Version2.1 2020-12-14T03:24:23Z 10.1021/jm300687e Gaussian16 RevisionB.01 CFLINN 12-Nov-2020 #N HF/6-31G(d) OPT=(MaxStep=1) FREQ IOp(6/10=2,6/11=2,6/12=2) DUDE CC(C)[C@@H](c1[nH]c2ccccc2n1)NC(=O)CN3C(=O)[C@]4(CCCc5c4cccc5)NC3=O C09219585 RHF 6-31G(d) (6D,7F) CC(C)[C@@H](c1[nH]c2ccccc2n1)NC(=O)CN3C(=O)[C@]4(CCCc5c4cccc5)NC3=O C01[X(C25H27N5O3)] 174 C1 549 O=C(CN1C(=O)N[C@]2(C1=O)CCCc1c2cccc1)N[C@H](c1nc2c([nH]1)cccc2)C(C)C O=C(CN1C(=O)N[C@]2(C1=O)CCCc1c2cccc1)N[C@H](c1nc2c([nH]1)cccc2)C(C)C CC(C)[C@H](NC(=O)CN1C(=O)N[C@@]2(CCCc3ccccc23)C1=O)c4[nH]c5ccccc5n4 InChIKey=YXGJBMKVSNJEMJ-SQJMNOBHSA-N InChI=1S/C25H27N5O3/c1-15(2)21(22-26-18-11-5-6-12-19(18)27-22)28-20(31)14-30-23(32)25(29-24(30)33)13-7-9-16-8-3-4-10-17(16)25/h3-6,8,10-12,15,21H,7,9,13-14H2,1-2H3,(H,26,27)(H,28,31)(H,29,33)/t21-,25+/m0/s1 InChI=1/C25H27N5O3/c1-15(2)21(22-26-18-11-5-6-12-19(18)27-22)28-20(31)14-30-23(32)25(29-24(30)33)13-7-9-16-8-3-4-10-17(16)25/h3-6,8,10-12,15,21H,7,9,13-14H2,1-2H3,(H,26,27)(H,28,31)(H,29,33)/t21-,25+/m0/s1/f/h26,28-29H CC(C)[C@@H](c1[nH]c2ccccc2n1)NC(=O)CN3C(=O)[C@]4(CCCc5c4cccc5)NC3=O C01[X(C25H27N5O3)] 174 C01 549 O=C(CN1C(=O)N[C@]2(C1=O)CCCc1c2cccc1)N[C@H](c1nc2c([nH]1)cccc2)C(C)C O=C(N[C@H]([C]1[N][C]2[C]([CH][CH][CH][CH]2)N1)C(C)C)CN1C(=O)N[C@]2(C1=O)CCC[C]1[C]2[CH][CH][CH][CH]1 CC(C)[C@H](NC(=O)CN1C(=O)N[C@@]2(CCC[C]3[CH][CH][CH][CH][C]23)C1=O)[C]4[N][C]5[CH][CH][CH][CH][C]5N4 InChIKey=YXGJBMKVSNJEMJ-SQJMNOBHSA-N InChI=1S/C25H27N5O3/c1-15(2)21(22-26-18-11-5-6-12-19(18)27-22)28-20(31)14-30-23(32)25(29-24(30)33)13-7-9-16-8-3-4-10-17(16)25/h3-6,8,10-12,15,21H,7,9,13-14H2,1-2H3,(H,26,27)(H,28,31)(H,29,33)/t21-,25+/m0/s1 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-0.00601 0.00827 0.99995 1 0.00892 0.00393 0.00306 0.18589 0.08196 0.06386 18.40 29.95 32.88 62.86 64.66 76.57 88.82 100.03 112.86 130.92 137.81 168.78 206.62 236.54 268.69 287.32 307.99 339.08 378.96 380.31 393.05 407.64 410.65 422.09 458.01 471.87 478.04 508.50 515.95 542.43 593.26 601.86 621.33 638.20 684.05 700.39 719.02 753.31 764.57 783.31 841.53 855.16 876.61 890.35 922.17 928.35 934.39 965.84 977.89 989.91 1023.20 1073.97 1087.49 1129.71 1149.62 1180.21 1197.09 1209.51 1220.62 1230.20 1238.49 1243.17 1269.96 1293.53 1328.04 1359.03 1370.82 1392.79 1403.96 1422.85 1432.93 1457.24 1463.31 1487.08 1507.83 1528.51 1529.48 1544.19 1556.33 1581.11 1583.92 1591.04 1612.96 1613.20 1617.83 1642.27 1645.52 1691.15 1729.46 1762.36 1766.64 1769.87 1779.40 1788.06 1792.14 1832.08 1847.90 1861.79 1881.35 1895.36 1907.59 1914.97 1930.18 1946.56 1956.19 1977.34 1986.24 2015.58 2029.89 2053.99 2058.91 2061.08 2108.96 2121.29 2141.63 2170.65 2173.22 2190.06 2191.16 2199.58 2243.21 2244.70 2255.80 2266.40 2299.97 2311.50 2328.22 2341.24 2341.61 2341.99 2352.42 2356.49 2363.95 2375.54 2380.43 2384.35 2393.76 2402.22 2475.15 2507.18 2558.83 2572.62 2608.04 2630.55 2822.64 2831.10 2932.87 4594.57 4596.23 4607.37 4610.91 4649.55 4666.96 4675.81 4685.36 4688.68 4689.86 4699.66 4716.58 4724.14 