Version2.2 2021-02-10T14:23:13Z 10.1021/jm300687e Gaussian16 RevisionB.01 SBUNGAY 24-Dec-2020 #N HF/6-31G(d) OPT=(MaxStep=1) FREQ IOp(6/10=2,6/11=2,6/12=2) DUDE CC1=C2[C@H](SCC(=O)N=C2N(N1)c3nc4ccc(cc4s3)OC)c5ccccc5 C15084867 RHF 6-31G(d) (6D,7F) CC1=C2[C@H](SCC(=O)N=C2N(N1)c3nc4ccc(cc4s3)OC)c5ccccc5 C01[X(C21H18N4O2S2)] 135 C1 479 COc1ccc2c(c1)sc(n2)N1NC(=C2C1=NC(=O)CS[C@@H]2c1ccccc1)C COc1ccc2c(c1)sc(n2)N1NC(=C2C1=NC(=O)CS[C@@H]2c1ccccc1)C CCCC[NH+](C)Cc1c(O)ccc2C(=O)C(/Oc12)=C\c3cn(C)c4ccccc34 InChIKey=WZHNZYLKAMYZLN-LPYMAVHISA-O InChI=1S/C24H26N2O3/c1-4-5-12-25(2)15-19-21(27)11-10-18-23(28)22(29-24(18)19)13-16-14-26(3)20-9-7-6-8-17(16)20/h6-11,13-14,27H,4-5,12,15H2,1-3H3/p+1/b22-13+ InChI=1/C24H26N2O3/c1-4-5-12-25(2)15-19-21(27)11-10-18-23(28)22(29-24(18)19)13-16-14-26(3)20-9-7-6-8-17(16)20/h6-11,13-14,27H,4-5,12,15H2,1-3H3/p+1/b22-13+/fC24H27N2O3/h25H/q+1 CC1=C2[C@H](SCC(=O)N=C2N(N1)c3nc4ccc(cc4s3)OC)c5ccccc5 C01[X(C21H18N4O2S2)] 135 C01 479 COc1ccc2c(c1)sc(n2)N1NC(=C2C1=NC(=O)CS[C@@H]2c1ccccc1)C CO[C]1[CH][CH][C]2[C]([CH]1)SC(=N2)N1NC(=[C]2[C]1[N]C(=O)CS[C@@H]2[C]1[CH][CH][CH][CH][CH]1)C CCCC[NH](C)C[C]1[C](O)[CH][CH][C]2[C]1OC(=C[C]3[CH]N(C)[C]4[CH][CH][CH][CH][C]34)C2=O InChIKey=KMURBEHDJNJIRL-UHFFFAOYSA-N InChI=1S/C24H27N2O3/c1-4-5-12-25(2)15-19-21(27)11-10-18-23(28)22(29-24(18)19)13-16-14-26(3)20-9-7-6-8-17(16)20/h6-11,13-14,25,27H,4-5,12,15H2,1-3H3 InChI=1/C24H27N2O3/c1-4-5-12-25(2)15-19-21(27)11-10-18-23(28)22(29-24(18)19)13-16-14-26(3)20-9-7-6-8-17(16)20/h6-11,13-14,25,27H,4-5,12,15H2,1-3H3 2951.6335993205 -1968.2108788 1-A 17351.0986 110 369 479 |A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A| -91.97855 -91.94579 -20.58827 -20.51721 -15.66842 -15.65659 -15.56866 -15.53214 -11.36139 -11.36115 -11.33406 -11.33114 -11.30070 -11.29455 -11.28270 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509.7246 516.7084 557.2092 567.9862 623.2447 640.6881 648.8293 662.1906 668.8477 678.4932 688.0187 692.9375 739.9824 759.0500 761.6409 779.6369 806.0141 811.4347 833.7833 854.9064 860.4437 877.7174 896.6151 924.3276 931.6326 944.8707 959.8146 981.1953 998.1705 1009.2010 1026.6765 1053.8762 1070.2424 1090.3228 1105.4064 1109.6879 1128.4141 1130.4916 1136.3602 1153.1304 1168.8531 1184.9223 1196.2886 1211.3456 1216.6363 1231.4911 1257.7784 1291.0639 1293.7279 1296.8504 1304.3837 1328.0354 1334.6733 1352.2873 1364.8477 1373.9683 1388.3935 1402.4407 1428.1233 1435.8398 1445.3241 1454.5448 1499.5330 1507.6611 1546.4463 1579.1980 1588.8877 1601.8888 1614.4739 1621.6632 1625.1714 1634.6990 1651.5985 1654.2089 1662.3513 1668.5445 1672.1341 1734.6219 1762.3452 1766.8356 1784.8059 1794.5009 1808.2910 1817.9435 1985.0185 3206.7660 3224.2181 3232.9816 3246.3898 3268.7128 3301.1821 3325.6377 3327.7227 