Version2.1 2020-12-27T14:04:54Z 10.1021/jm300687e Gaussian16 RevisionB.01 PWARBURT 31-Oct-2020 #N HF/6-31G(d) OPT=(MaxStep=1) FREQ IOp(6/10=2,6/11=2,6/12=2) DUDE CC1(CC2=C([C@@H](c3c([nH]c(=O)[nH]c3=O)N2)c4ccc(o4)c5ccccc5[N+](=O)[O-])C(=O)C1)C C39795117 RHF 6-31G(d) (6D,7F) CC1(CC2=C([C@@H](c3c([nH]c(=O)[nH]c3=O)N2)c4ccc(o4)c5ccccc5[N+](=O)[O-])C(=O)C1)C C01[X(C23H20N4O6)] 153 C1 535 O=c1[nH]c2NC3=C([C@@H](c2c(=O)[nH]1)c1ccc(o1)c1ccccc1[N+](=O)[O-])C(=O)CC(C3)(C)C O=c1[nH]c2NC3=C([C@@H](c2c(=O)[nH]1)c1ccc(o1)c1ccccc1[N+](=O)[O-])C(=O)CC(C3)(C)C CC1(C)CC(=O)C2=C(C1)NC3=C([C@H]2c4oc(cc4)c5ccccc5[N+]([O-])=O)C(=O)NC(=O)N3 InChIKey=UVJGXFOLGGCOLZ-SFHVURJKSA-N InChI=1S/C23H20N4O6/c1-23(2)9-12-17(14(28)10-23)18(19-20(24-12)25-22(30)26-21(19)29)16-8-7-15(33-16)11-5-3-4-6-13(11)27(31)32/h3-8,18H,9-10H2,1-2H3,(H3,24,25,26,29,30)/t18-/m0/s1 InChI=1/C23H20N4O6/c1-23(2)9-12-17(14(28)10-23)18(19-20(24-12)25-22(30)26-21(19)29)16-8-7-15(33-16)11-5-3-4-6-13(11)27(31)32/h3-8,18H,9-10H2,1-2H3,(H3,24,25,26,29,30)/t18-/m0/s1/f/h24-26H CC1(CC2=C([C@@H](c3c([nH]c(=O)[nH]c3=O)N2)c4ccc(o4)c5ccccc5[N+](=O)[O-])C(=O)C1)C C01[X(C23H20N4O6)] 153 C01 535 O=c1[nH]c2NC3=C([C@@H](c2c(=O)[nH]1)c1ccc(o1)c1ccccc1[N+](=O)[O-])C(=O)CC(C3)(C)C O=c1[nH]c2NC3=C([C@@H](c2c(=O)[nH]1)C1=[CH][CH]=C(O1)[C]1[CH][CH][CH][CH][C]1[N]([O])[O])C(=O)CC(C3)(C)C CC1(C)CC(=O)C2=C(C1)NC3=C([C@H]2c4oc(cc4)[C]5[CH][CH][CH][CH][C]5N([O])[O])C(=O)NC(=O)N3 InChIKey=UVJGXFOLGGCOLZ-SFHVURJKSA-N InChI=1S/C23H20N4O6/c1-23(2)9-12-17(14(28)10-23)18(19-20(24-12)25-22(30)26-21(19)29)16-8-7-15(33-16)11-5-3-4-6-13(11)27(31)32/h3-8,18H,9-10H2,1-2H3,(H3,24,25,26,29,30)/t18-/m0/s1 InChI=1/C23H20N4O6/c1-23(2)9-12-17(14(28)10-23)18(19-20(24-12)25-22(30)26-21(19)29)16-8-7-15(33-16)11-5-3-4-6-13(11)27(31)32/h3-8,18H,9-10H2,1-2H3,(H3,24,25,26,29,30)/t18-/m0/s1/f/h24-26H 3550.5321443894 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298.150 1.00000 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 6 6 6 6 6 6 1 6 6 7 1 6 8 7 1 6 8 7 6 6 6 6 8 6 6 6 6 6 6 7 8 8 6 8 6 6 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 12.00000 12.00000 12.00000 12.00000 12.00000 12.00000 1.00783 12.00000 12.00000 14.00307 1.00783 12.00000 15.99491 14.00307 1.00783 12.00000 15.99491 14.00307 12.00000 12.00000 12.00000 12.00000 15.99491 12.00000 12.00000 12.00000 12.00000 12.00000 12.00000 14.00307 15.99491 15.99491 12.00000 15.99491 12.00000 12.00000 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783
