Version2.4 2021-06-07T03:57:14Z 10.1021/jm300687e Gaussian16 RevisionB.01 PWARBURT 08-Nov-2019 #N HF/6-31G(d) OPT=(MaxStep=1) FREQ IOp(6/10=2,6/11=2,6/12=2) DUDE CCCCCOc1cccc(c1)[C@H]2C(=C(C(=O)N2c3nc4ccc(cc4s3)F)[O-])C(=O)c5cccs5 C33489666 RHF 6-31G(d) (6D,7F) CCCCCOc1cccc(c1)[C@H]2C(=C(C(=O)N2c3nc4ccc(cc4s3)F)[O-])C(=O)c5cccs5 C01[X(C27H22F1N2O4S2)] 168 C1 592 CCCCCOc1cccc(c1)[C@@H]1N(c2nc3c(s2)cc(cc3)F)C(=O)C(=C1C(=O)c1cccs1)[O-] CCCCCOc1cccc(c1)[C@@H]1N(c2nc3c(s2)cc(cc3)F)C(=O)C(=C1C(=O)c1cccs1)[O-] CCCCCOc1cccc(c1)[C@@H]2N(C(=O)C(=C2C(=O)c3sccc3)[O-])c4sc5cc(F)ccc5n4 InChIKey=AJVAJWNVDKVKET-QHCPKHFHSA-M InChI=1S/C27H23FN2O4S2/c1-2-3-4-12-34-18-8-5-7-16(14-18)23-22(24(31)20-9-6-13-35-20)25(32)26(33)30(23)27-29-19-11-10-17(28)15-21(19)36-27/h5-11,13-15,23,32H,2-4,12H2,1H3/p-1/t23-/m0/s1 InChI=1/C27H23FN2O4S2/c1-2-3-4-12-34-18-8-5-7-16(14-18)23-22(24(31)20-9-6-13-35-20)25(32)26(33)30(23)27-29-19-11-10-17(28)15-21(19)36-27/h5-11,13-15,23,32H,2-4,12H2,1H3/p-1/t23-/m0/s1/fC27H22FN2O4S2/h32h/q-1 CCCCCOc1cccc(c1)[C@H]2C(=C(C(=O)N2c3nc4ccc(cc4s3)F)[O-])C(=O)c5cccs5 C01[X(C27H22F1N2O4S2)] 168 C01 592 CCCCCOc1cccc(c1)[C@@H]1N(c2nc3c(s2)cc(cc3)F)C(=O)C(=C1C(=O)c1cccs1)[O-] CCCCCO[C]1[CH][CH][CH][C]([CH]1)[C@@H]1N(C2=N[C]3[C]([CH][C]([CH][CH]3)F)S2)C(=O)[C]([C]1[C](=O)C1=[CH][CH]=CS1)=O CCCCCO[C]1[CH][CH][CH][C]([CH]1)[C@H]2[C](C(=O)C(=O)N2C3=N[C]4[CH][CH][C](F)[CH][C]4S3)C(=O)c5sccc5 InChIKey=XUNSQDFLDLHJLL-QHCPKHFHSA-N InChI=1S/C27H22FN2O4S2/c1-2-3-4-12-34-18-8-5-7-16(14-18)23-22(24(31)20-9-6-13-35-20)25(32)26(33)30(23)27-29-19-11-10-17(28)15-21(19)36-27/h5-11,13-15,23H,2-4,12H2,1H3/t23-/m0/s1 InChI=1/C27H22FN2O4S2/c1-2-3-4-12-34-18-8-5-7-16(14-18)23-22(24(31)20-9-6-13-35-20)25(32)26(33)30(23)27-29-19-11-10-17(28)15-21(19)36-27/h5-11,13-15,23H,2-4,12H2,1H3/t23-/m0/s1 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9.52228
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MUNgauss RevisionA2.1 retrievium 07-Jun-2021 DUDE CCCCCOc1cccc(c1)[C@H]2C(=C(C(=O)N2c3nc4ccc(cc4s3)F)[O-])C(=O)c5cccs5 C33489666 RHF 6-31G(d) (6D,10F) C1 521.100504 |X|Y|Z| 109.520122 95.973574 43.173332
76.845844 26 6 7 16 22 2 2
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|1.757186|2.027348|2.263374|2.747121|3.118392|7.151762|4.814327|3.998439|4.210635|5.591347|8.960584|7.436567|17.560269|0.500000| |1.574203|1.773689|1.983419|2.316232|2.660765|5.716721|3.933118|3.694027|4.312161|6.110098|7.409420|5.195112|12.543023|0.241896|36.858105| |1.432407|1.593120|1.767988|2.022764|2.300576|4.785595|3.223848|3.154482|3.756095|5.110913|5.413683|3.986516|7.882510|0.166723|13.508516|36.858105| |1.441221|1.604554|1.780801|2.040532|2.320534|4.838363|3.257997|3.176634|3.766682|5.110735|5.467359|4.040524|7.956462|0.170409|8.066360|12.375424|36.858105| |1.346184|1.485790|1.636711|1.849544|2.079157|4.241108|2.788525|2.759589|3.226609|4.099337|4.193744|3.311319|5.392990|0.127069|5.427158|7.769731|16.058448|73.516695| |1.593915|1.799229|2.014866|2.360407|2.717492|5.871239|4.053760|3.787221|4.405329|6.247536|7.728