.00000 12.00000 15.99491 12.00000 12.00000 12.00000 12.00000 12.00000 12.00000 15.99491 12.00000 12.00000 15.99491 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783
7120.0505 51741.1470 55032.4819
0.99995 0.01020 -0.00233 -0.01018 0.99992 0.00755 0.00241 -0.00753 0.99997
1
0.01216 0.00167 0.00157
0.25347 0.03488 0.03279
12.16 15.04 27.35 35.22 64.54 66.81 84.40 120.67 132.03 146.14 176.12 192.17 207.54 222.51 230.38 265.95 299.45 311.45 318.69 357.65 372.26 377.75 421.45 452.16 469.43 503.38 516.31 538.28 547.90 569.25 588.86 631.92 637.50 673.10 693.29 708.33 729.49 738.61 746.73 753.20 809.00 817.09 830.68 878.35 901.36 909.96 942.60 958.11 974.83 1045.72 1075.36 1097.50 1127.89 1150.07 1161.91 1163.03 1183.79 1197.20 1235.83 1261.15 1266.04 1324.88 1340.87 1361.85 1393.47 1400.94 1421.45 1443.92 1455.47 1473.80 1484.90 1495.02 1504.58 1524.37 1537.14 1563.98 1578.37 1611.07 1629.47 1638.75 1677.08 1691.29 1697.66 1721.31 1731.00 1737.05 1754.79 1761.27 1780.26 1797.23 1806.34 1840.03 1852.87 1881.52 1893.16 1905.64 1910.18 1945.34 1986.07 1995.65 2011.03 2023.74 2034.96 2036.45 2055.45 2063.31 2094.45 2097.93 2114.90 2127.72 2160.02 2191.56 2208.15 2216.32 2238.63 2246.16 2252.75 2259.63 2264.90 2277.60 2296.74 2318.36 2341.15 2355.47 2356.03 2367.75 2375.22 2379.92 2385.42 2390.29 2400.53 2437.30 2474.85 2556.22 2574.44 2584.89 2603.93 2806.06 2828.82 3768.79 4641.34 4654.13 4654.95 4665.37 4670.78 4679.28 4697.78 4705.12 4722.62 4731.41 4748.41 4763.52 4786.03 4787.76 4789.49 4812.12 4834.72 4845.35 4870.31 4898.76 4904.55 4925.51 5001.99 5216.12 5548.20
0.499765
0.526550
0.527495
0.437340
-1844.982925
-1844.956139
-1844.955195
-1845.045350
3.023814D-04
MUNgauss
RevisionA2.1
retrievium
05-Feb-2021
DUDE C[C@@H](C(=O)Nc1ccc(c(c1)Cl)C#N)[NH+]2CCC(CC2)C(=O)c3ccc4c(c3)OCCO4 C14329273
RHF
6-31G(d)
(6D,10F)
C1
454.153359
|X|Y|Z|
161.229941 54.518014 34.409118
67.125328
26
|36.858105|
|12.431788|36.858105|
|8.820342|17.606608|0.500000|
|7.619299|12.381652|0.242314|36.858105|
|5.947312|8.084599|0.166426|15.870028|73.516695|
|6.027334|7.823500|0.201743|14.199874|14.912033|53.358707|
|4.297975|4.992908|0.131490|7.656925|11.495773|18.276985|36.858105|
|3.596402|3.982370|0.111407|5.179112|7.870078|10.853754|13.701317|36.858105|
|2.897311|3.127904|0.086648|3.913895|6.397928|7.083151|7.959296|13.843307|36.858105|
|2.684921|2.894758|0.078032|3.681493|6.404928|6.181085|6.857485|7.918938|13.688505|36.858105|
|2.948901|3.229236|0.084284|4.335595|7.978179|6.985037|7.976592|6.893454|7.959390|13.710598|36.858105|
|3.701901|4.205572|0.106609|6.320286|11.669059|10.520264|13.748532|7.905555|6.860457|7.880801|13.751538|36.858105|
|2.508362|2.703115|0.069852|3.454567|6.749414|5.046019|4.804126|4.243338|4.769362|7.024624|11.036364|7.121075|448.794386|
|2.239307|2.375082|0.064416|2.885118|5.094752|4.601410|4.515360|5.132080|7.801044|13.217736|7.688214|5.083206|50.177338|36.858105|
