Version2.4
2021-05-20T09:06:24Z
10.1021/jm300687e
Gaussian16
RevisionB.01
SBUNGAY
08-Jul-2020
#N HF/6-31G(d) OPT=(MaxStep=1) FREQ IOp(6/10=2,6/11=2,6/12=2)
DUDE C[C@H]1C(=c2cc(ccc2=[NH+]1)Br)CCNS(=O)(=O)c3cc(c(cc3OC)Cl)OC C63515515
RHF
6-31G(d)
(6D,7F)
C[C@H]1C(=c2cc(ccc2=[NH+]1)Br)CCNS(=O)(=O)c3cc(c(cc3OC)Cl)OC
C01[X(C19H21Br1Cl1N2O4S1)]
141
C1
485
COc1cc(Cl)c(cc1S(=O)(=O)NCCC1=c2cc(Br)ccc2=[NH+][C@H]1C)OC
COc1cc(Cl)c(cc1S(=O)(=O)NCCC1=c2cc(Br)ccc2=[NH+][C@H]1C)OC
COc1cc(c(OC)cc1Cl)[S](=O)(=O)NCCC2=C3C=C(Br)C=CC3=[NH+][C@H]2C
InChIKey=JXVZCOZCYKCYSZ-NSHDSACASA-O
InChI=1S/C19H20BrClN2O4S/c1-11-13(14-8-12(20)4-5-16(14)23-11)6-7-22-28(24,25)19-10-17(26-2)15(21)9-18(19)27-3/h4-5,8-11,22H,6-7H2,1-3H3/p+1/t11-/m0/s1
InChI=1/C19H20BrClN2O4S/c1-11-13(14-8-12(20)4-5-16(14)23-11)6-7-22-28(24,25)19-10-17(26-2)15(21)9-18(19)27-3/h4-5,8-11,22H,6-7H2,1-3H3/p+1/t11-/m0/s1/fC19H21BrClN2O4S/h23H/q+1
C[C@H]1C(=c2cc(ccc2=[NH+]1)Br)CCNS(=O)(=O)c3cc(c(cc3OC)Cl)OC
C01[X(C19H21Br1Cl1N2O4S1)]
141
C01
485
COc1cc(Cl)c(cc1S(=O)(=O)NCCC1=c2cc(Br)ccc2=[NH+][C@H]1C)OC
C[C@H]1C(=[C]2[C]([NH]1)[CH]=[CH][C](=[CH]2)Br)CCN[S@]([O])(=O)[C]1[CH][C]([C]([CH][C]1OC)Cl)OC
CO[C]1[CH][C]([C]([CH][C]1Cl)OC)[S]([O])(=O)NCCC2=C3C=C(Br)C=C[C]3N[C@H]2C
InChIKey=ABOMOJSULXXWJV-NSHDSACASA-N
InChI=1S/C19H21BrClN2O4S/c1-11-13(14-8-12(20)4-5-16(14)23-11)6-7-22-28(24,25)19-10-17(26-2)15(21)9-18(19)27-3/h4-5,8-11,23H,6-7H2,1-3H3,(H,22,24,25)/t11-/m0/s1
InChI=1/C19H21BrClN2O4S/c1-11-13(14-8-12(20)4-5-16(14)23-11)6-7-22-28(24,25)19-10-17(26-2)15(21)9-18(19)27-3/h4-5,8-11,23H,6-7H2,1-3H3,(H,22,24,25)/t11-/m0/s1/f/h22H
3526.7831522880
-4566.6311341
1-A
18501.8304
124
361
485
|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|
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7.16960
-16.7627 7.3164 -5.6040
19.1291
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-74.9437 -150.7764 -176.8264 -19.3482 24.5421 -2.0066
|XX|YY|ZZ|XY|XZ|YZ|
59.2384 -16.5942 -42.6442 -19.3482 24.5421 -2.0066
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-579.1408 -4.4225 -0.5940 -138.9262 114.0131 -10.0568 10.9189 -40.7182 -14.2481 44.1478
|XXXX|YYYY|ZZZZ|XXXY|XXXZ|YYYX|YYYZ|ZZZX|ZZZY|XXYY|XXZZ|YYZZ|XXYZ|YYXZ|ZZXY|
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1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86 87 88 89 90 91 92 93 94 95 96 97 98 99 100 101 102 103 104 105 106 107 108 109 110 111 112 113 114 115 116 117 118 119 120 121 122 123 124 125 126 127 128 129 130 131 132 133 134 135 136 137 138 139 140 141
