Version2.4 2021-05-26T17:33:01Z 10.1021/jm300687e Gaussian16 RevisionB.01 PWARBURT 13-Jan-2021 #N HF/6-31G(d) OPT=(MaxStep=1) FREQ IOp(6/10=2,6/11=2,6/12=2) DUDE C[C@@H](c1ccc(cc1)F)NC(=O)COc2ccc(cc2C(=O)[O-])S(=O)(=O)N3CCOCC3 C13086986 RHF 6-31G(d) (6D,7F) C[C@@H](c1ccc(cc1)F)NC(=O)COc2ccc(cc2C(=O)[O-])S(=O)(=O)N3CCOCC3 C01[X(C21H22F1N2O7S1)] 156 C1 528 O=C(N[C@H](c1ccc(cc1)F)C)COc1ccc(cc1C(=O)[O-])S(=O)(=O)N1CCOCC1 O=C(N[C@H](c1ccc(cc1)F)C)COc1ccc(cc1C(=O)[O-])S(=O)(=O)N1CCOCC1 C[C@H](NC(=O)COc1ccc(cc1C([O-])=O)[S](=O)(=O)N2CCOCC2)c3ccc(F)cc3 InChIKey=XINNWZQVXBHLTR-AWEZNQCLSA-M InChI=1S/C21H23FN2O7S/c1-14(15-2-4-16(22)5-3-15)23-20(25)13-31-19-7-6-17(12-18(19)21(26)27)32(28,29)24-8-10-30-11-9-24/h2-7,12,14H,8-11,13H2,1H3,(H,23,25)(H,26,27)/p-1/t14-/m0/s1 InChI=1/C21H23FN2O7S/c1-14(15-2-4-16(22)5-3-15)23-20(25)13-31-19-7-6-17(12-18(19)21(26)27)32(28,29)24-8-10-30-11-9-24/h2-7,12,14H,8-11,13H2,1H3,(H,23,25)(H,26,27)/p-1/t14-/m0/s1/fC21H22FN2O7S/h23H/q-1 C[C@@H](c1ccc(cc1)F)NC(=O)COc2ccc(cc2C(=O)[O-])S(=O)(=O)N3CCOCC3 C01[X(C21H22F1N2O7S1)] 156 C01 528 O=C(N[C@H](c1ccc(cc1)F)C)COc1ccc(cc1C(=O)[O-])S(=O)(=O)N1CCOCC1 O=[C]([NH][C@H]([C]1[CH][CH][C]([CH][CH]1)F)C)CO[C]1[CH][CH][C]([CH][C]1[C]([O])=O)[S@]([O])(=O)N1CCOCC1 C[C@H](NC(=O)CO[C]1[CH][CH][C]([CH][C]1C([O])=O)[S]([O])(=O)N2CCOCC2)[C]3[CH][CH][C](F)[CH][CH]3 InChIKey=FUVUIRHYTNHWET-AWEZNQCLSA-N InChI=1S/C21H22FN2O7S/c1-14(15-2-4-16(22)5-3-15)23-20(25)13-31-19-7-6-17(12-18(19)21(26)27)32(28,29)24-8-10-30-11-9-24/h2-7,12,14H,8-11,13H2,1H3,(H,23,25)/t14-/m0/s1 InChI=1/C21H22FN2O7S/c1-14(15-2-4-16(22)5-3-15)23-20(25)13-31-19-7-6-17(12-18(19)21(26)27)32(28,29)24-8-10-30-11-9-24/h2-7,12,14H,8-11,13H2,1H3,(H,23,25)/t14-/m0/s1/f/h23H 3435.6332115346 -1937.9264011 1-A 21855.4635 122 406 528 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0.6152 0.6064 0.5573 0.3969 0.3076 0.3290 0.3245 0.3477 298.150 1.00000 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 6 6 1 6 6 6 6 6 6 9 7 6 8 6 8 6 6 6 6 6 6 6 8 8 16 8 8 7 6 6 8 6 6 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 12.00000 12.00000 1.00783 12.00000 12.00000 12.00000 12.00000 12.00000 12.00000 18.99840 14.00307 12.00000 15.99491 12.00000 15.99491 12.00000 12.00000 12.00000 12.00000 12.00000 12.00000 12.00000 15.99491 15.99491 31.97207 15.99491 15.99491 14.00307 12.00000 12.00000 15.99491 12.00000 12.00000 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 7148.9841 35549.6611 38249.5289 0.99988 0.01418 0.00656 -0.01420 0.99989 0.00294 -0.00652 -0.00304 0.99997 1 0.01212 0.00244 0.00226 0.25245 0.05077 0.04718 15.62 24.24 32.83 44.61 55.02 70.27 77.66 87.43 95.28 123.88 138.88 165.62 186.33 206.97 229.03 262.46 272.45 306.92 307.72 347.20 370.22 386.77 401.17 423.79 429.47 460.60 482.93 511.68 519.99 565.88 599.98 610.43 632.94 653.18 666.58 674.70 696.04 706.70 739.59 759.29 770.09 804.83 866.83 877.77 885.19 