|1.979180|2.080656|0.056645|2.462940|4.370434|3.831329|3.558979|3.982221|5.510272|7.395689|5.393647|3.928061|40.924906|16.783824|53.358707|
|7.491055|12.670870|0.253009|7.882178|13.033602|7.185840|3.913020|3.187742|2.639470|2.526603|2.850804|3.590197|20.154485|2.126826|2.571608|53.358707|
|6.694587|9.471089|0.184777|8.075708|16.372868|7.031148|3.988249|3.163701|2.658527|2.607428|3.020277|3.844513|21.775788|2.192676|2.646557|25.579896|0.500000|
|6.505588|7.467120|0.179451|5.028782|8.530490|5.257820|3.046950|2.607488|2.218396|2.126000|2.348804|2.831547|17.015817|1.834303|2.251778|17.224570|0.256565|36.858105|
|4.370061|4.921688|0.123304|3.929098|7.174820|4.257675|2.604919|2.251935|1.968015|1.921580|2.130075|2.509085|15.908471|1.685123|2.088277|10.418526|0.199118|12.501339|36.858105|
|3.602023|4.329045|0.115151|3.651558|6.669714|4.069181|2.530762|2.207864|1.941673|1.897423|2.093512|2.443201|15.673951|1.671031|2.075670|8.757366|0.164040|7.503814|12.452888|36.858105|
|3.779879|4.973556|0.131286|4.460689|8.351078|4.843966|2.991407|2.548668|2.220301|2.178263|2.439160|2.902095|18.089228|1.892039|2.327704|10.373754|0.199847|6.515108|7.619132|12.393448|36.858105|
|4.941063|7.672640|0.207380|6.310974|10.729251|6.490834|3.715097|3.096431|2.595199|2.485602|2.778625|3.429296|19.731471|2.107067|2.556558|17.190132|0.259406|7.709383|6.555314|7.526078|12.517379|36.858105|
|2.860309|3.273764|0.086835|2.938875|5.516684|3.375537|2.179861|1.924062|1.729537|1.714047|1.889363|2.155251|14.513264|1.533412|1.922892|5.985944|0.121417|4.905913|7.578111|12.413134|7.596804|4.921766|36.858105|
|2.777445|3.083954|0.079786|2.824013|5.427064|3.232098|2.110619|1.854901|1.679434|1.680939|1.865840|2.119655|14.545547|1.509656|1.897154|5.541937|0.118235|4.545219|7.024640|8.116905|5.964091|4.226423|15.922677|73.516695|
|2.410469|2.745234|0.075017|2.513927|4.649461|2.985418|1.962792|1.764495|1.603060|1.586918|1.728050|1.938052|13.325778|1.434540|1.811167|4.709323|0.093953|3.715588|4.923451|7.275364|5.698532|4.019496|12.819931|14.422206|36.858105|
|2.346026|2.701259|0.076103|2.457078|4.434304|2.972366|1.950997|1.775721|1.609799|1.577630|1.698335|1.898785|12.942320|1.426851|1.802536|4.507374|0.087025|3.499226|4.274299|6.268272|5.315239|4.004908|7.498048|9.359717|13.666509|36.858105|
|2.016722|2.285499|0.064799|2.119030|3.814664|2.620331|1.750362|1.615508|1.481824|1.454722|1.552132|1.709412|11.907365|1.329656|1.691476|3.662638|0.071383|2.799077|3.267959|4.311891|3.927882|3.179424|5.019486|7.121094|7.911489|13.806441|36.858105|
|1.821425|2.031596|0.056831|1.913089|3.486493|2.372872|1.605577|1.483729|1.374534|1.361142|1.454367|1.587118|11.311634|1.253913|1.603295|3.225692|0.064194|2.461642|2.891440|3.628787|3.332485|2.715976|4.464072|6.813881|6.845113|7.947493|13.746278|36.858105|