725|5.402826|12.930577|0.253912|8.165112|8.103959|13.686070|14.748401|53.358707| |1.625891|1.837981|2.051715|2.403122|2.740237|5.880293|3.940168|3.643259|4.045773|5.195486|6.197499|5.022496|7.613499|0.192415|5.200215|5.174416|7.824704|11.895666|18.891951|36.858105| |1.562085|1.745272|1.945243|2.232569|2.539257|5.253884|3.464186|3.359723|3.767091|4.557214|4.830688|4.072672|5.268625|0.132441|4.094632|4.313331|6.373628|11.420237|11.044598|15.041819|53.358707| |1.577736|1.761578|1.943948|2.219355|2.470468|5.035585|3.177732|3.032798|3.225288|3.653427|3.919579|3.602650|4.103929|0.110614|3.263523|3.335369|4.449732|8.092241|7.368242|8.695144|18.766418|36.858105| |1.499264|1.651560|1.810293|2.021328|2.226422|4.389972|2.714820|2.663474|2.817740|3.061750|3.142269|2.940914|3.199044|0.085887|2.685312|2.783762|3.552125|6.702940|5.429510|5.419700|10.557851|13.692297|36.858105| |1.496339|1.642616|1.777807|1.967715|2.120186|4.119458|2.467873|2.393637|2.456210|2.602435|2.700879|2.623792|2.724680|0.075112|2.315236|2.359182|2.884209|5.355858|4.385442|4.163828|7.025758|7.958941|13.810194|36.858105| |1.571275|1.740545|1.867024|2.086006|2.208827|4.326963|2.534563|2.387690|2.388956|2.528896|2.708954|2.712164|2.742833|0.077938|2.299511|2.290601|2.752784|4.978895|4.288993|4.075337|6.290515|6.942042|7.978323|13.734299|36.858105| |1.661521|1.869369|2.011768|2.300887|2.438539|4.919318|2.881822|2.628298|2.606067|2.811677|3.134793|3.181255|3.222358|0.094164|2.613270|2.550992|3.084153|5.426750|5.016225|4.957069|7.105058|7.833817|6.777132|7.855025|13.880320|36.858105| |1.663915|1.880518|2.057307|2.385503|2.602748|5.397909|3.299577|3.001169|3.055520|3.427052|3.901379|3.804768|4.116361|0.118809|3.191518|3.123557|3.965587|6.879645|6.831232|7.752931|11.022076|13.663325|7.918783|6.911418|8.098970|13.721716|36.858105| |1.727557|1.981637|2.180048|2.600529|2.862621|6.254098|3.908734|3.368220|3.426131|4.058010|5.145773|4.987186|5.940796|0.188373|4.171367|3.857374|4.861210|7.714723|9.507476|10.686192|10.008359|7.448509|4.894953|4.254117|4.719217|6.725245|10.941528|388.023441| |1.538443|1.690892|1.786179|1.966583|2.038846|3.917865|2.243233|2.116500|2.089748|2.175468|2.316666|2.356201|2.330271|0.066651|1.996306|1.980548|2.313531|4.176835|3.533218|3.189521|4.749892|4.667876|5.296120|8.143177|14.247681|8.174645|5.326654|26.258441|97.533100| |1.325605|1.459793|1.608269|1.811733|2.038199|4.139752|2.726166|2.717956|3.205324|4.086195|4.107879|3.221200|5.274787|0.122177|7.895098|15.784884|8.016286|11.842803|7.460843|4.015831|4.860407|2.863477|2.477410|2.125893|2.049794|2.238646|2.667368|22.356357|4.042551|73.516695| |1.586086|1.784817|1.989030|2.312262|2.631728|5.577753|3.731607|3.504310|3.942899|5.083691|5.854514|4.679504|7.279180|0.176283|13.310804|7.603888|5.078697|6.972564|6.959658|3.802841|4.296034|2.651198|2.251532|1.991897|1.995131|2.244255|2.640052|23.739932|3.978440|11.050689|36.858105| |1.485759|1.651337|1.829531|2.083654|2.351039|4.818030|3.156140|3.076722|3.481197|4.253977|4.463047|3.710227|5.116423|0.126208|8