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10.5797 15.3959 20.6763 39.6415 49.4569 60.3559 67.8819 83.6228 90.8086 95.7674 131.9226 141.3820 152.3757 170.4770 189.9989 193.2344 199.8999 208.2858 227.2184 259.8810 268.1716 277.0420 288.5405 294.0731 298.4407 304.8178 321.4226 327.2989 337.8961 341.3508 376.0769 425.8182 446.7994 464.2457 473.4971 498.2476 501.4731 514.3561 528.7157 552.0744 559.8741 568.1882 582.2385 616.7765 635.7427 650.3000 688.3951 705.8153 712.9884 751.3475 779.6619 794.6738 796.4777 807.0120 819.3349 847.5771 863.7491 912.5928 926.0965 937.8796 981.6762 991.6926 1031.4548 1051.6800 1054.5272 1059.3974 1093.2360 1116.2795 1130.0569 1160.6848 1166.7439 1170.8657 1183.7503 1188.5994 1199.6352 1210.1105 1226.5440 1229.6371 1262.8127 1269.9746 1277.9260 1290.1965 1292.5010 1330.6226 1331.5919 1341.5451 1368.1560 1382.2228 1394.2716 1414.3641 1431.3770 1437.9065 1448.9368 1455.9210 1466.9263 1468.8555 1498.4607 1533.4497 1534.7318 1557.3270 1565.6667 1585.7960 1610.2861 1621.9338 1630.9995 1634.8707 1636.5429 1638.2822 1642.3200 1649.7250 1651.6957 1654.6249 1655.4818 1659.9248 1688.2038 1727.4067 1758.1255 1759.8046 1811.9022 1838.3484 3214.6884 3216.6967 3227.5156 3232.4484 3252.2469 3259.4256 3284.4423 3302.0803 3308.8171 3310.4895 3322.2183 3338.4286 3351.8708 3358.3823 3401.9062 3408.0429 3416.6908 3434.7780 3448.9136 3816.6061 3866.6071
9.4669 6.3169 6.4532 8.0607 3.8185 4.4678 4.2534 4.2789 7.1478 4.8036 4.6232 4.8292 5.2884 4.0113 3.6372 4.1041 3.9581 4.8340 2.3790 1.2877 1.4367 4.9182 1.3727 6.8701 2.8179 4.2122 4.3348 4.3810 3.8193 2.7654 3.8110 4.1828 4.4725 4.8244 6.4250 3.0036 3.9461 6.0427 2.0877 4.8469 1.9888 6.5309 2.1705 4.0742 3.5399 4.7484 7.0090 5.1230 5.6875 8.0594 5.1102 3.8764 3.8881 4.4209 1.7348 3.8013 4.3423 3.3741 1.6369 3.0817 1.4803 3.3548 1.3857 4.4690 4.2904 2.1838 1.4155 1.9233 2.4487 1.3713 7.2343 2.9545 6.7964 2.8941 2.7286 3.2114 3.1530 4.0202 2.2625 4.2629 1.4234 1.2629 1.2636 1.4074 1.6347 1.4748 1.3138 3.1651 1.5247 1.2971 1.3381 2.4649 1.6385 1.9893 3.6359 1.7798 2.3607 2.3323 1.9115 2.9115 1.5738 1.6024 1.6435 1.4448 1.3049 1.1830 1.1431 1.0683 1.1318 1.0485 1.0470 1.3923 1.0660 1.0609 2.5060 6.3942 4.5038 9.3250 6.1177 6.3832 1.0837 1.0345 1.0322 1.0356 1.0633 1.0720 1.1083 1.1089 1.1038 1.1036 1.1051 1.1046 1.1022 1.0985 1.0911 1.0970 1.0983 1.0924 1.0915 1.0773 1.0817
0.0006 0.0009 0.0016 0.0075 0.0055 0.0096 0.0115 0.0176 0.0347 0.0260 0.0474 0.0569 0.0723 0.0687 0.0774 0.0903 0.0932 0.1236 0.0724 0.0512 0.0609 0.2224 0.0673 0.3500 0.1479 0.2306 0.2639 0.2765 0.2569 0.1899 0.3176 0.4469 0.5261 0.6126 0.8487 0.4393 0.5847 0.9419 0.3438 0.8704 0.3673 1.2422 0.4335 0.9132 0.8430 1.1831 1.9570 1.5037 1.7035 2.6806 1.8302 1.4423 1.4532 1.6964 0.6862 1.6089 1.9087 1.6556 0.8272 1.5971 0.8405 1.9439 0.8686 2.9123 2.8110 1.4440 0.9968 1.4120 1.8424 1.0885 5.8022 2.3865 5.6111 2.4090 2.3136 2.7707 2.7947 3.5814 2.1258 4.0508 1.3696 1.2386 1.2437 1.4682 1.7077 1.5639 1.4490 3.5628 1.7463 1.5288 1.6153 3.0027 2.0267 2.4844 4.6098 2.2624 3.1231 3.2312 2.6527 4.1604 2.2730 2.3742 2.5109 2.2393 2.0451 1.8629 1.8039 1.6893 1.7986 1.6812 1.6829 2.2459 1.7212 1.7223 4.2080 11.2415 8.2021 17.0148 11.8334 12.7099 6.5985 6.3065 6.3353 6.3752 6.6261 6.7100 7.0443 7.1238 7.1200 7.1261 7.1863 7.2535 7.2959 7.2997 7.4399 7.5071 7.5541 7.5931 7.6497 9.2461 9.5281