4731.24 4734.47 4783.57 4823.95 4827.68 4831.52 4848.83 4854.63 4867.85 4877.74 4879.88 5542.66 5584.04 5615.41 0.532283 0.559282 0.560227 0.471867 -1458.852664 -1458.825665 -1458.824721 -1458.913081 2.963609D-04 MUNgauss RevisionA2.0 retrievium 14-Dec-2020 DUDE CC(C)[C@@H](c1[nH]c2ccccc2n1)NC(=O)CN3C(=O)[C@]4(CCCc5c4cccc5)NC3=O C09219585 RHF 6-31G(d) (6D,10F) C1 445.211390 |X|Y|Z| 105.460264 67.079285 33.983164 62.179472 27 6 7 22 5 |36.858105| |12.444401|36.858105| |7.544732|12.433276|36.858105| |7.541971|12.363765|7.424759|36.858105| |7.201216|8.894625|5.481303|17.619345|0.500000| |4.918156|7.484969|6.040328|12.575307|0.251877|36.858105| 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|2.806840|3.010796|2.802475|3.869213|0.107138|3.783459|6.201403|0.165861|3.672174|3.466374|2.775384|2.447116|2.513216|3.003883|4.152656|6.625939|6.437592|10.819965|7.754635|19.083062|36.858105| |2.905270|3.259329|3.054850|4.327212|0.116118|4.531808|8.163276|0.242399|4.678025|4.400307|3.341921|2.871551|2.939030|3.602416|4.858278|7.263060|6.391815|10.287392|6.706148|11.427096|15.931708|73.516695| |2.359954|2.471435|2.300394|3.037536|0.086418|2.996558|4.763724|0.118346|3.019508|2.969621|2.465376|2.175704|2.193541|2.533121|3.446555|4.853882|4.478216|8.226422|5.119890|11.103613|12.448550|13.852263|36.858105| |2.316714|2.430498|2.207629|3.005468|0.088426|3.019720|4.793299|0.116198|3.104347|3.074941|2.568167|2.265001|2.274638|2.611931|3.520036|4.536310|4.096595|8.144130|4.145022|7.665698|7.690222|11.268949|12.389224|36.858105| |1.967420|2.040610|1.876715|2.431050|0.071217|2.453686|3.800240|0.088280|2.567716|2.609073|2.260957|2.007112|1.987152|2.215375|2.957336|3.583867|3.102719|6.058700|3.179252|5.540490|4.962168|7.698854|7.552682|12.506581|36.858105| |1.793139|1.883319|1.768056|2.217756|0.063519|2.289684|3.597187|0.083034|2.498773|2.628114|2.296571|2.005419|1.945642|2.138138|2.796519|3.263783|2.735034|5.123475|2.856116|4.870010|4.439511|7.259549|6.357110|7.654307|12.490696|36.858105| |1.822210|1.921709|1.835266|2.260257|0.063447|2.326784|3.688009|0.086450|2.534577|2.665949|2.304450|2.001474|1.943712|2.149238|2.816409|3.415662|2.861282|5.166319|3.132628|5.484813|5.096039|8.152078|7.482992|6.634958|7.523789|12.557317|36.858105| |2.041157|2.153674|2.059965|2.570017|0.071554|2.604514|4.157679|0.100442|2.756604|2.823886|2.385196|2.079231|2.051209|2.315023|3.079051|4.024932|3.467134|6.124535|3.993949|7.568127|7.476088|10.790033|12.459781|7.470738|6.589982|7.475878|13.695043|36.858105| |1.994438|2.106247|2.064512|2.469710|0.067247|2.491895|3.938757|0.094205|2.617741|2.676279|2.279166|1.997697|1.972529|2.217180|2.958312|3.933752|3.304339|5.582573|4.003215|7.236065|6.386738|9.694949|7.547799|4.967214|4.457613|4.988882|7.915121|13.647157|36.858105| |1.762440|1.861758|1.848074|2.135643|0.057921|2.179919|3.408699|0.079172|2.337250|2.439285|2.129041|1.867575|1.820560|2.005669|2.647067|3.319515|2.693884|4.565192|3.156518|5.258053|4.418225|7.266040|5.008008|3.841971|3