.096020|6.476793|4.324824|6.280975|5.556864|3.171497|3.735720|2.332905|2.028593|1.804970|1.793371|1.983013|2.294158|19.791337|3.610160|11.169100|15.748106|73.516695| |1.730355|1.974639|2.195194|2.600586|2.919538|6.316183|4.073451|3.603987|3.756838|4.517334|5.564927|5.132791|6.190684|0.174997|7.485002|4.940744|3.917719|5.624367|5.808236|3.432650|3.874124|2.483965|2.115711|1.910567|1.951361|2.217208|2.558525|23.292358|3.932843|7.460055|12.530615|14.664291|36.858105| |1.829067|2.086442|2.328478|2.740826|3.069018|6.464577|4.044132|3.635844|3.659085|4.081704|4.683322|4.653521|4.592040|0.127919|5.146774|3.817733|3.158014|4.702680|4.644058|2.879684|3.361081|2.198433|1.910408|1.745371|1.782217|2.000094|2.260524|19.809793|3.634753|6.054027|7.484616|11.571397|14.136753|36.858105| |1.949277|2.248944|2.467439|2.927724|3.139606|6.560451|3.806822|3.300095|3.148928|3.374163|3.923004|4.237049|3.820001|0.112686|3.957415|3.089988|2.692905|4.104747|4.018295|2.601605|3.058183|2.054430|1.796727|1.668859|1.727855|1.945719|2.156554|18.790757|3.563615|4.947344|5.029788|7.943955|8.185229|13.282027|36.858105| |1.913331|2.225327|2.401195|2.885700|3.016962|6.449326|3.665973|3.076636|2.926669|3.200916|3.887245|4.271106|3.991004|0.125690|3.982632|3.108298|2.769028|4.221053|4.199500|2.750254|3.182489|2.158724|1.869845|1.746020|1.831409|2.092024|2.314407|20.670903|3.777261|4.912505|4.777806|7.235087|7.654765|8.238127|14.161280|36.858105| |1.749685|2.018633|2.195664|2.634724|2.834487|6.210980|3.753987|3.158685|3.142202|3.669259|4.723656|4.803086|5.530077|0.187785|5.608839|4.092596|3.565328|5.254683|5.477465|3.425952|3.807529|2.520625|2.130037|1.956141|2.046289|2.373071|2.704920|25.492560|4.147481|6.208594|6.609034|8.942107|10.961052|7.486176|7.476614|11.039674|388.023441| |17.541787|8.768463|5.451869|4.037804|3.171195|4.787691|2.285753|2.168220|1.871882|1.725573|1.783526|2.031213|1.605258|0.045796|1.476589|1.348641|1.356884|2.261183|2.033614|1.525452|1.995407|1.486347|1.416208|1.421086|1.497887|1.581337|1.573006|11.591571|3.323685|2.226569|1.489284|2.486491|1.624971|1.711993|1.834752|1.815671|11.796216|0.500000| |17.532739|8.773612|6.768033|4.494549|3.630856|5.236075|2.503705|2.425420|2.067874|1.869044|1.904267|2.169390|1.686090|0.047607|1.539087|1.410078|1.428861|2.383554|2.149436|1.622211|2.140536|1.596845|1.529738|1.532871|1.604303|1.681634|1.676003|12.202485|3.546470|2.321160|1.537647|2.562222|1.658611|1.738518|1.827906|1.795979|11.866298|0.301615|0.500000| |17.532768|8.773625|6.768070|4.494630|3.630905|5.236102|2.504803|2.425773|2.068778|1.870565|1.905993|2.171055|1.687804|0.047637|1.560837|1.419896|1.417470|2.350993|2.120998|1.574890|2.058269|1.513968|1.437859|1.425163|1.485210|1.568418|1.584005|11.755460|3.255989|2.345103|1.585499|2.657356|1.729866|1.848388|1.967424|1.904357|12.290793|0.301614|0.301694|0.500000| |8.860445|17.513857|8.861373|6.871344|4.549687|6.741982|3.008269|2.726231|2.275459|2.097818|2.219720|2.627790|1.966989|0.056807|1.758739|1.584888|1.611856|2.662003|2.472225|1.878269|2.431