3331.1615 3353.6494 3362.3289 3373.1413 3383.0951 3384.7393 3391.8239 3397.3353 3411.1930 3829.3025 5.8065 6.8633 5.4253 5.7618 3.9057 4.6811 5.5185 5.1803 6.3173 1.2835 2.9180 5.9617 6.4274 5.5754 3.9721 4.9994 4.9574 3.8679 4.3443 1.5272 4.1162 4.6323 5.3244 5.4154 5.0062 7.1798 5.9486 7.3448 2.9086 3.6271 3.1657 1.7656 3.1110 6.3070 6.5889 3.5963 5.3414 5.2937 5.4594 6.1070 5.2276 6.0104 5.2083 4.8762 7.2618 7.5449 7.0960 2.0625 6.3665 4.7149 1.9146 6.2572 5.6506 4.2074 5.4370 1.4754 4.1150 4.6446 1.2504 1.4742 5.4648 4.4978 2.2857 1.6166 1.3398 6.1576 1.3682 1.6774 1.5610 1.9918 3.1858 2.3664 1.6280 1.7729 4.5992 4.4194 2.8657 1.9992 1.4329 2.2111 1.2660 2.0409 1.1461 1.7336 1.6871 2.8286 2.3274 1.4722 1.7600 1.5916 2.1393 4.7026 1.4510 3.1701 2.1194 2.3171 1.9114 2.2669 2.4605 1.1065 1.1955 2.0273 1.4401 1.1064 1.0480 1.8964 1.1432 2.2013 2.5208 10.2763 6.8835 6.8661 5.2688 10.6473 5.2346 6.5327 11.8905 1.0345 1.0855 1.0378 1.0665 1.1075 1.1040 1.1018 1.1016 1.1015 1.0880 1.0890 1.0926 1.0954 1.0909 1.0988 1.0933 1.0938 1.0796 0.0009 0.0036 0.0062 0.0080 0.0056 0.0115 0.0145 0.0247 0.0498 0.0139 0.0344 0.0927 0.1204 0.1271 0.1046 0.1486 0.1727 0.1433 0.1689 0.0743 0.2101 0.2537 0.3150 0.3436 0.3858 0.6296 0.6279 0.8901 0.3585 0.5004 0.4489 0.2592 0.4762 0.9921 1.2053 0.6836 1.2224 1.2803 1.3541 1.5778 1.3779 1.6302 1.4526 1.3795 2.3428 2.5612 2.4253 0.7386 2.4369 1.8291 0.7842 2.6944 2.4648 1.9098 2.5753 0.7427 2.1043 2.4431 0.6787 0.8362 3.2080 2.6990 1.4195 1.0579 0.9042 4.3130 0.9850 1.2170 1.1711 1.4998 2.4238 1.8540 1.3105 1.4666 3.8780 3.8207 2.4992 1.7863 1.3356 2.1715 1.2484 2.0224 1.1489 1.8014 1.7707 3.0476 2.5544 1.6375 1.9989 1.8444 2.5707 5.7122 1.7858 3.9516 2.8079 3.1031 2.6932 3.3309 3.6599 1.6729 1.8359 3.1412 2.2410 1.7420 1.6843 3.0575 1.8613 3.6109 4.1527 18.2179 12.5963 12.6285 9.8887 20.2012 10.0848 12.7205 27.6044 6.2680 6.6483 6.3912 6.6224 6.9716 7.0885 7.1798 7.1871 7.2017 7.2096 7.2539 7.3243 7.3869 7.3636 7.4480 7.4347 7.4988 9.3276 0.0564 2.9468 2.0020 0.6012 1.3518 3.5239 3.5622 0.5094 3.5895 0.1146 0.1239 5.8422 4.2433 9.8530 4.4784 0.4303 2.7406 0.7094 2.1671 2.1839 0.5103 1.2784 0.2710 9.7285 4.6397 3.5478 34.6716 6.9322 0.2551 60.6732 14.7324 331.6662 48.0680 3.1363 24.5659 5.3790 9.5680 7.0350 33.0341 2.8685 16.3810 0.5977 4.3914 7.6783 4.2443 13.5258 27.6608 31.1077 2.5354 0.3044 61.3992 4.3032 21.1816 11.3357 10.1957 41.1167 9.3566 28.3344 0.1246 35.3660 2.5250 17.4216 7.6991 2.2656 0.3434 1.5639 0.0925 14.3495 3.9790 12.3096 36.5316 5.0035 8.7703 1.6750 20.8395 84.0741 33.5789 3.9405 142.6352 0.4693 3.1552 2.6554 1.5095 13.4385 79.8225 275.0812 67.9913 36.1511 82.7533 38.4884 27.9273 429.4871 14.4738 9.4881 298.4667 307.1433 202.5069 19.3715 251.2376 20.5775 