|1.849288|2.047529|0.056305|1.936763|3.582647|2.376205|1.609876|1.475232|1.368574|1.365281|1.470823|1.607484|11.548676|1.257526|1.607403|3.292828|0.066732|2.531214|3.067168|3.791632|3.413852|2.715732|5.093421|8.179665|7.909283|6.868274|7.913861|13.645704|36.858105|
|2.093152|2.330675|0.063265|2.185018|4.081528|2.629883|1.762229|1.594605|1.467832|1.465691|1.593781|1.762287|12.488017|1.339105|1.702189|3.866345|0.078969|3.013084|3.850288|4.925000|4.213284|3.179178|7.745214|12.250638|13.662514|7.931039|6.879341|7.943616|13.843534|36.858105|
|1.664090|1.817075|0.049725|1.739082|3.231221|2.150227|1.473287|1.356108|1.269064|1.273148|1.369307|1.482152|10.865545|1.181837|1.518576|2.871971|0.058835|2.196679|2.614029|3.069674|2.823182|2.316499|3.960722|6.835208|5.241693|4.618011|5.220967|7.963436|14.094095|8.098659|73.516695|
|1.510245|1.638385|0.045224|1.568666|2.886694|1.963472|1.352044|1.256943|1.181473|1.181822|1.260431|1.354566|9.986580|1.103273|1.423625|2.542462|0.051682|1.942254|2.251262|2.598862|2.413435|2.043407|3.167643|5.406206|4.040288|3.892015|4.683746|7.071377|8.194090|5.321207|24.032141|36.858105|
|1.497301|1.640247|0.045719|1.576234|2.882489|1.988138|1.372193|1.282105|1.206125|1.202892|1.276982|1.369348|10.070961|1.123767|1.450632|2.526748|0.050970|1.903266|2.166715|2.542978|2.422120|2.068425|2.995538|4.953665|3.866211|4.032540|5.284188|8.153986|7.037703|4.673042|14.193690|12.595037|36.858105|
|1.625905|1.797163|0.050521|1.706995|3.096640|2.147413|1.467963|1.370497|1.279518|1.267265|1.343944|1.451738|10.485414|1.176505|1.512417|2.788087|0.055530|2.110722|2.408300|2.905825|2.736905|2.320321|3.396723|5.384973|4.619660|5.278605|8.122940|14.206165|7.975859|5.244180|12.119338|7.955300|13.466600|73.516695|
|17.579681|8.758801|0.172746|6.885879|10.979437|7.182030|4.038164|3.326893|2.758755|2.631434|2.950084|3.686953|20.688196|2.211128|2.668500|9.323819|0.194796|6.179496|4.425149|3.524774|3.660116|4.499004|2.873833|5.102980|2.388232|2.275059|1.957341|1.790323|1.842181|2.099306|2.968035|1.507300|1.481822|2.837427|0.500000|
|17.594864|8.894754|0.210205|7.107110|9.539632|9.032983|4.753436|4.078705|3.215843|2.907982|3.133073|3.917171|20.829118|2.401942|2.871960|7.507017|0.141917|4.785524|3.509425|3.029277|3.218565|4.125717|2.478846|4.283260|2.141942|2.106161|1.841512|1.671534|1.687619|1.884244|2.720294|1.400048|1.394459|2.680910|0.302664|0.500000|
|17.624921|8.735049|0.213891|5.506370|8.119810|6.343488|3.521973|3.085984|2.545022|2.353976|2.536462|3.074065|17.635779|2.003977|2.440902|8.981264|0.156040|6.942986|4.515502|3.640428|3.617591|4.579027|2.875790|4.927790|2.431444|2.381585|2.044988|1.838979|1.860165|2.102487|2.968374|1.521079|1.504666|2.917986|0.299261|0.303425|0.500000|