0.1402 0.8953 0.5992 0.4961 8.4158 1.6033 0.5581 0.3598 6.4597 2.1077 2.1582 2.2957 2.6108 0.3697 3.9708 5.9751 3.9819 2.6409 0.0836 0.2199 1.7556 1.0911 2.2436 1.7874 1.4361 0.7850 2.7058 0.8509 2.6689 22.5350 6.1703 16.4167 2.2596 10.9228 6.0603 32.5385 5.3137 4.1574 21.6755 23.6136 19.6876 48.4230 49.6395 23.4075 57.3491 16.1333 195.3298 22.9571 35.4860 11.7281 8.6488 26.5786 12.9526 6.0431 118.1856 0.4372 47.9858 116.2641 51.0733 30.2986 19.6809 18.9206 27.5893 106.7081 37.5316 34.9352 6.1410 38.3255 21.6359 1.4795 148.0608 16.5002 48.5172 167.9485 25.9397 31.1759 101.6371 258.2051 5.5727 59.2165 98.8847 2.8650 3.4312 2.1401 3.9621 0.3328 13.6851 338.8708 77.2111 14.9130 15.5860 148.6795 157.5876 26.6836 48.5198 13.2542 24.4275 272.5517 78.5986 90.2141 50.3218 4.1689 297.1868 4.7545 82.9646 1.0603 7.9496 16.0679 11.9940 7.0562 8.5611 96.1782 38.5440 30.6585 371.6958 5.7136 155.5800 68.9878 30.5396 331.4953 4.1321 41.9843 37.5294 11.7221 14.1873 23.4048 42.0844 28.0066 9.2404 3.6945 11.1704 36.0004 25.3761 5.2628 0.2227 56.4778 0.4716 0.8456 6.3219 69.0932 210.3688
3.0981 2.6650 1.6954 0.8361 0.0966 2.4220 0.4748 1.9782 0.8929 2.3533 0.3502 0.9286 1.3422 1.3306 0.8460 0.7377 1.3670 0.9021 1.7313 0.3019 1.6385 4.3517 0.0811 3.1819 0.7770 2.2715 0.6849 2.3034 4.3097 0.8719 1.9700 0.7344 1.9315 2.1841 1.7624 4.2821 0.4439 6.9362 1.1664 0.7452 1.2863 0.9946 1.3013 3.7720 3.0099 3.4885 4.6900 1.5065 9.5520 0.7031 19.5097 3.1156 2.8051 10.0892 2.7960 4.2278 0.7928 3.6287 2.6304 5.2802 1.5658 3.5611 0.4782 36.0051 25.8592 9.3014 6.6538 16.9251 23.7129 2.1325 1.9328 8.7645 4.2941 8.5460 9.3834 6.8210 8.6269 1.0946 12.0057 13.0196 6.9855 3.4319 3.9649 9.1342 12.5318 0.6821 19.2724 1.1963 99.6944 2.7537 8.2881 18.0966 74.5818 11.2896 46.8648 11.5450 46.8665 31.2131 36.9352 101.3116 20.9742 18.8550 145.0553 18.4296 0.4109 14.9989 36.0845 26.9413 3.1205 17.0584 22.4293 39.1826 7.5548 12.2951 0.8020 53.5713 9.6355 57.9384 62.6301 113.6595 123.1774 90.7743 92.9496 102.9599 106.6911 85.3168 38.0162 42.2899 71.2608 49.2068 58.5816 84.2495 140.3032 12.2747 66.6038 63.6556 176.4554 52.3567 46.0282 58.9466 112.8417
0.7440 0.7413 0.7467 0.7425 0.7494 0.7473 0.7302 0.7495 0.7350 0.7491 0.4719 0.6115 0.3372 0.5478 0.6065 0.7417 0.6835 0.7449 0.4143 0.4198 0.5795 0.1622 0.3545 0.5943 0.4925 0.5031 0.7175 0.6076 0.1003 0.4955 0.1733 0.7182 0.2884 0.0163 0.7240 0.6466 0.7005 0.5391 0.1657 0.7490 0.4779 0.3890 0.2695 0.6870 0.2494 0.4275 0.6225 0.4440 0.3202 0.0393 0.0885 0.2490 0.1618 0.4719 0.5237 0.4915 0.7414 0.2319 0.7408 0.5243 0.7486 0.1780 0.7072 0.1168 0.3606 0.5168 0.6343 0.4674 0.5147 0.7405 0.2122 0.3924 0.6885 0.6794 0.2918 0.1870 0.4961 0.2682 0.1490 0.1900 0.3241 0.7497 0.7494 0.4413 0.5140 0.1674 0.1106 0.3361 0.1886 0.3037 0.3871 0.3329 0.4827 0.3121 0.2634 0.3690 0.4129 0.3267 0.4147 0.2322 0.4453 0.7052 0.1932 0.1504 0.4952 0.6770 0.2739 0.5100 0.3876 0.7429 0.7500 0.2008 0.6985 0.7399 0.2498 0.5845 0.2803 0.3626 0.7406 0.3682 0.3477 0.0290 0.0103 0.0269 0.1153 0.2185 0.7485 0.7500 0.6985 0.6660 0.6527 0.5554 0.4701 0.6382 0.6450 0.2888 0.2047 0.2513 0.2255 0.2351 0.2980