631|1.825547|1.714219|1.722028|1.844851|1.985083|1.970729|14.645357|4.063374|2.575000|1.751822|2.866810|1.931252|2.009836|2.162557|2.179106|14.252803|0.212656|0.210656|0.172937|0.500000| |8.860390|17.513962|8.861488|6.871674|4.549798|6.742064|3.010168|2.726734|2.276659|2.099956|2.222437|2.630736|1.969695|0.056857|1.791151|1.598761|1.595683|2.617216|2.429557|1.806413|2.313842|1.705398|1.588650|1.574328|1.671025|1.806994|1.826638|13.895932|3.644919|2.607552|1.823010|3.000876|2.045458|2.183801|2.402842|2.379787|15.000303|0.212654|0.172936|0.210655|0.304038|0.500000| |6.880854|8.866293|17.492337|8.843502|6.891516|8.390123|3.753860|3.603289|2.868613|2.505231|2.553445|3.026245|2.165077|0.060741|1.966741|1.752497|1.744391|2.846380|2.659769|1.961610|2.531789|1.836239|1.711899|1.667692|1.733165|1.859456|1.919829|14.544308|3.717458|2.850251|1.997716|3.297444|2.205504|2.381715|2.517281|2.394126|15.385537|0.140526|0.169255|0.204150|0.173830|0.211929|0.500000| |6.880787|8.866305|17.492137|8.843110|6.891305|8.390121|3.750228|3.602166|2.866235|2.501619|2.549345|3.021794|2.161499|0.060681|1.924038|1.734265|1.765616|2.904346|2.716130|2.054754|2.688702|1.989050|1.872375|1.846664|1.929775|2.055529|2.089495|15.411556|4.165201|2.807862|1.905033|3.121818|2.064103|2.160705|2.244623|2.189927|14.581353|0.140525|0.204147|0.169253|0.211930|0.173831|0.303717|0.500000| |4.518795|6.825057|8.822244|17.536331|8.945636|13.169426|4.919020|4.049508|3.153742|2.882215|3.153419|4.043102|2.669421|0.077735|2.287959|2.009788|2.059705|3.334154|3.273395|2.501235|3.165977|2.356492|2.143529|2.112169|2.276646|2.532303|2.583733|19.847345|4.853726|3.187874|2.246038|3.574551|2.508426|2.578053|2.748124|2.790741|18.542148|0.108222|0.119248|0.110945|0.205897|0.170439|0.173240|0.210953|0.500000| |4.518424|6.824088|8.821226|17.537616|8.946936|13.170998|4.927663|4.051382|3.157091|2.887906|3.161384|4.054091|2.676308|0.077865|2.360946|2.038423|2.026277|3.247322|3.176160|2.338434|2.917920|2.113255|1.911601|1.855325|1.971218|2.189904|2.281631|18.089794|4.182006|3.250487|2.402720|3.845867|2.776069|2.981302|3.302228|3.256258|20.289563|0.108214|0.110937|0.119242|0.170412|0.205871|0.210941|0.173228|0.303472|0.500000| |3.643218|4.524368|6.838772|8.839423|17.518744|16.548078|7.108092|6.809492|4.608729|3.764579|3.808450|4.795816|2.973620|0.081724|2.634188|2.276449|2.250604|3.581287|3.518831|2.545971|3.220334|2.266158|2.054993|1.943585|1.999367|2.185189|2.346245|18.387426|4.158483|3.619203|2.665717|4.296118|2.960618|3.212940|3.261852|3.017812|19.771198|0.085391|0.097071|0.102533|0.111875|0.120407|0.205986|0.170251|0.174162|0.213086|0.500000| |3.643744|4.525083|6.840566|8.840603|17.516620|16.544124|7.081531|6.800401|4.598108|3.751723|3.794202|4.777147|2.963939|0.081567|2.533113|2.236389|2.296926|3.699554|3.653323|2.761988|3.566447|2.577091|2.354540|2.247984|2.323244|2.528067|2.681610|20.257217|4.823056|3.532617|2.454878|3.924798|2.639966|2.720519|2.721569|2.633800|18.132495|0.085401|0.102548|0.097086|0.120421|0.111890|0.170295|0.206048|