11934.0113 14404.2108 18712.5608 0.99631 -0.08492 -0.01264 0.08525 0.99594 0.02884 0.01014 -0.02981 0.99950 1 0.00726 0.00601 0.00463 0.15123 0.12529 0.09645 31.23 40.46 54.96 62.84 79.07 100.26 109.80 133.49 136.92 152.66 186.23 205.46 221.10 236.85 246.89 328.44 347.32 349.73 362.93 372.24 387.71 414.42 439.03 461.07 465.26 498.05 512.54 524.84 571.62 579.45 597.29 606.82 628.74 647.72 674.35 720.03 753.81 763.46 780.68 794.35 831.83 859.09 906.93 923.04 928.14 954.21 1002.71 1012.38 1025.29 1033.50 1052.79 1086.62 1110.31 1114.37 1154.84 1170.56 1187.08 1227.80 1230.36 1233.57 1271.49 1290.92 1298.74 1309.31 1347.66 1388.34 1420.82 1432.83 1434.10 1454.87 1474.41 1486.36 1488.93 1537.65 1553.36 1565.70 1566.81 1607.40 1622.53 1632.40 1643.37 1644.51 1686.94 1690.53 1744.63 1777.95 1787.03 1817.65 1829.72 1848.60 1860.57 1878.52 1909.59 1920.58 1928.80 1938.24 1967.32 1976.24 2004.29 2034.89 2056.86 2076.92 2084.13 2107.56 2115.56 2148.67 2208.82 2228.58 2235.58 2245.31 2266.97 2271.84 2317.22 2324.27 2340.65 2351.71 2361.95 2363.60 2368.51 2377.32 2386.24 2403.17 2452.48 2481.09 2544.42 2590.11 2615.81 2634.18 2658.14 2714.26 2823.47 2840.68 2886.77 4592.16 4598.51 4603.93 4617.69 4663.24 4689.31 4697.68 4702.00 4713.52 4721.44 4749.23 4857.94 4881.48 4894.80 4910.19 4947.98 4980.70 5517.24 5550.93 5579.02 0.441852 0.467802 0.468746 0.384738 -1549.082288 -1549.056339 -1549.055395 -1549.139403 2.817642D-04
MUNgauss RevisionA2.0 retrievium 27-Dec-2020 DUDE CC1(CC2=C([C@@H](c3c([nH]c(=O)[nH]c3=O)N2)c4ccc(o4)c5ccccc5[N+](=O)[O-])C(=O)C1)C C39795117 RHF 6-31G(d) (6D,10F) C1 448.138285 |X|Y|Z| 76.140495 67.562002 46.828203
62.221704 25 6 7 8 21 3 1
|36.858105| |12.424573|36.858105| |7.605729|12.374023|36.858105| |4.938070|7.481501|12.641086|36.858105| |4.353924|6.488326|7.578712|14.282834|36.858105| |3.233762|4.281447|4.874031|7.652893|12.553225|36.858105| |2.993027|3.901146|4.117695|5.773613|8.884740|17.635743|0.500000| |2.896081|3.704006|4.452724|6.846433|7.699049|12.588067|0.247496|36.858105| |3.084096|3.913336|5.129014|7.970952|6.882918|7.683485|0.160534|14.209970|36.858105| |2.643427|3.181875|4.025468|5.289811|4.612824|5.072891|0.118154|8.030582|13.895248|53.358707| |2.654015|3.122762|4.007137|4.905179|4.078839|4.190005|0.099358|5.825993|9.208716|26.039867|0.500000| |2.244219|2.646251|3.160641|3.976229|3.755177|4.383116|0.108657|6.710718|7.881217|18.865858|0.262734|36.858105| |2.023025|2.325891|2.735274|3.265780|3.061505|3.439113|0.087444|4.724148|5.432852|11.517359|0.216561|15.955375|73.516695| |2.178215|2.594702|3.002183|3.854827|3.924086|5.016342|0.129285|7.953754|7.109214|11.304925|0.166187|13.953971|14.978646|53.358707| |1.960270|2.296186|2.597327|3.217284|3.308244|4.140728|0.111285|5.777898|5.180085|8.121696|0.132307|9.460391|13.698370|25.982917|0.500000| |2.382505|2.915511|3.334173|4.507816|4.985208|7.402365|0.192927|13.124733|7.927001|9.366646|0.140654|7.703300|9.509135|18.614272|0.258849|36.858105| |2.197814|2.655936|2.916731|3.783140|4.375256|6.494016|0.195537|8.082605|5.406996|6.542043|0.106760|5.397814|7.516841|11.551831|0.216822|15.906150|73.516695| |3.858302|5.073099|7.808868|13.687037|8.026264|6.677293|0.140511|8.025083|13.901676|11.176774|0.211116|5.268935|7.411000|6.411466|0.104960|5.170501|7.176296|53.358707| |2.924758