.716708|4.418413|6.815331|7.882129|13.834210|36.858105| |1.616179|1.706490|1.681509|1.948737|0.053385|2.010466|3.137802|0.071822|2.199267|2.337835|2.073067|1.812108|1.745421|1.896372|2.476135|2.953826|2.379640|4.125664|2.677963|4.389506|3.734146|6.282094|4.418285|3.714099|3.862483|5.022822|7.872788|6.843900|7.977266|13.713418|36.858105| |1.639391|1.729787|1.677772|1.994673|0.055396|2.065507|3.240402|0.074366|2.276084|2.430140|2.148386|1.869487|1.796635|1.953652|2.542261|2.989250|2.436305|4.325901|2.674526|4.460383|3.917693|6.545972|4.993317|4.470204|5.010234|7.588546|13.648288|7.946550|6.934194|7.962460|13.828380|36.858105| |2.362555|2.391674|2.224157|2.863907|0.082152|2.703794|4.091879|0.098441|2.584312|2.489436|2.117609|1.916441|1.957654|2.245695|3.130861|4.640504|4.388586|8.132278|5.326968|11.804235|8.330484|9.792527|13.056349|7.674455|5.994777|4.854520|5.460064|7.711666|6.166091|4.372099|3.805779|4.101000|53.358707| |2.693720|2.684598|2.498588|3.215498|0.091351|2.913196|4.304635|0.103697|2.642716|2.475231|2.100130|1.925566|1.999864|2.322364|3.316732|5.485267|5.470820|9.655277|7.605787|18.556446|8.325533|9.862592|8.075675|5.559483|4.324303|3.673558|4.099258|5.550110|5.187341|3.822018|3.236203|3.320582|19.195168|36.858105| |2.668710|2.577425|2.413216|2.977557|0.084615|2.638321|3.772299|0.088087|2.343376|2.184308|1.886684|1.756020|1.834372|2.110031|3.049286|5.026413|4.827204|8.469246|6.565240|11.288350|5.566023|7.501178|5.419163|4.226275|3.546359|3.063818|3.354376|4.241645|4.162366|3.285414|2.817665|2.843683|11.304696|16.004382|73.516695| |17.548296|8.746765|6.786396|6.759199|0.175952|4.454922|4.944187|0.099598|2.967390|2.461952|2.181102|2.207569|2.542271|3.042129|5.199625|9.256071|5.564394|8.802859|4.430381|4.628634|2.994878|5.400316|2.493344|2.393648|2.023695|1.840504|1.890415|2.144697|2.114879|1.855964|1.684248|1.698047|3.462070|2.979612|5.339960|0.500000| |17.550095|8.807825|6.933282|5.487171|0.145059|4.071583|4.389271|0.084753|2.781681|2.314592|2.113191|2.206267|2.589593|3.010353|5.234568|6.394485|3.883799|6.508384|3.204131|3.590363|2.429882|4.461184|2.083931|2.046568|1.769378|1.627155|1.653269|1.834101|1.804178|1.614735|1.487652|1.503154|2.848223|2.360052|4.198324|0.301874|0.500000| |17.547894|8.751880|5.478254|6.911203|0.218048|4.654050|4.976414|0.097336|3.048387|2.505731|2.244966|2.310519|2.704760|3.225913|5.656837|7.580969|4.848789|8.739370|3.669436|4.137403|2.795710|5.087285|2.389827|2.396170|2.037089|1.831727|1.835873|2.042922|1.965753|1.732533|1.601196|1.640574|3.269584|2.712786|4.774391|0.301542|0.301761|0.500000| |8.909480|17.589510|8.955494|9.043629|0.214648|7.216581|6.488537|0.114497|4.092671|3.155296|2.854053|3.073191|3.886821|4.842471|10.152562|7.680732|4.267148|7.177047|3.302995|3.790549|2.710357|5.245672|2.277832|2.286606|1.944362|1.800746|1.816741|2.004336|1.945711|1.737109|1.611384|1.642490|2.974641|2.398995|4.082169|0.173335|0.213372|0.213122|0.500000| |6.868189|8.724422|17.511949|6.572412|0.138405|5.199927|5.750010