0.8532 0.8514 0.8550 0.8522 0.8567 0.8554 0.8441 0.8568 0.8473 0.8566 0.6412 0.7589 0.5043 0.7078 0.7550 0.8517 0.8120 0.8538 0.5858 0.5913 0.7338 0.2792 0.5235 0.7455 0.6599 0.6694 0.8355 0.7559 0.1824 0.6626 0.2954 0.8360 0.4477 0.0320 0.8399 0.7854 0.8239 0.7006 0.2843 0.8565 0.6468 0.5601 0.4246 0.8145 0.3993 0.5990 0.7673 0.6150 0.4851 0.0756 0.1627 0.3987 0.2785 0.6412 0.6874 0.6591 0.8515 0.3764 0.8511 0.6879 0.8562 0.3022 0.8285 0.2092 0.5301 0.6814 0.7762 0.6370 0.6796 0.8509 0.3501 0.5636 0.8155 0.8091 0.4518 0.3151 0.6632 0.4230 0.2593 0.3194 0.4895 0.8570 0.8567 0.6124 0.6790 0.2868 0.1992 0.5032 0.3173 0.4659 0.5581 0.4995 0.6511 0.4757 0.4170 0.5390 0.5845 0.4925 0.5863 0.3768 0.6162 0.8271 0.3238 0.2614 0.6623 0.8074 0.4301 0.6755 0.5587 0.8525 0.8571 0.3345 0.8225 0.8505 0.3998 0.7378 0.4379 0.5322 0.8510 0.5383 0.5159 0.0563 0.0205 0.0525 0.2067 0.3586 0.8562 0.8571 0.8225 0.7996 0.7898 0.7142 0.6396 0.7792 0.7842 0.4481 0.3399 0.4016 0.3680 0.3807 0.4592
298.150
1.00000
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49
6 6 1 6 6 6 6 6 6 6 7 1 35 6 6 7 16 8 8 6 6 6 6 6 6 8 6 17 8 6 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1
12.00000 12.00000 1.00783 12.00000 12.00000 12.00000 12.00000 12.00000 12.00000 12.00000 14.00307 1.00783 78.91834 12.00000 12.00000 14.00307 31.97207 15.99491 15.99491 12.00000 12.00000 12.00000 12.00000 12.00000 12.00000 15.99491 12.00000 34.96885 15.99491 12.00000 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783
8958.3862 28562.4858 32884.5499
0.99959 -0.02593 0.01243 0.02549 0.99909 0.03426 -0.01331 -0.03393 0.99934
1
0.00967 0.00303 0.00263
0.20146 0.06319 0.05488
15.22 22.15 29.75 57.04 71.16 86.84 97.67 120.31 130.65 137.79 189.81 203.42 219.23 245.28 273.37 278.02 287.61 299.68 326.92 373.91 385.84 398.60 415.15 423.11 429.39 438.56 462.46 470.91 486.16 491.13 541.09 612.66 642.84 667.95 681.26 716.87 721.51 740.04 760.70 794.31 805.53 817.50 837.71 887.40 914.69 935.64 990.45 1015.51 1025.83 1081.02 1121.76 1143.36 1145.95 1161.11 1178.84 1219.47 1242.74 1313.02 1332.45 1349.40 1412.41 1426.82 1484.03 1513.13 1517.23 1524.24 1572.92 1606.08 1625.90 1669.97 1678.68 1684.61 1703.15 1710.13 1726.01 1741.08 1764.72 1769.17 1816.91 1827.21 1838.65 1856.31 1859.62 1914.47 1915.86 1930.18 1968.47 1988.71 2006.05 2034.95 2059.43 2068.83 2084.70 2094.75 2110.58 2113.36 2155.95 2206.29 2208.14 2240.65 2252.65 2281.61 2316.84 2333.60 2346.64 2352.21 2354.62 2357.12 2362.93 2373.59 2376.42 2380.64 2381.87 2388.26 2428.95 2485.35 2529.55 2531.97 2606.92 2644.97 4625.22 4628.11 4643.68 4650.77 4679.26 4689.59 4725.58 4750.96 4760.65 4763.06 4779.93 4803.25 4822.59 4831.96 4894.58 4903.41 4915.86 4941.88 4962.22 5491.24 5563.19