|3.637324|4.120233|5.702255|7.670089|12.629918|0.251125|7.736663|5.755881|5.817802|0.101152|3.838511|5.547118|5.926191|0.104091|5.925303|9.999374|7.099972|36.858105| |2.477881|2.954111|3.212222|4.071260|5.091525|7.239750|0.188158|5.512967|4.283219|4.760384|0.084245|3.341332|4.990465|5.287583|0.097796|5.087782|9.589095|5.238239|14.190113|36.858105| |2.353696|2.710245|2.981252|3.598502|4.160219|5.118914|0.128038|4.320058|3.710760|4.301265|0.078370|3.003922|4.615534|4.531894|0.085015|3.997154|7.206173|4.720120|8.571282|13.258604|36.858105| |2.638908|3.039422|3.480839|4.211657|4.655167|5.325456|0.123440|4.558324|4.163379|4.734316|0.087368|3.159628|4.832735|4.558531|0.083419|3.925153|6.630107|5.535118|8.724561|8.565430|14.162285|36.858105| |3.088843|3.741930|4.473093|5.950370|6.824076|7.888740|0.161210|6.201246|5.574829|5.781665|0.104309|3.663204|5.406918|5.264023|0.092686|4.736874|7.613203|7.555200|14.139122|8.659969|8.659327|14.153092|73.516695| |2.561917|2.829468|3.265419|3.687029|3.783973|3.965194|0.094138|3.612407|3.550234|4.232332|0.081182|2.807084|4.428040|3.882456|0.071932|3.159321|5.273501|4.937746|5.367899|5.175625|7.372793|12.998510|14.145540|36.858105| |2.288254|2.457107|2.725053|2.962493|3.068449|3.185548|0.079085|2.899213|2.824629|3.454486|0.066990|2.348636|3.784481|3.266920|0.061879|2.626768|4.506107|3.918733|4.124108|4.275537|6.072335|7.699214|9.368698|13.661521|36.858105| |2.158399|2.252727|2.488282|2.611343|2.628068|2.655802|0.066578|2.477202|2.476164|3.100446|0.061338|2.109363|3.461423|2.879669|0.054920|2.260820|3.858303|3.487423|3.235361|3.272654|4.223175|5.074562|7.103632|7.861999|13.788659|36.858105| |2.242091|2.309267|2.604887|2.678641|2.602544|2.571785|0.063752|2.454649|2.532316|3.211185|0.064680|2.153700|3.560303|2.872081|0.054465|2.216787|3.714055|3.638218|3.026031|2.937028|3.596877|4.451449|6.735066|6.765050|7.927667|13.744525|36.858105| |2.502482|2.612544|3.068017|3.177559|2.994726|2.926424|0.070727|2.836885|3.009977|3.799141|0.077057|2.484413|4.070764|3.254465|0.060770|2.502406|4.097391|4.405721|3.418649|3.175705|3.807372|5.020548|7.979471|7.816067|6.894052|7.977994|13.792179|36.858105| |2.693547|2.928598|3.523003|3.859008|3.684933|3.679490|0.086179|3.526201|3.704098|4.512855|0.089193|2.906924|4.632898|3.853341|0.070762|3.031439|4.905966|5.366148|4.522348|4.072783|5.021047|7.552587|11.695944|13.671350|8.043736|6.960819|7.987756|13.788645|36.858105| |2.920193|3.260023|4.199190|4.768586|4.240230|4.175156|0.094238|4.250973|4.820585|5.848424|0.117023|3.560517|5.574801|4.533192|0.080954|3.506491|5.422588|7.197407|4.801387|4.011628|4.483676|6.387806|12.361460|7.633613|5.099909|4.539222|5.167194|7.917318|13.010360|53.358707| |3.356651|3.685282|5.004187|5.250447|4.315460|3.926575|0.089362|3.977722|4.722976|5.720227|0.119490|3.367632|5.325846|4.190402|0.074733|3.217071|4.957360|7.850331|4.188844|3.448114|3.677462|4.