|0.111554|3.501049|2.858651|2.527398|2.572906|2.999217|3.633129|6.208923|9.286994|4.750952|6.881800|4.160023|4.369262|2.960422|5.655620|2.401771|2.252339|1.909340|1.800684|1.892842|2.151612|2.186949|1.948714|1.751159|1.731832|3.200307|2.694440|4.670394|0.202185|0.172361|0.139596|0.173606|0.500000| |5.477636|8.741019|17.579468|6.811585|0.139111|6.737551|6.889549|0.122250|4.409709|3.439569|3.078000|3.248871|3.997529|4.970922|9.046224|7.862619|4.101211|6.246958|3.490336|3.914042|2.808679|5.590346|2.300162|2.211435|1.881619|1.794056|1.867752|2.087076|2.097323|1.889157|1.722918|1.715825|2.968085|2.411150|4.078398|0.139225|0.141024|0.122376|0.212547|0.299687|0.500000| |6.875410|8.824260|17.558429|5.449979|0.123537|4.671456|4.969289|0.092490|3.233971|2.653130|2.438888|2.587954|3.102114|3.613569|6.344991|6.435014|3.595634|5.655708|3.104081|3.478242|2.423412|4.626885|2.040001|1.969267|1.701878|1.608107|1.662147|1.845838|1.852915|1.677842|1.537019|1.531882|2.708992|2.218548|3.858674|0.167143|0.207557|0.140964|0.216759|0.303323|0.302484|0.500000| |2.407614|2.871360|2.780889|3.528190|0.092526|4.602251|8.979806|0.182316|8.831123|17.720577|8.871500|5.590246|4.869203|5.577064|5.856748|4.741179|3.349810|5.721846|3.092354|4.328436|3.884424|9.017084|3.349611|3.447556|2.909210|3.000006|3.082101|3.254924|3.062129|2.784786|2.677713|2.798722|3.702874|2.655726|4.101896|0.065418|0.060284|0.065605|0.078596|0.074757|0.085999|0.067776|0.500000| |2.034553|2.398417|2.363353|2.727468|0.072275|3.459072|5.606671|0.105114|5.704470|8.968594|17.713439|8.887705|5.626872|4.968566|4.988120|3.500519|2.425011|4.209098|2.243885|3.075055|2.586044|5.446386|2.354664|2.454935|2.209036|2.289676|2.294827|2.330648|2.231288|2.120474|2.095584|2.173715|2.748550|1.978780|3.164831|0.054283|0.052513|0.055556|0.068294|0.062151|0.073605|0.059869|0.214253|0.500000| |2.122920|2.535805|2.506438|2.738916|0.072362|3.485333|5.030116|0.089325|4.997823|5.624397|8.892523|17.715168|8.957127|5.678521|5.610093|3.335797|2.237873|3.895576|2.020835|2.678629|2.159408|4.417190|1.953749|2.034617|1.835519|1.844678|1.834963|1.886134|1.818843|1.720464|1.682673|1.733033|2.364717|1.739561|2.841996|0.055210|0.055831|0.057840|0.075331|0.063694|0.079024|0.065032|0.123610|0.216049|0.500000| |2.751630|3.456594|3.359161|3.585409|0.093049|4.742598|5.975150|0.099627|5.620846|4.869770|5.594938|8.876324|17.727995|8.873202|9.157992|4.043823|2.589391|4.486181|2.244725|2.866936|2.246121|4.566933|1.980106|2.050268|1.810713|1.765302|1.759121|1.851627|1.787590|1.657904|1.591546|1.634030|2.444418|1.843343|3.041244|0.068974|0.072633|0.074369|0.109243|0.080752|0.108358|0.087458|0.106111|0.123627|0.213922|0.500000| |5.445851|6.787100|6.847017|9.038856|0.180958|6.850825|8.542224|0.186129|4.459600|3.557039|2.924495|2.810033|3.184582|4.095555|6.690839|26.069252|9.445313|10.881537|7.569173|6.953625|4.628599|9.157811|3.389194|3.075423|2.471950|2.303067|2.458181|2.909991|2.934459|2.498863|2.196436|2.184655|4.401933|3.825121|6.283994|0.168