2.0043 14.2924 155.5501 20.6444 4.2319 237.8393 1.2443 36.3891 42.0538 1127.0874 89.3075 24.9804 11.7880 611.4146 3.3938 192.0238 396.6013 65.5418 16.9321 9.9538 13.9099 57.1797 11.9089 9.5363 47.5582 3.3678 6.1726 0.2305 20.9441 35.8888 7.1561 18.5181 3.6683 18.6745 121.2282 1.3742 3.5129 2.5707 1.7576 4.2830 2.7412 2.9993 3.3881 0.7835 1.2035 0.7524 0.7617 1.7744 1.1539 1.6284 0.4954 2.9597 0.8499 3.5933 0.0409 0.1247 1.9260 2.8575 3.2071 1.1378 5.4285 4.7820 2.9269 0.1328 8.4465 1.4908 22.3568 3.3375 4.0873 5.4650 1.1789 8.5422 4.3053 3.1588 5.4711 8.2226 5.6465 1.1505 3.4150 6.4979 5.0125 6.5463 0.4891 3.7456 3.3899 6.4803 4.0289 4.3704 15.9015 3.9190 0.9972 3.0933 21.3363 2.0082 1.9040 8.6925 10.1711 6.9536 1.8474 1.1910 33.3863 0.2536 3.7862 4.2915 3.1875 14.1182 5.3240 0.2782 0.6583 5.1213 4.9429 8.9964 1.0151 3.5938 42.4475 5.0010 25.8411 5.1492 6.7994 33.7938 23.8902 61.9140 8.8530 6.7861 27.7049 90.2520 89.5147 27.6193 15.6239 6.0928 2.7186 11.2084 7.0881 47.0795 16.5522 8.1527 1.4936 56.2573 14.1019 29.9077 63.9509 46.1076 2.6381 22.4477 258.3709 43.2301 219.4233 10.3295 488.0508 58.6838 90.6452 58.7530 119.1382 56.1122 132.9842 69.1759 54.9613 65.2156 48.1373 167.5294 132.0232 27.3948 87.9217 104.2876 34.9880 53.5630 302.3716 80.7852 149.7887 90.0470 0.7462 0.7458 0.7308 0.7495 0.7484 0.7452 0.7105 0.7206 0.7467 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6 7 6 6 6 6 6 6 16 8 6 6 6 6 6 6 6 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 12.00000 12.00000 12.00000 12.00000 1.00783 31.97207 12.00000 12.00000 15.99491 14.00307 12.00000 14.00307 14.00307 12.00000 14.00307 12.00000 12.00000 12.00000 12.00000 12.00000 12.00000 31.97207 15.99491 12.00000 12.00000 12.00000 12.00000 12.00000 12.00000 12.00000 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 5001.1036 27259.4588 30761.1003 1.00000 0.00195 0.00198 -0.00194 0.99998 -0.00574 -0.00199 0.00573 0.99998 1 0.01732 0.00318 0.00282 0.36087 0.06621 0.05867 23.76 43.21 63.49 69.70 71.19 92.96 96.17 129.53 166.45 194.81 203.66 233.74 256.57 282.98 304.20 323.21 349.84 360.84 369.57 413.36 423.50 438.66 455.90 472.12 520.32 555.05 609.01 652.51 658.02 696.24 705.83 718.12 733.38 743.43 801.70 817.21 896.71 921.81 933.52 952.74 962.32 976.20 989.91 996.98 1064.67 1092.10 1095.83 1121.72 1159.67 1167.47 1199.63 1230.02 1237.99 1262.84 1290.03 1329.90 1340.41 1359.46 1380.96 1411.72 1436.14 1452.02 1477.16 1516.29 1539.84 1568.73 1590.43 1596.59 1623.54 1626.53 1634.97 1659.10 1681.72 1704.84 1721.19 1742.86 1750.47 1771.84 1809.66 1857.55 1861.39 1865.88 1876.72 1910.75 1920.30 1945.64 1963.71 1976.83 1997.59 2017.80 2054.75 2065.85 2079.50 2092.77 2157.49 2169.19 2224.99 2272.11 2286.05 2304.76 2322.87 2333.21 2338.26 2351.97 2376.28 