909243|10.064531|5.589587|4.171893|3.909252|4.574166|6.749146|8.356841|21.610682|73.516695| |2.641291|3.003164|3.822181|4.595876|4.171571|4.423937|0.099257|4.880054|5.609437|7.097769|0.137956|4.352944|6.702793|5.465147|0.096225|4.120131|6.196010|7.514403|5.052812|4.251321|4.631656|6.212791|12.118894|6.462412|4.495106|3.922030|4.244209|5.773719|8.362917|21.829694|16.021667|73.516695| |4.901324|7.424240|6.514087|7.822355|12.904543|7.412406|0.194466|4.978746|4.496086|4.636202|0.086678|2.925651|4.416652|4.186395|0.075115|3.777112|6.336282|6.957909|5.883070|4.487405|3.758193|4.049664|9.430237|3.393580|2.895358|2.505335|2.444613|2.721448|3.227940|4.723061|6.339150|5.877384|36.858105| |3.922591|5.248837|4.621817|5.411382|8.159039|6.708160|0.205418|4.472809|3.836839|4.104089|0.076164|2.697105|4.106399|3.973225|0.072733|3.633393|6.422740|5.512801|5.703370|4.733900|3.825159|3.870304|8.480634|3.180982|2.794049|2.399097|2.289459|2.485889|2.922436|4.134327|5.387157|5.232262|15.903652|73.516695| |7.591341|12.404165|7.641240|6.672290|7.445091|4.837922|0.125529|3.789825|3.721035|4.045623|0.078665|2.540047|3.938912|3.510103|0.063798|2.997622|4.995878|6.109971|4.235948|3.441404|3.106313|3.433222|7.534968|3.095899|2.707257|2.424033|2.413022|2.677741|3.056235|4.431316|6.241175|5.322465|12.563652|14.298096|36.858105| |7.626465|12.389832|7.537922|6.011289|5.518871|3.958842|0.105411|3.573306|3.732094|4.240390|0.084859|2.638945|4.147666|3.535963|0.064273|2.895160|4.716443|6.204713|3.216681|2.673053|2.400923|2.603732|5.597721|2.394466|2.105596|1.936198|1.973090|2.205198|2.453605|3.726819|5.358812|4.659507|6.072868|8.467516|7.553028|36.858105| |17.536114|8.763383|6.918825|4.517366|3.831261|2.943090|0.075582|2.741182|2.992292|3.581662|0.074844|2.227173|3.608407|2.893722|0.053242|2.279844|3.710487|5.113750|2.651577|2.261651|2.158771|2.417537|4.988146|2.372809|2.121595|2.024626|2.130503|2.390101|2.538398|3.806373|5.792929|4.533261|4.039738|5.889542|5.497620|6.936873|0.500000| |17.548005|8.777260|5.505121|4.064813|3.814744|2.934624|0.077575|2.610037|2.712291|3.200904|0.065146|2.039409|3.288669|2.726499|0.050585|2.194523|3.657811|4.430885|2.669228|2.311422|2.187944|2.402498|4.903832|2.321004|2.112350|1.996727|2.049055|2.241451|2.394655|3.459503|5.057999|4.137959|4.505239|6.758572|6.884689|6.968759|0.301723|0.500000| |17.544753|8.744822|6.909960|4.665013|4.140730|3.139119|0.079714|2.795101|2.974616|3.482342|0.071418|2.176899|3.497664|2.874715|0.052904|2.306476|3.790822|5.046583|2.954721|2.518080|2.447646|2.790457|5.725708|2.775210|2.491312|2.371753|2.483338|2.772355|2.946610|4.265472|6.489346|4.903822|4.612356|6.657551|6.920140|5.506253|0.301303|0.301490|0.500000| |6.726821|8.796887|17.543280|8.963291|5.743439|4.147864|0.099625|4.095296|4.959469|5.630751|0.119523|3.209695|5.020528|4.021064|0.071190|3.163740|4.874723|10.253251|3.509045|2.816497|2.632270|3.030570|