897.06 915.31 960.86 1000.32 1007.53 1040.25 1083.86 1128.94 1138.33 1156.68 1165.35 1197.61 1223.10 1285.23 1303.02 1305.16 1332.50 1358.83 1366.55 1372.27 1389.68 1401.15 1441.71 1459.69 1518.61 1522.87 1532.87 1559.45 1585.00 1602.54 1614.76 1625.09 1645.10 1665.21 1693.52 1705.89 1711.57 1724.29 1733.50 1753.55 1762.96 1774.88 1795.22 1815.77 1826.80 1849.73 1855.66 1875.65 1879.23 1895.33 1927.34 1956.21 1971.04 1977.87 1985.49 2009.46 2039.57 2088.31 2091.25 2094.10 2098.99 2116.58 2117.69 2166.12 2167.71 2179.49 2220.53 2224.12 2237.97 2244.85 2245.99 2279.35 2282.76 2353.59 2357.37 2360.15 2363.85 2371.65 2377.97 2380.22 2394.88 2444.22 2523.29 2562.33 2571.25 2584.16 2618.54 2751.07 2794.47 4585.51 4594.79 4603.97 4609.39 4618.29 4662.63 4696.95 4706.49 4719.94 4726.95 4734.93 4740.05 4783.92 4796.79 4821.88 4846.07 4861.85 4872.94 4883.25 4909.58 4943.99 5306.61 0.452160 0.479442 0.480386 0.389572 -1937.474241 -1937.446959 -1937.446015 -1937.536829 3.045916D-04 MUNgauss RevisionA2.1 retrievium 26-May-2021 DUDE C[C@@H](c1ccc(cc1)F)NC(=O)COc2ccc(cc2C(=O)[O-])S(=O)(=O)N3CCOCC3 C13086986 RHF 6-31G(d) (6D,10F) C1 465.113176 |X|Y|Z| 36.910476 52.650689 133.120173 63.718547 24 6 7 8 16 19 2 2 1 |36.858105| |12.437213|36.858105| |8.889663|17.617223|0.500000| |7.558665|12.475228|0.249099|36.858105| |5.641587|7.550227|0.203562|13.727449|36.858105| |4.162033|4.997137|0.133084|7.868581|13.734866|36.858105| |3.796010|4.440202|0.111801|6.891847|8.033978|13.853827|36.858105| |4.213869|4.982768|0.117022|7.890945|6.895608|7.913105|13.827216|36.858105| |5.758644|7.469844|0.156578|13.666040|7.966058|6.853945|7.998651|13.749961|36.858105| |3.019770|3.384500|0.087522|4.643523|5.303182|8.152815|14.233916|8.134081|5.290121|97.533100| |7.872618|13.179850|0.259215|7.671294|5.176103|3.932651|3.759816|4.422856|6.449701|6.726520|53.358707| |5.211326|7.814854|0.206140|5.894944|4.518762|3.587023|3.423401|3.897161|5.174060|6.293237|19.381865|36.858105| |4.531335|6.740312|0.210514|5.511181|4.672445|3.697184|3.393538|3.659484|4.588560|6.287594|11.454107|15.781289|73.516695| |3.977704|5.049748|0.130415|4.273699|3.429765|2.922405|2.914421|3.367838|4.208215|5.567208|10.781467|12.519108|14.293799|36.858105| |4.024081|4.607963|0.116223|3.768689|3.029478|2.599051|2.606028|3.020914|3.754404|5.036647|9.597359|7.922973|9.834062|13.550175|73.516695| |3.284851|3.592944|0.090736|3.138539|2.588172|2.297807|2.355643|2.739422|3.266738|4.657042|6.683533|5.237293|7.261333|8.058747|24.961625|36.858105| |2.747009|2.950572|0.077194|2.598689|2.220632|1.993933|2.024956|2.293078|2.653149|4.071663|5.158212|4.136268|6.185703|5.850069|14.547774|13.669581|36.858105| |2.349193|2.477111|0.064851|2.247565|1.952396|1.787257|1.833381|2.066840|2.330559|3.745806|4.139211|3.233228|4.998950|4.247643|9.388597|7.899336|13.836000|36.858105| |2.297313|2.403011|0.061910|2.232610|1.932656|1.791257