0.411068
0.437302
0.438247
0.350554
-4566.220066
-4566.193832
-4566.192888
-4566.280580
2.941204D-04
MUNgauss
RevisionA2.1
retrievium
20-May-2021
DUDE C[C@H]1C(=c2cc(ccc2=[NH+]1)Br)CCNS(=O)(=O)c3cc(c(cc3OC)Cl)OC C63515515
RHF
6-31G(d)
(6D,10F)
C1
487.009393
|X|Y|Z|
37.484857 59.019309 116.677121
63.671521
19
|36.858105|
|12.421534|36.858105|
|8.817447|17.508059|0.500000|
|7.438089|12.649265|0.249444|36.858105|
|5.470506|8.169430|0.175142|14.032331|36.858105|
|3.943609|5.064571|0.120496|7.443627|13.190037|36.858105|
|3.326665|4.100205|0.099976|5.153189|7.996013|14.210282|36.858105|
|3.365036|4.142616|0.100869|4.653461|6.899118|7.838520|13.164191|36.858105|
|4.048178|5.180075|0.122817|5.293254|7.674337|6.591698|7.720320|14.067873|36.858105|
|5.574686|8.324715|0.177450|8.422835|13.230137|7.619065|6.828204|8.075312|13.452514|36.858105|
|7.688889|13.096723|0.254015|8.277887|8.453282|5.285861|4.663091|5.257840|7.714525|14.502033|53.358707|
|6.720356|8.766424|0.204921|5.826249|5.924564|4.228913|3.954829|4.641936|6.811851|9.280697|26.006178|0.500000|
|2.535074|2.942546|0.074618|3.541674|4.582870|6.746445|10.117453|6.677506|4.592928|4.080512|4.344821|0.079228|2539.412838|
|5.822050|7.182989|0.179565|12.728266|7.456130|5.905750|4.191632|3.612007|3.813967|5.114922|6.906443|0.112921|109.242092|36.858105|
|4.227676|5.299878|0.152205|7.529659|5.765058|5.162095|3.845700|3.289860|3.378000|4.252510|5.644318|0.096143|105.595363|12.270491|36.858105|
|3.390799|3.872175|0.109709|5.010811|4.205533|4.112105|3.231864|2.752568|2.750745|3.275989|4.333721|0.076626|95.642817|7.614173|13.170442|53.358707|
|2.883264|3.213536|0.087396|4.166958|3.841130|4.147008|3.318352|2.723934|2.612793|2.988758|3.803036|0.067856|104.570075|5.677917|7.090746|15.741838|388.023441|
|2.735524|2.895186|0.077989|3.599672|3.272980|3.447559|2.843754|2.394783|2.318500|2.632162|3.415764|0.061819|90.949453|4.847485|5.229178|10.473779|94.728159|73.516695|
|3.030335|3.479889|0.091651|4.769271|4.740367|5.671437|4.321247|3.323536|3.080231|3.500762|4.244231|0.074485|135.784423|6.054035|6.846560|10.508544|94.390378|13.670301|73.516695|
|2.334478|2.598846|0.072467|3.169091|3.034215|3.304522|2.825158|2.373623|2.257052|2.493002|3.183399|0.058101|93.956444|3.888850|4.962529|9.507873|76.786093|13.138424|12.884975|36.858105|
|2.062161|2.232242|0.062060|2.640332|2.530226|2.729979|2.398824|2.054404|1.958210|2.134956|2.754619|0.050964|81.568490|3.176511|3.771154|6.872485|50.200840|11.973692|9.194894|13.710104|36.858105|
|1.814026|1.959955|0.054878|2.263062|2.197170|2.364354|2.134621|1.858088|1.769218|1.899139|2.457118|0.045972|73.907126|2.625767|3.082828|5.237367|33.828285|8.052035|6.953684|7.898856|13.770821|36.858105|
|1.771746|1.942910|0.054879|2.229915|2.191038|2.363672|2.159391|1.888722|1.793473|1.910264|2.462568|0.046192|75.136207|2.529558|3.031468|4.940012|30.076931|6.668811|6.541980|6.948630|8.020771|13.667643|36.858105|