6.691418|2.893715|2.445721|2.272470|2.409679|2.837832|3.178582|5.241417|8.273410|6.378545|4.915732|6.696552|5.541808|7.124817|0.199739|0.138957|0.163852|0.500000| |7.242825|8.786226|17.503980|9.036373|6.254806|4.387124|0.102352|3.997701|4.578626|5.051248|0.103779|2.951870|4.600538|3.802468|0.067733|3.068176|4.814759|9.048237|4.033882|3.190333|3.079990|3.719960|8.333454|3.643264|3.019193|2.786700|2.973419|3.573533|4.070512|6.583820|10.943113|7.347932|5.600512|7.419495|6.709410|5.505897|0.181490|0.144629|0.217275|0.303386|0.500000| |3.781242|4.648972|7.315376|9.285439|5.954985|5.106746|0.112543|5.939055|9.332732|10.200547|0.222350|4.880203|7.226371|5.666198|0.095261|4.307824|6.145699|25.979729|4.437049|3.427893|3.236119|3.877141|8.942182|3.657085|2.901839|2.637636|2.827196|3.511569|4.200055|8.136498|12.641886|10.794463|4.272362|6.155704|4.011548|4.079785|0.105084|0.087574|0.103347|0.213227|0.192714|0.500000| |2.279036|2.700793|2.859795|3.553080|4.435339|6.260197|0.186102|4.978625|3.811719|4.359756|0.077209|3.164731|4.776785|5.161209|0.098298|5.006203|10.395971|4.594763|8.841459|17.816959|8.450703|5.840346|10.480926|4.053797|3.550933|2.824801|2.544309|2.703243|3.323334|4.487814|5.172881|6.245755|4.068917|8.006764|3.135075|2.517605|0.058048|0.059909|0.063588|0.070748|0.077610|0.083412|0.500000| |2.102514|2.368849|2.563950|2.994714|3.381512|4.019533|0.104697|3.539319|3.108391|3.736222|0.069028|2.667355|4.194200|4.008366|0.077134|3.417510|6.296087|3.967181|5.844740|8.465799|17.795745|8.804461|10.468909|6.339669|6.104915|4.288253|3.512158|3.544757|4.409373|5.197331|5.650575|6.992415|3.152127|5.786415|2.688927|2.123896|0.053913|0.054857|0.060840|0.063873|0.073740|0.076774|0.193559|0.500000| |2.166732|2.335812|2.529414|2.766234|2.947579|3.119168|0.079313|2.788837|2.646384|3.229337|0.062084|2.230015|3.592491|3.161202|0.060442|2.571611|4.514723|3.615428|4.089487|4.518304|6.674903|7.166737|8.669152|8.946932|17.745816|8.949080|5.650104|4.966366|5.696051|5.618913|6.189241|6.774855|2.842737|5.017342|2.621909|2.026475|0.055518|0.056298|0.064931|0.062980|0.076323|0.073022|0.106068|0.206806|0.500000| |1.976097|2.041918|2.211174|2.300027|2.332455|2.360450|0.060245|2.201005|2.183976|2.756359|0.054608|1.897827|3.139375|2.604211|0.050154|2.038128|3.520309|3.058301|2.829704|2.919230|3.687326|4.140885|5.949898|5.622270|8.957041|17.726929|8.914886|5.663245|4.998247|4.919127|5.712712|5.732501|2.263070|3.907637|2.202717|1.774951|0.051571|0.051399|0.060096|0.056456|0.067990|0.063865|0.071747|0.107674|0.216674|0.500000| |2.094132|2.118705|2.362188|2.384338|2.301765|2.258394|0.056641|2.174305|2.255105|2.900342|0.059005|1.957636|3.275976|2.595994|0.049572|1.982604|3.331973|3.246127|2.589698|2.520495|2.997756|3.558694|5.574402|4.897432|5.638549|8.887446|17.739807|8.936454|5.669326|5.716675|6.957632|6.322202|2.185084|3.649756|2.188286|1.826751|0.055787|0.053505|0.