|1.868220|2.131444|2.376979|3.840664|3.961701|3.007414|4.629377|3.848767|8.234885|6.904021|8.011490|13.712655|36.858105| |2.585080|2.712843|0.068248|2.545934|2.159105|2.000276|2.116328|2.472750|2.785459|4.315883|4.538180|3.357977|5.028688|4.312385|9.277471|8.011629|6.930000|7.910520|13.747502|36.858105| |3.148817|3.377467|0.083157|3.099421|2.543978|2.307733|2.432598|2.897381|3.400068|4.846611|5.997540|4.402224|6.239050|5.993470|13.974933|13.636031|7.841251|6.745950|7.848797|13.696903|36.858105| |3.566235|3.824909|0.090164|3.667240|2.912906|2.660058|2.889030|3.612676|4.313686|5.679667|6.651174|4.512006|6.333130|5.454228|11.056856|7.237695|4.888640|4.357283|5.000079|7.603816|12.276153|36.858105| |3.043834|3.208172|0.076949|3.216204|2.640496|2.490874|2.767304|3.452401|3.868597|5.588179|5.205360|3.582765|5.298918|4.155792|7.976925|5.227979|4.000874|3.847403|4.669898|7.061316|8.142852|15.603003|73.516695| |4.608448|5.045909|0.112417|4.734313|3.532681|3.121763|3.365489|4.337455|5.665605|6.375331|9.235709|5.630909|7.492677|6.182948|12.111837|6.475135|4.402882|3.736083|3.976284|5.301920|8.007110|15.382224|15.263634|73.516695| |1.911205|1.975416|0.051408|1.871661|1.655832|1.560319|1.632477|1.836163|1.993824|3.416142|3.132092|2.360272|3.749823|2.859103|5.764099|4.212605|4.757313|6.975555|10.801405|6.968078|4.712103|3.648743|6.563045|5.354095|388.023441| |1.880089|1.912545|0.049372|1.828933|1.618585|1.535218|1.618425|1.827134|1.968813|3.403676|2.986192|2.195912|3.483042|2.583473|5.198786|3.677429|3.855311|4.997723|7.300481|6.291369|4.333639|3.618189|6.825672|5.274611|94.698184|73.516695| |1.776289|1.827952|0.048195|1.716091|1.533910|1.441451|1.491145|1.654745|1.796259|3.125663|2.873866|2.181583|3.515687|2.608935|5.251284|3.693964|4.447934|6.547996|7.352295|4.937733|3.800208|2.998327|5.249885|4.600128|94.438018|13.622818|73.516695| |1.775855|1.866649|0.048834|1.803556|1.611280|1.536334|1.617701|1.811600|1.934520|3.417804|2.933353|2.247484|3.630027|2.715586|5.186226|3.648436|3.977909|5.246638|6.926689|5.525882|4.069935|3.334892|6.172446|4.932998|81.959198|13.744748|13.735019|53.358707| |1.804820|1.906978|0.049483|1.878544|1.676004|1.614806|1.724812|1.948069|2.054080|3.665558|2.978348|2.265420|3.654209|2.709423|5.050199|3.487477|3.534874|4.268199|5.659586|5.464975|4.110564|3.590089|7.025996|5.208127|50.669439|11.618763|8.870650|17.716534|36.858105| |1.607069|1.702637|0.044606|1.696176|1.537759|1.497967|1.599692|1.781113|1.845749|3.444161|2.612291|1.998385|3.289835|2.335885|4.237544|2.800260|2.851631|3.310880|3.975568|3.835516|3.157663|2.877517|5.588468|4.349044|34.363998|8.086440|7.015480|10.747762|12.535793|36.858105| |1.566623|1.676598|0.044350|1.665208|1.519075|1.476998|1.564758|1.726425|1.791701|3.366702|2.576615|2.007137|3.344368|2.359513|4.207112|2.746990|2.859166|3.288296|3.720621|3.478981|2.973506|2.667928|5.008848|4.116845|30.580310|6