797|0.121598|0.129541|0.141389|0.227784|0.179583|0.138594|0.096363|0.071443|0.067737|0.081058|0.500000| |3.651232|3.901221|3.887161|4.799679|0.119549|4.196027|6.125126|0.149910|3.485029|3.074291|2.536252|2.346216|2.510096|3.043008|4.502232|10.221541|8.749087|10.456445|17.601201|12.505054|6.776061|11.619161|4.547225|3.660387|2.889106|2.695646|3.022322|3.837691|4.058899|3.260435|2.717000|2.647405|6.143567|5.900831|9.318442|0.116438|0.086550|0.094009|0.090561|0.125710|0.104508|0.090096|0.089087|0.064375|0.057674|0.063700|0.240988|0.500000| |3.820999|3.694303|3.470606|4.365193|0.117927|3.565611|4.916704|0.115329|2.879090|2.552828|2.166082|2.040967|2.193653|2.609302|3.932661|8.624012|8.893580|12.047490|17.626289|12.694653|5.754873|8.744908|4.385232|3.628712|2.906460|2.598358|2.825155|3.518564|3.563626|2.883953|2.464437|2.449284|6.756663|7.466833|13.723185|0.127646|0.089960|0.101968|0.086074|0.110381|0.088964|0.083323|0.073128|0.055411|0.050854|0.056730|0.170574|0.300784|0.500000| |2.515292|2.597143|2.304839|3.237503|0.098266|3.154046|4.853885|0.116269|3.076297|2.948041|2.477271|2.229991|2.281446|2.641789|3.646023|4.854632|4.534102|9.713626|4.371716|7.841194|6.980664|10.205009|8.889632|17.581326|8.765343|5.525166|4.869434|5.502542|4.100792|3.249327|3.103440|3.589087|9.998536|5.810814|8.016959|0.072202|0.061159|0.073509|0.067734|0.065102|0.063282|0.057085|0.089013|0.064947|0.055606|0.057576|0.088842|0.102968|0.107985|0.500000| |2.350669|2.528015|2.295413|3.175003|0.092787|3.325025|5.495839|0.134651|3.611738|3.652005|2.978996|2.568035|2.550741|2.945793|3.875483|4.684636|4.083906|7.991080|3.965412|6.899547|7.315301|12.697523|8.893868|17.556073|8.881361|7.109941|6.167400|6.603077|4.646710|3.707092|3.627052|4.348406|7.689785|4.589137|6.404711|0.066541|0.057630|0.067272|0.066669|0.064326|0.064790|0.056580|0.116653|0.078918|0.063406|0.062902|0.088304|0.100140|0.094242|0.302251|0.500000| |1.908158|1.947428|1.796718|2.286870|0.066998|2.260713|3.428410|0.079051|2.301586|2.309925|2.023058|1.820899|1.816204|2.018688|2.730368|3.402479|2.966609|5.780047|3.111591|5.443091|4.549782|6.813045|6.938385|8.833651|17.514877|8.823790|6.604150|6.091946|4.336409|3.636629|3.735851|4.691627|8.991700|4.569169|6.814041|0.054986|0.047852|0.054922|0.051308|0.051126|0.049619|0.045500|0.070536|0.054843|0.046519|0.046396|0.065403|0.077939|0.081119|0.208415|0.173626|0.500000| |1.916556|1.984368|1.809183|2.350001|0.069698|2.384657|3.650924|0.083078|2.503872|2.546968|2.238102|2.001235|1.979035|2.187000|2.912002|3.376892|2.877897|5.720382|2.849731|4.744715|4.121212|6.693061|5.500685|8.855459|17.561029|8.843596|5.505779|4.843526|3.576915|3.098080|3.251966|4.108106|6.350182|3.641705|5.502712|0.054184|0.048044|0.055639|0.053119|0.050622|0.050376|0.045816|0.077831|0.060854|0.051075|0.050287|0.064199|0.072030|0.072991|0.213947|0.210588|0.303699|0.500000| |1.636628|1.705300|1.607928|1.974503|0.056557|2.028089|3.129712|0.070965|2.197515|2.311755|2.063602|1.822396|1.764685|1.914430|2.509