|1.933490|2.167530|0.061603|2.517783|2.490142|2.702635|2.450529|2.124718|2.011859|2.150870|2.751088|0.051248|84.342296|2.842715|3.546859|5.676247|33.633054|6.837416|7.522340|8.004678|6.897386|7.856497|13.787933|36.858105|
|2.241060|2.551685|0.072237|3.067217|3.006050|3.287598|2.873045|2.431808|2.302141|2.510802|3.186717|0.058415|96.206890|3.576341|4.713994|7.910446|49.107600|8.750981|10.580429|13.703212|7.863451|6.753171|7.922516|13.735231|36.858105|
|2.485149|2.934800|0.083820|3.591365|3.567068|3.905116|3.357148|2.816934|2.668360|2.936842|3.681405|0.066716|108.403070|4.085435|5.730980|8.491131|45.733179|7.831276|11.268467|8.129552|5.252852|4.577191|5.210166|7.905078|14.189634|73.516695|
|2.277696|2.705351|0.078138|3.177963|3.252924|3.539806|3.210797|2.776756|2.622389|2.804135|3.508904|0.064587|105.483504|3.382634|4.438578|6.017285|31.106836|5.910940|8.047665|5.234713|3.969316|3.772478|4.535841|6.756171|8.009082|24.057258|36.858105|
|1.535190|1.668991|0.047263|1.870825|1.851762|1.981645|1.853570|1.654533|1.574860|1.653862|2.143962|0.040711|65.223013|2.067332|2.406892|3.747611|21.742338|5.011397|4.940468|4.263738|4.795157|7.045507|11.033104|7.115914|4.788601|6.659306|3.610036|448.794386|
|1.639590|1.744473|0.048730|1.980789|1.924164|2.055155|1.880361|1.658320|1.583963|1.688406|2.198227|0.041471|65.540628|2.269328|2.577679|4.257455|26.528089|6.744668|5.632325|5.200016|7.902237|14.249193|8.153338|5.267240|4.584099|6.160309|3.003482|52.961512|73.516695|
|1.628795|1.706455|0.047329|1.932251|1.864639|1.980900|1.807713|1.597986|1.531610|1.637019|2.140637|0.040431|62.757339|2.228316|2.460864|4.074084|25.565436|7.015063|5.398736|4.513707|6.727058|8.017884|5.237545|3.969314|3.767856|5.325031|2.583185|35.717937|24.100757|36.858105|
|17.608729|8.797584|0.212924|6.647854|4.719276|3.594174|2.999786|2.942602|3.390393|4.466208|7.606087|0.137915|80.378722|6.228458|4.486397|5.013337|21.676952|5.242185|5.500675|2.439876|2.165822|1.891655|1.830765|1.985347|2.307611|4.490609|2.279800|12.672487|3.042483|1.709874|0.500000|
|17.586835|8.837552|0.212160|5.477062|4.448541|3.352476|2.950321|3.080562|3.757042|4.882899|9.483865|0.195845|78.147674|4.451621|3.533110|3.961062|17.769652|4.233026|4.627734|2.086323|1.862643|1.661104|1.631992|1.774432|2.025394|3.976965|2.088785|11.494462|2.688585|1.500373|0.302616|0.500000|
|17.593761|8.783349|0.172824|6.799105|5.492979|4.079164|3.475099|3.512199|4.173558|5.575964|9.446800|0.169581|90.058263|5.387829|3.842634|4.328845|20.079592|4.834894|5.381246|2.270863|2.021854|1.775833|1.723819|1.868471|2.160322|4.216136|2.167890|12.005784|2.866630|1.612314|0.300096|0.300415|0.500000|
|3.601363|4.420196|0.108660|6.580438|8.690055|17.736074|8.999098|5.569653|4.805743|5.484636|5.832930|0.098037|217.857873|6.280350|5.735740|6.527104|37.018766|7.389307|14.451685|3.947329|3.183756|2.690706|2.659307|3.051422|3.827651|8.013631|3.867666|17.483522|4.098878|2.221283|0.095057|0.084814|0.102975|0.500000|