.702069|6.705176|9.312234|7.892611|13.591646|73.516695| |1.547441|1.648992|0.043871|1.613417|1.471529|1.417949|1.485913|1.632152|1.712786|3.177909|2.546331|1.993113|3.323377|2.360181|4.275575|2.815373|3.062084|3.648680|3.994680|3.486327|2.953644|2.559303|4.677790|3.978500|34.395575|7.014024|8.096128|10.752501|6.742862|8.179239|24.213791|36.858105| |1.718047|1.829284|0.048440|1.763297|1.587665|1.511690|1.578910|1.750272|1.868197|3.336678|2.877467|2.257319|3.702291|2.749205|5.118001|3.518323|3.985549|5.127604|5.719454|4.544706|3.672152|3.002455|5.379335|4.581520|50.808109|8.887635|11.619492|17.758584|7.824402|6.743407|14.037736|12.528877|36.858105| |17.552938|8.793607|0.173678|6.800698|4.952182|3.921013|3.798401|4.433489|6.104661|6.861250|9.652097|4.736971|7.082263|3.880834|7.216132|3.424870|2.812441|2.432052|2.426457|2.787823|3.411624|4.036325|6.125868|9.541131|14.326214|3.569472|3.290049|2.531056|1.903828|1.681729|2.883235|1.594398|1.774742|0.500000| |17.551152|8.788118|0.211365|6.959418|5.999317|4.440868|3.894704|4.096104|5.216577|7.011107|7.698641|4.211650|6.934406|3.303085|5.838818|2.769402|2.376396|2.071902|2.034789|2.265371|2.684463|3.023780|4.742623|6.667135|12.285755|3.036695|2.870014|2.202495|1.648781|1.484419|2.575043|1.427697|1.568833|0.301193|0.500000| |17.555634|8.811379|0.214791|5.502159|4.444705|3.426273|3.140456|3.431952|4.450600|5.816623|9.746923|5.046473|7.810965|3.956454|7.431843|3.368925|2.867912|2.428977|2.334508|2.582494|3.130205|3.387567|5.102244|7.535725|13.757898|3.364442|3.232290|2.418304|1.781002|1.581546|2.749091|1.542733|1.723758|0.300773|0.299726|0.500000| |5.474107|7.036520|0.223888|8.921640|17.694343|8.953272|5.695743|4.962040|5.653794|9.611506|6.529863|4.311345|8.300463|3.241513|5.127150|2.446621|2.135753|1.873529|1.832332|2.016423|2.357942|2.621781|4.211589|5.560887|11.203683|2.725712|2.621413|2.080554|1.574351|1.449190|2.558829|1.404782|1.515404|0.126081|0.168883|0.125540|0.500000| |3.530554|4.071965|0.113384|5.600962|8.835740|17.729162|8.961238|5.646466|4.943262|16.686571|4.486759|3.086931|5.776965|2.564381|4.084130|2.050037|1.809397|1.634210|1.632696|1.801611|2.048273|2.315250|3.889681|4.722869|10.225713|2.514511|2.377912|1.934065|1.488887|1.393111|2.451288|1.325935|1.404263|0.091785|0.106539|0.083544|0.213903|0.500000| |3.586570|4.057272|0.096647|5.614090|4.965256|5.648620|8.956067|17.734445|8.871641|16.647605|5.211980|3.448813|5.694262|3.144283|5.095379|2.682103|2.250960|2.061609|2.162878|2.533532|2.919358|3.714944|6.597395|7.616550|13.381980|3.360257|2.986578|2.547128|2.043106|1.872125|3.196225|1.681194|1.792632|0.107646|0.096039|0.083726|0.107705|0.124601|0.500000| |5.648420|6.892560|0.141528|8.862910|5.646751|4.940715|5.681075|8.954922|17.696237|9.598610|9.640552|5.484385|8.026548|4.744461|7.748545|3.831319|2.999391|2.620795|2.709909|3.273198|4.128173|5.661441|8.721223|14.542330|15.855809|3