|6.140195|7.613020|0.227407|9.519797|10.862777|26.026954|9.326525|7.699153|4.951367|4.086573|4.299773|5.754094|25.610076|3.138435|3.610864|6.728207|0.127073|3.788482|3.016262|2.887299|3.349547|4.514870|2.380998|4.014162|2.126771|2.146364|1.899811|1.710043|1.697903|1.867441|2.726794|1.409534|1.431617|2.761668|0.139295|0.199785|0.137131|0.500000|
|3.669229|4.019871|0.117714|4.842527|7.075160|9.989792|8.866732|17.712869|8.971549|5.643388|4.962290|5.624918|27.481128|4.173410|4.656892|4.293730|0.084604|2.621504|2.236354|2.192853|2.498778|3.069485|1.896413|3.225294|1.746854|1.774831|1.616745|1.476154|1.458136|1.571334|2.376121|1.243897|1.271663|2.428169|0.091363|0.117975|0.089171|0.235839|0.500000|
|2.595215|2.759071|0.077710|3.291599|5.371898|5.742432|5.655933|8.955250|17.749719|8.933732|5.661792|4.948012|31.573778|7.227303|7.619743|3.203394|0.065201|2.020022|1.801494|1.783001|2.012635|2.328057|1.597512|2.752763|1.493723|1.508587|1.399254|1.299696|1.288588|1.372798|2.130164|1.122100|1.148175|2.163694|0.068335|0.080060|0.064635|0.117012|0.216551|0.500000|
|3.863116|4.440078|0.107891|6.875868|15.045837|9.497538|8.878772|5.627796|4.955605|5.641409|8.966579|17.846008|54.830735|4.140950|4.587721|5.380808|0.123062|3.065123|2.746881|2.655273|3.191935|3.716465|2.348017|4.148512|2.081093|2.009605|1.793983|1.671042|1.708873|1.892439|2.799040|1.426997|1.434406|2.698254|0.110620|0.109117|0.088266|0.142929|0.123607|0.107612|0.500000|
|7.541027|6.962150|0.159556|4.818289|8.212542|5.103746|2.986096|2.561483|2.188030|2.101679|2.321732|2.788447|16.881406|1.817393|2.233793|12.328526|0.221370|17.686004|8.869113|5.494005|4.897418|5.615323|4.093716|7.137715|3.183202|2.971522|2.449238|2.201269|2.281598|2.684888|3.589400|1.796955|1.747879|3.401698|0.216564|0.147222|0.235930|0.102136|0.071420|0.055396|0.083893|0.500000|
|6.025011|6.845862|0.190297|4.525704|7.304970|5.018235|2.906575|2.553787|2.166576|2.045142|2.217186|2.641109|15.907211|1.771693|2.181451|12.390353|0.180855|17.597044|8.737134|6.719154|5.746270|7.058090|4.460834|7.063695|3.586665|3.544294|2.853368|2.463591|2.475759|2.887374|3.800301|1.915524|1.894962|3.778587|0.146381|0.128920|0.195107|0.104551|0.072806|0.055386|0.077476|0.301159|0.500000|
|4.180123|4.590274|0.110560|3.911119|7.534391|4.190196|2.610153|2.230660|1.966593|1.948431|2.188967|2.577801|16.621533|1.711482|2.121452|9.353885|0.209705|8.863804|17.589274|8.855462|6.810635|5.707852|7.111697|13.978644|4.581491|3.813968|3.001756|2.744679|2.990196|3.788199|4.626166|2.218189|2.110854|4.089713|0.124377|0.094165|0.115275|0.080624|0.060651|0.049742|0.079943|0.216650|0.172715|0.500000|
|3.881188|4.090644|0.105623|3.300047|5.932848|3.711802|2.307849|2.033979|1.794300|1.748394|1.915716|2.219587|14.388831|1.549063|1.932815|7.606082|0.145315|8.988725|17.579508|8.800131|5.519143|4.911066|6.798646|11.611899|4.716046|4.105311|3.198739|2.859537|3.043410|3.788812|4.643641|2.266432|2.154070|4.253872|0.109261|0.088492|0.116175|0.074188|0.056516|0.046056|0.066673|0.215432|0.213214|0.305075|0.500000|