|2.866737|3.390773|0.084712|3.686774|4.968936|5.652005|8.809677|17.742983|9.078270|5.699198|5.710158|0.108374|223.884436|3.007424|2.799838|3.282910|17.199102|3.826660|5.161738|2.161350|1.897423|1.738459|1.774485|1.982056|2.226567|4.519767|2.550608|12.647895|2.780482|1.506309|0.070590|0.074489|0.083145|0.123896|0.500000|
|3.722656|4.524571|0.110915|4.290363|5.501092|4.807302|5.528923|8.967587|17.754534|8.744490|9.211983|0.192104|130.352937|3.231160|2.906382|3.287335|16.260048|3.660083|4.671711|2.011730|1.768557|1.614709|1.640301|1.826504|2.057447|4.189244|2.347060|11.708790|2.591709|1.411569|0.086546|0.100397|0.105991|0.105061|0.216735|0.500000|
|6.527756|6.903317|0.179044|8.932640|5.609621|4.503678|3.447235|3.098431|3.332692|4.367178|6.332328|0.107593|93.114464|17.585537|8.770251|9.091064|34.796573|8.115753|8.508186|3.494550|2.965832|2.472922|2.357809|2.594768|3.177144|6.223905|2.952322|15.665521|3.862159|2.160785|0.222930|0.136162|0.161054|0.129927|0.073315|0.081048|0.500000|
|4.920391|5.570542|0.135222|9.066933|6.900004|6.301659|4.389780|3.619813|3.661484|4.670338|5.966673|0.099734|117.633422|17.619158|8.836135|9.814956|46.124183|10.146370|13.251368|4.114676|3.386126|2.744538|2.593863|2.875758|3.634082|7.137434|3.266915|16.882497|4.220693|2.359072|0.143593|0.107106|0.137505|0.204400|0.084264|0.085724|0.302710|0.500000|
|3.807131|4.949568|0.140268|7.123235|6.345527|6.119802|4.475407|3.702898|3.696792|4.557339|5.707276|0.096806|121.504593|8.747381|17.691078|12.649162|48.026936|8.368392|13.453028|5.122318|3.766526|3.131225|3.171187|3.850350|5.244102|12.700936|5.484210|20.146873|4.598473|2.424525|0.106937|0.090240|0.098074|0.191951|0.086762|0.086792|0.173215|0.204223|0.500000|
|4.260485|5.365170|0.170044|6.561821|4.982087|4.277774|3.369748|3.020247|3.188184|4.003807|5.605183|0.097494|93.190666|8.742517|17.591166|12.658005|38.027818|7.604976|8.855811|4.257836|3.367769|2.849772|2.847234|3.319994|4.218020|9.060590|4.224949|18.562460|4.293263|2.295634|0.127481|0.101634|0.103090|0.124470|0.072261|0.077983|0.216932|0.173874|0.303355|0.500000|
|3.338601|3.639751|0.104042|4.447197|3.662984|3.496970|2.823249|2.464806|2.494799|2.959508|4.023055|0.072218|84.313894|6.644675|9.054386|25.932918|61.015799|13.570774|10.337763|5.914473|4.776281|3.686673|3.390905|3.726303|4.838887|8.685292|3.702379|21.085105|5.482326|3.020522|0.104054|0.080173|0.086522|0.109881|0.060582|0.061766|0.186421|0.173780|0.180165|0.220970|0.500000|
|2.076605|2.206603|0.060813|2.603052|2.470361|2.645060|2.316937|1.990884|1.905872|2.085282|2.705448|0.050106|78.416615|3.169806|3.604485|6.590710|48.821964|14.429632|8.808391|8.995216|17.807939|8.906837|5.672292|4.972457|5.643687|7.592683|3.327985|31.592660|12.542122|7.467200|0.061067|0.051949|0.056981|0.085599|0.051052|0.047891|0.083710|0.095723|0.097075|0.089037|0.133245|0.500000|