2380.04 2391.75 2400.66 2405.83 2495.73 2535.62 2542.08 2567.94 2581.89 2601.73 2615.62 2856.00 4613.82 4638.93 4651.54 4670.83 4702.95 4749.66 4784.85 4787.85 4792.80 4825.15 4837.64 4853.20 4867.52 4869.88 4880.08 4888.01 4907.95 5509.51 0.386604 0.410176 0.411121 0.331063 -1967.824274 -1967.800702 -1967.799758 -1967.879816 2.685158D-04 MUNgauss RevisionA2.1 retrievium 10-Feb-2021 DUDE CC1=C2[C@H](SCC(=O)N=C2N(N1)c3nc4ccc(cc4s3)OC)c5ccccc5 C15084867 RHF 6-31G(d) (6D,10F) C1 422.087120 |X|Y|Z| 119.797240 49.279051 23.900661 52.060263 25 6 7 16 19 4 2 |36.858105| 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|2.666748|3.228897|3.191113|2.581604|0.067378|17.422917|2.751155|3.373776|5.793625|5.740984|4.058850|6.852488|5.509830|7.875746|11.059707|13.673464|7.946766|6.926686|8.013868|13.791110|36.858105| |2.997841|3.855109|4.076307|3.200279|0.082010|22.070893|3.649948|4.884392|8.232773|9.154957|5.840578|9.392467|6.468865|10.859854|9.971653|7.376870|4.876341|4.244672|4.686577|6.738859|10.864465|388.023441| |1.811654|2.029585|1.995766|1.738447|0.046357|12.018585|1.848513|2.128351|3.812244|3.251916|2.304225|3.534113|3.195436|3.197482|4.711647|4.619971|5.188047|7.852412|14.107909|8.227793|5.321668|26.344695|73.516695| |1.673010|1.838337|1.789266|1.574521|0.042186|10.821137|1.642186|1.854783|3.304066|2.806135|2.018917|3.083743|2.865834|2.708439|4.053880|3.799154|4.520212|6.725809|8.001254|5.268864|4.005288|21.123085|24.218695|36.858105| |6.034129|6.182637|7.461226|12.496195|0.249373|50.723924|4.601397|3.953790|5.793213|5.547029|4.932420|5.533460|5.933678|3.153462|3.813118|2.352634|2.061807|1.820597|1.784021|1.960697|2.272118|19.176892|2.836330|1.462509|36.858105| |5.207684|4.739594|5.162874|7.554199|0.206685|38.004275|3.792933|3.204662|4.855879|4.390002|3.749103|4.422180|4.826808|2.631434|3.268365|2.055381|1.837662|1.638134|1.600394|1.736623|1.979897|16.271348|2.568896|1.337398|13.726092|36.858105| |4.334488|3.802798|3.925656|5.006449|0.134168|28.829770|3.026773|2.662184|4.161647|3.659177|3.054937|3.747780|4.096049|2.303097|2.921616|1.863881|1.692876|1.519229|1.478901|1.587600|1.788977|14.379588|2.389660|1.254043|7.897314|13.736586|36.858105| |4.070581|3.635636|3.703336|4.416066|0.111376|26.613331|2.808634|2.567502|4.064127|3.574783|2.969723|3.702359|4.018358|2.299104|2.934963|1.878261|1.711378|1.536534|1.493348|1.599111|1.799137|14.364475|2.413325|1.268075|6.828650|7.938212|13.769685|36.858105| |4.424605|4.173404|4.327779|4.994011|0.116819|30.089181|3.094902|2.908302|4.569435|4.121475|3.462755|4.281418|4.587677|2.621341|3.307578|2.095404|1.886541|1.682942|1.638280|1.767994|2.008783|16.239533|2.629671|1.372502|7.905050|6.894632|7.955525|13.731823|36.858105| |5.361100|5.515210|6.187075|7.493224|0.155723