.927977|3.521409|2.917611|2.286987|2.018926|3.451663|1.853690|2.045650|0.179791|0.133543|0.125468|0.123964|0.107339|0.214872|0.500000| |7.169119|8.967987|0.179777|6.511174|4.466849|3.592360|3.597434|4.410942|6.407191|6.539286|25.761214|9.587920|10.913740|7.779299|14.289271|5.743075|4.157659|3.334320|3.261945|3.878048|5.385656|6.353013|8.282076|17.996717|17.966872|4.320651|4.053632|3.176773|2.382375|2.054797|3.557375|1.971502|2.249869|0.210639|0.143567|0.182183|0.112312|0.083884|0.110081|0.223884|0.500000| |3.382414|4.189782|0.114570|3.625433|3.066352|2.654646|2.617191|2.929801|3.506602|5.095902|7.922692|8.968345|13.580693|17.586615|16.497116|6.734723|5.789984|4.227219|3.672338|3.878886|4.957529|4.320353|6.216700|8.195366|19.811556|4.385116|4.625863|3.657399|2.633880|2.306287|4.234357|2.415614|2.808562|0.090173|0.080505|0.095044|0.082369|0.066050|0.076401|0.105546|0.152238|0.500000| |3.680735|4.646686|0.116631|4.295646|3.434526|3.014061|3.107253|3.690381|4.538232|5.958465|9.187003|8.988815|11.666261|17.591619|16.471905|7.521256|5.342265|4.155742|3.984541|4.673971|6.579266|6.403987|8.674814|12.414916|21.136526|4.803736|4.694474|3.943526|2.979411|2.557184|4.569832|2.515728|2.911374|0.102833|0.086445|0.098129|0.087601|0.072881|0.097775|0.146322|0.197356|0.299337|0.500000| |2.715719|2.928413|0.078483|2.535692|2.193328|1.954720|1.955071|2.179624|2.522128|3.928079|5.073957|4.183916|6.428216|5.731626|13.532390|8.971324|17.728210|8.913922|5.664873|4.983123|5.625587|4.008529|5.928861|6.797619|27.831668|5.753519|6.902355|4.609959|3.012686|2.526304|4.586972|2.787860|3.516395|0.075502|0.065537|0.080083|0.059445|0.049586|0.058743|0.077556|0.109104|0.170702|0.136006|0.500000| |2.116574|2.218306|0.058892|2.019008|1.781529|1.638502|1.671008|1.858559|2.072257|3.439804|3.621219|2.838245|4.508104|3.589022|7.585363|5.622680|8.912278|17.756818|8.891374|5.634132|4.888832|3.499194|5.650622|5.500542|47.219044|8.258010|13.519796|6.914409|3.926840|3.170964|5.724818|3.730428|5.271664|0.060317|0.052474|0.061118|0.047880|0.041971|0.051422|0.063688|0.079336|0.102417|0.096489|0.213331|0.500000| |2.450319|2.544001|0.063695|2.445970|2.087706|1.962445|2.104978|2.471517|2.728761|4.337054|4.131688|2.997387|4.554638|3.666439|7.499288|5.707859|4.986958|5.626128|8.872258|17.781015|9.054480|7.311739|14.734951|8.872207|46.869425|12.445087|8.030555|7.524883|6.069798|4.131889|6.312164|3.430328|4.274363|0.074294|0.060348|0.067130|0.053794|0.049151|0.071672|0.089180|0.097883|0.091625|0.112397|0.108134|0.123730|0.500000| |1.961845|2.102150|0.054250|2.080098|1.839607|1.769104|1.899642|2.168281|2.296667|4.012247|3.325259|2.551105|4.081557|3.112047|5.711542|3.989751|3.901525|4.541533|6.009623|6.332568|4.844700|4.223355|8.306716|5.982192|43.939789|9.804309|7.884288|12.268256|17.516749|8.876964|12.468122|5.841071|6.961665|0.057523|0.049476|0.053435|0.047699|0.045017|0.063322|0.071