064438|0.061539|0.074528|0.070383|0.061852|0.082258|0.124191|0.214054|0.500000| |2.517594|2.588276|3.078452|3.107239|2.841514|2.730061|0.066129|2.705695|2.950285|3.801028|0.078893|2.463288|4.085346|3.158778|0.058951|2.385902|3.869098|4.392728|3.063949|2.805297|3.225190|4.100932|6.937810|5.609078|4.966249|5.652343|8.889638|17.754541|8.961357|10.094183|12.877202|9.737950|2.570211|4.131795|2.574281|2.193529|0.067983|0.062198|0.077493|0.080961|0.100357|0.100155|0.067421|0.083340|0.107811|0.124072|0.213959|0.500000| |7.122970|8.822948|6.864459|5.923931|6.362784|4.456508|0.112953|3.518763|3.482878|3.838305|0.075089|2.418262|3.775474|3.327326|0.060754|2.815906|4.706833|5.705253|4.251172|3.502160|3.289624|3.732241|8.020284|3.452777|3.034964|2.719575|2.703325|2.990479|3.401196|4.780514|6.760314|5.556798|9.082584|11.942189|17.487524|5.502714|0.143554|0.175852|0.214655|0.139395|0.196905|0.107953|0.086790|0.079156|0.081049|0.068277|0.067687|0.079036|0.500000| |6.763259|8.735501|5.515291|4.943786|5.573889|4.070687|0.111505|3.259398|3.150154|3.531901|0.068856|2.273163|3.568890|3.167514|0.058430|2.685613|4.576164|4.951310|3.619481|3.083574|2.784844|2.982933|6.272759|2.707679|2.436189|2.202560|2.174177|2.361703|2.642604|3.755110|5.216092|4.566548|8.997457|13.496333|17.582022|6.973785|0.138845|0.200568|0.166763|0.123297|0.137890|0.091498|0.080239|0.068369|0.066543|0.056474|0.055382|0.063125|0.302936|0.500000| |6.982707|8.763281|6.839926|5.284975|4.553504|3.457499|0.091227|3.292972|3.568947|4.209364|0.086460|2.609980|4.163681|3.416837|0.062312|2.716659|4.383551|5.967930|2.860088|2.404929|2.191795|2.385447|5.056802|2.232250|1.968971|1.833322|1.890457|2.120530|2.327554|3.575270|5.211063|4.488222|4.628567|6.719237|5.486020|17.541270|0.209383|0.173136|0.141550|0.212496|0.142984|0.113021|0.063003|0.054303|0.052310|0.046749|0.049002|0.059432|0.123088|0.141512|0.500000| |5.499850|8.691773|6.826952|6.606061|6.442448|4.626199|0.125701|4.177318|4.255038|4.720300|0.092280|2.940617|4.545077|4.000021|0.072082|3.339163|5.414042|6.835438|3.536704|2.902617|2.536507|2.714585|5.927304|2.436286|2.124335|1.929753|1.950623|2.182918|2.466573|3.778256|5.315308|4.833102|6.696649|9.408998|6.814076|17.570590|0.141176|0.141298|0.122314|0.177908|0.138125|0.118490|0.076629|0.061893|0.057105|0.049064|0.049877|0.059882|0.138536|0.172467|0.301755|0.500000| |6.949232|8.780115|5.482826|4.620439|4.553854|3.462070|0.095284|3.086064|3.131800|3.636470|0.072566|2.327616|3.701320|3.160428|0.058333|2.585306|4.313311|4.971986|2.896254|2.475729|2.231166|2.380582|4.991746|2.196737|1.967868|1.817609|1.837642|2.020239|2.222522|3.294296|4.671124|4.117535|5.406880|8.155157|6.896240|17.551419|0.170895|0.209284|0.141433|0.143207|0.123129|0.092309|0.065673|0.055469|0.053133|0.046742|0.047543|0.055587|0.142281|0.209333|0.301766|0.302078|0.500000|
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