|3.448147|4.107487|0.115228|3.384926|5.946201|3.891027|2.415442|2.147185|1.885490|1.820816|1.978564|2.290706|14.674140|1.608991|2.003975|7.697198|0.135862|6.791779|8.893626|17.564773|8.861697|6.804950|8.808547|10.683457|6.906659|7.028136|4.717219|3.762226|3.739892|4.623019|5.320980|2.595263|2.579606|5.373717|0.090938|0.081654|0.099569|0.078549|0.060092|0.048508|0.067838|0.139645|0.198105|0.174391|0.215557|0.500000|
|3.633396|4.643785|0.116753|4.484972|9.076066|4.796180|3.034641|2.542998|2.239900|2.240985|2.559136|3.049806|19.383595|1.948090|2.394991|9.343168|0.211381|5.688391|6.813217|8.815479|17.535618|8.879720|7.108528|11.332247|5.219692|4.546006|3.522080|3.136784|3.326830|4.149067|5.011855|2.380869|2.359540|4.621561|0.101627|0.086530|0.094193|0.089495|0.067953|0.055973|0.095913|0.127934|0.132294|0.199130|0.139279|0.173799|0.500000|
|3.218928|4.147355|0.114637|3.872345|7.139262|4.432913|2.814450|2.446711|2.156164|2.115156|2.342443|2.734082|17.442825|1.853225|2.290997|7.585337|0.145944|4.889107|5.514923|8.744398|17.583222|8.988933|6.801506|9.232758|6.068253|6.172529|4.545866|3.733677|3.700774|4.437763|5.335692|2.573321|2.646968|5.408038|0.085722|0.078671|0.086113|0.086051|0.066818|0.054683|0.082176|0.107811|0.128865|0.139179|0.123090|0.214190|0.303815|0.500000|
|4.719859|6.991200|0.223852|5.375395|8.530339|6.032610|3.457476|2.998219|2.506515|2.353296|2.561576|3.097522|18.024487|2.009430|2.450292|12.413870|0.182114|7.106780|5.813802|6.787681|8.784268|17.600976|4.493706|6.700776|3.872047|4.087458|3.267730|2.724305|2.653515|3.040970|4.003229|2.015667|2.060704|4.166707|0.114181|0.111891|0.127953|0.123774|0.084967|0.063404|0.090147|0.144925|0.215648|0.133277|0.130164|0.200333|0.173186|0.213682|0.500000|
|4.631541|7.298011|0.197641|7.370246|12.648510|7.643310|4.384243|3.549901|2.941602|2.824542|3.200870|4.044166|22.313463|2.354647|2.825962|12.330769|0.224042|5.618173|4.909114|5.487770|8.835833|17.657216|4.092788|6.471309|3.505321|3.515033|2.904270|2.522411|2.513984|2.880823|3.870499|1.933734|1.974076|3.895189|0.117839|0.112758|0.114222|0.141502|0.095923|0.072184|0.121946|0.126441|0.144588|0.127879|0.108036|0.139622|0.215609|0.214857|0.300473|0.500000|
|2.570873|3.014286|0.086676|2.682114|4.748052|3.241598|2.095919|1.908366|1.711815|1.660959|1.782178|2.009361|13.385122|1.491543|1.875992|5.052873|0.094382|3.921855|4.619019|7.026112|5.994852|4.662798|6.804026|8.495590|8.824909|17.745769|9.033423|5.676549|4.952276|5.623258|6.514925|3.211970|3.362724|7.606198|0.068063|0.063842|0.072936|0.065625|0.053389|0.044537|0.058731|0.090104|0.114114|0.109520|0.121167|0.252423|0.132052|0.196773|0.139090|0.110606|0.500000|