214|2.882482|2.387680|4.464807|2.494906|4.146474|3.593786|5.906707|4.858522|5.543382|8.818706|17.554354|8.915140|5.690616|4.241600|3.999018|4.754503|7.163028|5.595757|3.198388|4.907290|0.046621|0.041585|0.046481|0.045491|0.045462|0.045221|0.040965|0.072225|0.057594|0.047063|0.044862|0.056732|0.065741|0.064264|0.123208|0.142497|0.216673|0.208169|0.500000| |1.788804|1.902477|1.785198|2.248147|0.064271|2.373985|3.782090|0.086621|2.686790|2.896551|2.533680|2.178697|2.084316|2.275816|2.924089|3.252690|2.675049|5.003129|2.724616|4.510996|4.176486|7.263532|5.404492|6.783414|8.890485|17.506219|8.935597|6.103386|4.395144|3.996327|4.554286|6.536115|5.545596|3.262358|4.879629|0.050517|0.045131|0.050738|0.050946|0.050071|0.050754|0.045072|0.093259|0.070877|0.055615|0.052146|0.063745|0.072205|0.068171|0.140736|0.206348|0.174101|0.219594|0.304077|0.500000| |2.151990|2.266669|2.240666|2.658322|0.071537|2.633907|4.125189|0.099417|2.679043|2.674393|2.264767|2.005403|2.006647|2.279755|3.088255|4.368222|3.698773|6.040011|4.789129|8.742164|7.052150|10.354559|7.040068|4.548362|3.894672|4.063181|5.633777|8.885593|17.703208|8.990271|5.670545|4.982642|8.658756|6.019192|8.548145|0.064230|0.053855|0.058373|0.057383|0.066955|0.062877|0.055524|0.083683|0.060827|0.050520|0.050639|0.091979|0.138723|0.117620|0.109873|0.118089|0.106803|0.089139|0.097519|0.101841|0.500000| |1.712588|1.806565|1.818779|2.043642|0.054915|2.078253|3.211388|0.073713|2.209226|2.294473|2.022701|1.789396|1.748144|1.916747|2.538701|3.182842|2.540051|4.242363|3.001863|4.801847|3.851178|6.452423|4.093380|3.220519|3.088511|3.536742|4.922522|5.621784|8.942977|17.723853|8.882170|5.653245|5.114134|3.468021|5.478493|0.050267|0.043849|0.046413|0.046727|0.053622|0.051686|0.046062|0.071855|0.055967|0.045984|0.044440|0.067518|0.088125|0.077205|0.078186|0.086972|0.084817|0.073465|0.090973|0.090912|0.217045|0.500000| |1.491334|1.572615|1.560007|1.773044|0.048457|1.833315|2.832439|0.063845|2.011221|2.148644|1.938740|1.704492|1.633750|1.754511|2.284817|2.660425|2.111851|3.656770|2.352640|3.741628|3.101020|5.311926|3.536420|3.087003|3.238707|4.105189|5.618611|4.936919|5.661034|8.891626|17.717456|8.942829|4.289564|2.759179|4.380487|0.043049|0.038403|0.040969|0.041441|0.045043|0.044482|0.039882|0.067715|0.054910|0.044344|0.041592|0.055188|0.066750|0.060810|0.073574|0.084578|0.087734|0.078292|0.112778|0.106726|0.124523|0.213728|0.500000| |1.523472|1.604623|1.554019|1.834632|0.051177|1.907927|2.967750|0.067046|2.117100|2.278506|2.050534|1.790849|1.709431|1.836106|2.377869|2.705347|2.182074|3.909972|2.347253|3.817998|3.288659|5.596023|4.072813|3.918362|4.610066|7.111558|8.922852|5.654312|4.982372|5.657643|8.959008|17.700349|4.703807|2.851904|4.434168|0.043565|0.039007|0.042499|0.042659|0.044273|0.044182|0.039659|0.072323|0.058227|0.046505|0.043360|0.054730|0.064374|0.060260|0.089606|0.107417|0.119903|0.110509|0.215177|0.180470|0.108005|0.124246|0.216163|0.500000| 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