|40.967128|3.925535|3.659740|5.536689|5.258846|4.586903|5.378295|5.689245|3.137512|3.836035|2.378208|2.092635|1.848419|1.807608|1.980333|2.290069|19.115729|2.873450|1.483566|13.687852|7.962679|6.882589|7.927770|13.767850|36.858105| |17.632823|8.902267|6.646160|6.341903|0.185669|28.075668|3.458094|3.170797|4.708803|4.820585|4.557439|6.041855|7.959637|3.434865|4.407995|2.623033|2.333947|2.004998|1.902435|2.046994|2.402396|19.293805|2.984531|1.554977|6.540859|6.239749|4.924131|4.276669|4.364563|5.199429|0.500000| |17.589289|8.962662|5.581559|4.539643|0.124613|22.684686|2.966665|2.909493|4.403831|4.635482|4.407471|6.714788|10.275474|3.933240|5.382916|3.089147|2.775654|2.312710|2.133579|2.263023|2.694482|20.772395|3.295373|1.724283|4.495388|4.093041|3.584513|3.409846|3.626619|4.153693|0.301297|0.500000| |17.583371|8.922718|6.204204|5.442044|0.137036|26.147273|3.131881|3.036994|4.587763|4.747773|4.507694|6.307912|8.532227|3.613528|4.740410|2.785261|2.486552|2.113727|1.985517|2.125151|2.507298|19.838886|3.097343|1.616450|6.334539|5.434207|4.825983|4.814294|5.401816|6.292837|0.302810|0.299952|0.500000| |3.623669|4.553801|6.308209|6.917535|0.205493|56.339992|17.572238|8.784383|10.928818|9.330746|6.425322|6.217123|5.478353|3.725338|4.151470|2.652596|2.239220|2.017400|2.062324|2.369725|2.752331|25.524669|3.283159|1.646453|4.512134|3.844135|3.019226|2.736854|2.949419|3.699757|0.104796|0.088597|0.089872|0.500000| |2.867974|3.443549|4.517588|5.147452|0.139920|57.115037|17.646546|9.003077|13.900554|7.710561|4.774177|4.882570|4.262400|3.109697|3.524033|2.334726|1.998219|1.841012|1.913570|2.201688|2.484052|22.816386|3.100282|1.554682|3.868686|3.354609|2.758246|2.563046|2.773068|3.378618|0.081825|0.070896|0.074597|0.300788|0.500000| |6.981354|9.184705|6.123948|4.211134|0.106858|23.071948|3.202367|3.479232|5.264110|6.165296|6.133722|12.925101|25.954535|7.453001|10.815638|5.068674|4.167773|3.217562|2.918476|3.174739|4.087506|31.527341|4.300326|2.189577|3.824042|3.196717|2.814694|2.823825|3.224933|3.837592|0.142773|0.207969|0.169779|0.092518|0.075386|0.500000| |2.714505|2.999840|2.686947|2.213169|0.058793|14.119747|2.088282|2.342463|3.910063|3.815068|3.003783|5.189768|5.173194|4.812638|9.469027|8.928427|17.731005|8.906235|5.621282|4.917164|5.648025|28.751056|7.430537|3.909785|2.053966|1.844758|1.710168|1.731028|1.898718|2.087439|0.066629|0.081537|0.071672|0.059358|0.052613|0.120659|0.500000| |2.039574|2.238378|2.106024|1.804573|0.048212|12.002620|1.799590|2.026404|3.503974|3.170553|2.367448|3.800889|3.621535|3.437556|5.660933|5.673497|8.982946|17.768123|8.857837|5.621490|4.983835|24.374294|12.517513|7.490341|1.678749|1.525941|1.426672|1.444582|1.571141|1.706236|0.051656|0.059609|0.054470|0.050614|0.046419|0.079522|0.216230