676|0.074251|0.083344|0.097757|0.090889|0.111237|0.192768|0.500000| |1.808082|1.885690|0.048620|1.862052|1.658141|1.601373|1.718452|1.948866|2.049465|3.659433|2.922540|2.180873|3.499745|2.564345|4.847678|3.326563|3.298646|3.931246|5.335762|5.453217|4.037347|3.649556|7.409629|5.247566|48.956305|13.837370|8.383599|12.446920|17.655425|8.878047|10.149674|5.043042|5.676225|0.053489|0.045961|0.049475|0.043154|0.040971|0.057142|0.063689|0.065503|0.068166|0.077946|0.078090|0.099794|0.184713|0.300144|0.500000| |1.601223|1.701130|0.044449|1.717105|1.561369|1.534435|1.653092|1.842999|1.886638|3.584608|2.589787|1.972910|3.257757|2.278093|4.073843|2.645943|2.623052|2.945859|3.497688|3.547415|3.015134|2.857616|5.668743|4.339611|28.318538|6.956051|5.840127|7.722918|8.870370|17.609554|16.908115|5.883840|5.028894|0.046648|0.041238|0.043433|0.040666|0.039642|0.054346|0.057192|0.056535|0.062019|0.070071|0.064896|0.077361|0.108283|0.217294|0.209566|0.500000| |1.501881|1.575237|0.041378|1.564743|1.425864|1.390253|1.479326|1.636756|1.692911|3.196288|2.396395|1.819319|3.005381|2.098796|3.844905|2.519333|2.592735|3.028212|3.595716|3.405112|2.810348|2.572829|4.977856|3.935498|32.866728|8.075601|6.978051|9.603639|8.878754|17.506547|16.541155|7.277371|5.871405|0.043664|0.038704|0.041210|0.037475|0.036063|0.047693|0.051197|0.052259|0.057601|0.062887|0.064483|0.082273|0.102117|0.173993|0.217551|0.299846|0.500000| |1.503468|1.611918|0.043213|1.576968|1.447595|1.395206|1.454297|1.585338|1.661158|3.113833|2.481689|1.963771|3.313536|2.316562|4.131380|2.667271|2.918991|3.378579|3.519312|3.099814|2.724871|2.374742|4.278109|3.757396|28.345670|5.840555|6.962839|7.723888|5.026448|5.880587|16.919265|17.598239|8.861357|0.042707|0.038631|0.041681|0.038547|0.036376|0.045120|0.049533|0.052815|0.066951|0.068183|0.075559|0.097261|0.083297|0.131054|0.110379|0.132276|0.147608|0.500000| |1.450941|1.530779|0.040767|1.496411|1.370409|1.322926|1.384281|1.514254|1.584417|2.971392|2.343228|1.815375|3.032350|2.117476|3.875292|2.531433|2.756376|3.294400|3.612001|3.144580|2.658147|2.329060|4.278069|3.643824|32.915549|6.971425|8.104379|9.614020|5.871395|7.274810|16.544924|17.503807|8.886648|0.041585|0.037340|0.040283|0.036433|0.034476|0.043341|0.047494|0.050396|0.059891|0.062056|0.070285|0.095234|0.087172|0.134199|0.132248|0.147589|0.217347|0.299923|0.500000| |1.666014|1.762071|0.046954|1.681241|1.519169|1.439863|1.491442|1.642484|1.760587|3.147491|2.764191|2.167809|3.571395|2.621336|4.948496|3.370352|3.987071|5.266195|5.416277|4.111458|3.390873|2.752285|4.844194|4.274998|49.118325|8.395474|13.859324|12.462604|5.674370|5.044144|10.157643|8.882108|17.648144|0.047584|0.042310|0.046838|0.040558|0.037276|0.046392|0.053282|0.059712|0.075165|0.075270|0.100295|0.164948|0.105209|0.142124|0.127530|0.110427|0.132287|0.209632|0.218030|0.500000| 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