|1.940380|2.197883|0.063231|2.038692|3.625100|2.556342|1.712220|1.596368|1.466018|1.430814|1.513718|1.659758|11.545291|1.310817|1.670298|3.445299|0.066473|2.609658|2.936475|3.761920|3.531568|2.998368|4.069305|5.922962|5.620043|8.879090|17.744256|8.993136|5.652675|4.957795|7.514934|4.071016|4.838113|13.284778|0.051840|0.049645|0.054793|0.051915|0.044647|0.038654|0.047940|0.063712|0.075218|0.074461|0.079933|0.117147|0.087231|0.113945|0.087681|0.076992|0.216468|0.500000|
|2.069895|2.275166|0.060876|2.150038|4.067240|2.575986|1.734280|1.562837|1.443635|1.450831|1.585854|1.750566|12.545105|1.328061|1.689928|3.770996|0.078615|2.947020|3.807456|4.565470|3.930471|3.005168|7.203356|13.801120|8.881401|5.638513|4.959048|5.660876|9.007050|17.764472|13.200318|4.853914|4.056101|7.528143|0.058472|0.051707|0.057525|0.050497|0.042563|0.037432|0.052576|0.074321|0.076867|0.108646|0.104684|0.114264|0.112410|0.110361|0.078404|0.076145|0.123467|0.107672|0.500000|
|1.416657|1.528026|0.042024|1.474773|2.723668|1.852699|1.284524|1.196271|1.130457|1.135468|1.210596|1.293672|9.658060|1.064962|1.378508|2.352618|0.048143|1.787018|2.053709|2.326035|2.187927|1.873174|2.797349|4.889062|3.406510|3.236118|3.736277|5.127845|5.940979|4.377390|16.879800|17.646934|8.842338|10.147478|0.039441|0.036631|0.039509|0.036868|0.032801|0.029857|0.037860|0.046330|0.048722|0.056835|0.057331|0.063891|0.060712|0.064285|0.051054|0.049645|0.076274|0.092694|0.117687|0.500000|
|1.497022|1.611884|0.044603|1.528954|2.796589|1.915122|1.313567|1.224228|1.148395|1.144237|1.216805|1.309297|9.599981|1.067686|1.377812|2.495294|0.050426|1.933089|2.239433|2.555405|2.323610|1.986891|3.086625|5.259179|3.890490|3.791227|4.526504|6.439571|7.044832|4.942497|16.536865|17.555501|8.874587|12.707580|0.041445|0.038527|0.042184|0.038364|0.033783|0.030354|0.038222|0.049856|0.053329|0.060795|0.063626|0.071823|0.063046|0.068052|0.054890|0.051826|0.087949|0.110997|0.125541|0.299889|0.500000|
|1.491241|1.642638|0.045677|1.596335|2.935473|2.016565|1.400137|1.306623|1.233446|1.235604|1.314360|1.405194|10.417739|1.156268|1.493608|2.526186|0.051274|1.874658|2.123694|2.498263|2.442278|2.081321|2.928432|4.872478|3.716849|3.828243|4.838238|6.920434|6.338927|4.459087|12.767083|8.879527|17.570831|16.548893|0.041057|0.038664|0.041331|0.040158|0.035852|0.032575|0.040942|0.047801|0.051517|0.057958|0.057875|0.069482|0.066857|0.074840|0.057124|0.055808|0.089636|0.123537|0.109474|0.213523|0.173753|0.500000|
|1.395196|1.518717|0.042494|1.460021|2.656005|1.855478|1.285158|1.208698|1.140843|1.135829|1.199140|1.279636|9.452312|1.065488|1.379681|2.312134|0.046510|1.742549|1.955815|2.258063|2.156030|1.878828|2.592690|4.312442|3.231188|3.417746|4.379322|5.953698|5.126754|3.741859|10.163574|8.824491|17.648607|16.872270|0.038282|0.036284|0.039036|0.037259|0.033388|0.030293|0.037049|0.044731|0.048481|0.052811|0.054291|0.064133|0.058185|0.065007|0.052353|0.049999|0.081991|0.118119|0.092621|0.208102|0.213149|0.299861|0.500000|
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