|0.500000| |2.070101|2.417122|2.460124|2.109254|0.055649|14.894706|2.372960|2.876153|5.257667|4.469492|3.003381|4.547274|3.829899|4.310674|5.761181|5.590450|4.918378|5.631773|8.949805|17.743777|8.834511|43.964574|13.496714|4.875739|1.882092|1.671404|1.528618|1.537718|1.696312|1.897326|0.053238|0.057593|0.054827|0.065048|0.061817|0.077884|0.106954|0.123967|0.500000| |1.539756|1.685539|1.654416|1.472271|0.039524|10.217749|1.551915|1.745752|3.138085|2.603485|1.858028|2.790166|2.591705|2.407399|3.521678|3.188505|3.620593|4.902902|5.877472|4.427257|3.425851|19.000973|17.015354|17.645489|1.370404|1.258309|1.182822|1.195507|1.289795|1.389103|0.040019|0.043861|0.041423|0.043100|0.041129|0.054569|0.088956|0.146307|0.121539|0.500000| |1.679411|1.834292|1.773689|1.560279|0.041618|10.680236|1.600281|1.803043|3.199370|2.737184|1.987090|3.048999|2.859063|2.662766|4.037293|3.749411|4.587898|6.730840|7.021554|4.767090|3.810755|20.257938|16.437031|17.557007|1.462156|1.336325|1.259504|1.281174|1.390096|1.495063|0.043151|0.048152|0.045408|0.044414|0.041978|0.061382|0.113049|0.225182|0.119940|0.300070|0.500000| |1.681297|1.835933|1.773050|1.559497|0.042059|10.626101|1.614954|1.807147|3.193254|2.735551|1.986285|3.048018|2.868746|2.663090|4.036615|3.749321|4.587877|6.730721|7.020839|4.766662|3.810794|20.256028|16.436951|17.556966|1.446929|1.329523|1.245457|1.253536|1.349707|1.458236|0.043499|0.048514|0.044873|0.045358|0.042414|0.060945|0.113056|0.225211|0.119926|0.300066|0.298876|0.500000| |4.822935|4.421263|4.826150|7.031343|0.230126|36.330188|3.851428|3.149461|4.771104|4.246507|3.579901|4.220262|4.589306|2.533363|3.148128|1.991333|1.784300|1.596336|1.562685|1.694799|1.924865|15.800840|2.515111|1.310402|8.915417|17.701049|8.929365|5.650864|4.962014|5.652566|0.169535|0.108913|0.130480|0.112667|0.095689|0.083631|0.049702|0.041355|0.045420|0.034303|0.036200|0.036331|0.500000| |3.732575|3.251543|3.310578|4.091144|0.114952|24.538151|2.696883|2.369752|3.752443|3.232438|2.657685|3.305436|3.606533|2.068984|2.650088|1.709157|1.567175|1.415292|1.377186|1.469493|1.641665|13.047423|2.237929|1.180377|5.632550|8.921820|17.716892|8.914482|5.649641|4.956978|0.119256|0.089209|0.112247|0.075582|0.069539|0.069385|0.044086|0.037116|0.039381|0.031010|0.032900|0.032651|0.215959|0.500000| |3.441500|3.069447|3.078438|3.535032|0.091160|22.177922|2.433300|2.253252|3.626931|3.130255|2.559321|3.250671|3.513611|2.064055|2.668240|1.729224|1.593750|1.440607|1.398262|1.485968|1.655859|13.028241|2.273030|1.201529|4.929027|5.643331|8.913040|17.718517|8.901716|5.640985|0.099360|0.083198|0.111945|0.065933|0.062643|0.069715|0.044925|0.037856|0.039745|0.031545|0.033809|0.032992|0.124219|0.214604|0.500000| 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