|1.845671|2.080868|0.059521|2.381091|2.380949|2.573915|2.377969|2.089672|1.978746|2.092395|2.676314|0.050184|82.211781|2.616604|3.235413|4.913670|27.635618|5.704648|6.483020|5.662828|4.971962|5.641374|9.025811|17.799222|8.876663|12.550322|7.509317|55.159249|7.615937|3.330433|0.052239|0.047448|0.049396|0.079040|0.054568|0.050222|0.066435|0.072534|0.098978|0.086034|0.090106|0.107972|0.500000|
|2.142170|2.510477|0.073690|2.860521|2.860732|3.009852|2.752096|2.450217|2.358995|2.525799|3.237044|0.060346|89.925007|3.055848|3.985530|5.506557|27.375561|5.415735|6.709828|4.705695|3.752703|3.702151|4.583073|6.741726|6.973380|16.415267|17.588120|30.428691|5.308701|2.541005|0.060017|0.055155|0.056212|0.089669|0.063035|0.059592|0.076193|0.080912|0.128871|0.110532|0.097733|0.087485|0.228227|0.500000|
|2.082844|2.439057|0.069327|2.848198|2.986242|3.350176|3.145227|2.707501|2.501013|2.605602|3.222782|0.059766|109.185395|2.988358|3.706845|5.091465|28.041435|5.490974|7.476841|4.811344|3.824989|3.759335|4.631583|6.783135|7.108063|16.426791|17.592954|30.502728|5.376859|2.577766|0.057575|0.053291|0.055789|0.101930|0.070341|0.062465|0.072884|0.082182|0.124214|0.096574|0.088810|0.089084|0.223098|0.298353|0.500000|
|2.463995|3.010060|0.087494|3.535480|3.694004|3.981722|3.620942|3.155000|2.992010|3.202566|3.962927|0.072512|114.353117|3.612622|4.714445|5.866800|28.983645|5.555124|7.843753|4.395181|3.397474|3.169523|3.631627|4.921430|5.887638|16.967540|17.656220|24.061205|4.623212|2.298474|0.067564|0.062799|0.064729|0.116928|0.079641|0.073838|0.086234|0.094824|0.170119|0.126257|0.099807|0.082026|0.146581|0.300183|0.300132|0.500000|
|1.667248|1.744476|0.047929|1.992922|1.937232|2.083007|1.901432|1.666574|1.585919|1.690773|2.194850|0.041334|66.734292|2.298215|2.498490|4.116775|26.937202|7.567146|5.796208|4.586121|6.730143|7.055669|4.768223|3.792674|3.729375|5.329187|2.565001|31.786038|16.426396|17.572427|0.048454|0.042472|0.046211|0.065474|0.043645|0.040454|0.061478|0.068748|0.068678|0.063745|0.083785|0.223425|0.088422|0.068707|0.071711|0.063873|0.500000|
|1.493809|1.556849|0.043220|1.741927|1.687356|1.785494|1.647209|1.470219|1.411326|1.498735|1.965714|0.037356|57.441270|1.980189|2.163091|3.492952|21.243840|5.766404|4.617849|3.619980|4.909794|5.899332|4.404419|3.402961|3.169617|4.617031|2.301414|33.298439|17.010928|17.671470|0.043448|0.038482|0.041120|0.054986|0.038732|0.036352|0.053631|0.057882|0.059319|0.056657|0.072152|0.145993|0.082223|0.063423|0.064225|0.057346|0.299861|0.500000|
|1.703003|1.772694|0.049329|2.002045|1.903368|1.994514|1.801938|1.598422|1.545674|1.667729|2.199255|0.041505|61.441046|2.342204|2.588946|4.371631|26.814352|7.648492|5.465602|4.571981|6.720688|7.022232|4.739801|3.772831|3.712674|5.311988|2.546040|31.619994|16.423798|17.570383|0.050131|0.043506|0.046646|0.061997|0.041633|0.039573|0.063911|0.068583|0.069494|0.067447|0.092543|0.224806|0.087997|0.069991|0.069158|0.063426|0.298360|0.299954|0.500000|
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