0.213077|0.174185|0.301233|0.500000| |2.646821|3.040406|4.000605|4.671920|7.416077|12.452845|8.876764|17.753133|8.901626|5.640969|4.924389|5.623255|3.528254|0.090914|3.075344|2.700392|2.716805|4.299240|4.274432|3.076169|3.971360|2.702734|2.442966|2.233839|2.224381|2.404127|2.672199|20.601717|4.507203|4.242270|2.977024|4.783114|3.076122|3.182346|2.963312|2.745538|19.481287|0.064385|0.073812|0.073782|0.079984|0.079947|0.113701|0.113809|0.115479|0.115373|0.226018|0.226841|0.500000| |1.975832|2.191342|2.645613|2.976748|3.900747|7.447301|5.670868|8.921569|17.701667|8.972035|5.645008|4.979260|4.082530|0.096537|3.733470|3.421167|3.419135|5.374511|5.155364|3.515782|4.644900|2.948715|2.659290|2.323809|2.225071|2.373011|2.738018|21.043572|4.416920|5.380535|3.470362|5.684736|3.242549|3.207364|2.774983|2.562104|19.329858|0.049621|0.055183|0.055201|0.058790|0.058812|0.074895|0.074852|0.077885|0.077937|0.113635|0.113471|0.216368|0.500000| |1.707961|1.908507|2.212342|2.548825|3.129375|6.510353|4.949192|5.624254|8.950826|17.743143|8.880333|5.660753|6.962516|0.140424|6.524600|6.055852|5.957089|8.438913|8.871669|5.122008|6.327380|3.593749|3.051564|2.554171|2.434945|2.665195|3.254941|26.763074|4.709156|8.637244|5.190987|8.035231|4.231710|3.761172|3.068530|2.914340|24.133317|0.043754|0.047178|0.047229|0.052141|0.052208|0.061385|0.061276|0.068927|0.069086|0.087201|0.086874|0.124207|0.215964|0.500000| |2.235640|2.691301|3.117544|4.125357|4.890086|13.554913|8.968475|5.667159|4.982459|5.640982|8.907131|17.736467|6.960144|0.228052|4.855718|3.728579|3.785327|5.576932|6.853354|4.813601|5.209490|3.503018|2.845232|2.589509|2.748477|3.303735|3.892003|38.340948|5.413425|5.402732|4.463994|6.259509|5.219550|4.639993|4.503127|4.882350|39.562159|0.057269|0.060056|0.060115|0.075305|0.075421|0.082064|0.081915|0.117010|0.117453|0.120991|0.120494|0.124248|0.108004|0.123974|0.500000| |1.432002|1.564544|1.718831|1.899245|2.105018|4.101779|2.559988|2.576978|2.785678|3.013300|2.986402|2.741034|3.025259|0.079418|2.611597|2.767584|3.526344|6.851963|5.151122|4.838643|9.567961|8.930478|17.741969|8.891521|5.650632|4.904018|5.643139|28.914314|9.572933|4.447145|2.194951|3.559893|2.033576|1.844623|1.720294|1.771219|14.291134|0.037541|0.040658|0.038362|0.044791|0.041796|0.045532|0.049491|0.055289|0.049922|0.054656|0.062004|0.066107|0.074604|0.085463|0.072506|0.500000| |1.427553|1.551051|1.669522|1.820838|1.949446|3.722659|2.213148|2.175229|2.230899|2.329293|2.377452|2.314312|2.382398|0.065381|2.070521|2.121436|2.543587|4.760717|3.768871|3.420204|5.646604|5.637185|8.874920|17.738848|8.954764|5.636128|4.974450|24.401998|16.774809|3.450777|1.805750|2.942165|1.732259|1.597089|1.530289|1.591758|12.539623|0.037759|0.040800|0.037805|0.045125|0.041195|0.043633|0.048396|0.054050|0.047638|0.049987|0.057627|0.057180|0.059507|0.063939|0.063220|0.211836|0.500000| |1.708241|1.933460|2.054031|2.358895|2.443068|4.929018|2.807582|2.511819|2.441887|2.613179|2.957596|3.090225|3.040241|0.091229|2.484305|2.385872|2.802037|4.862020|4.536954|4.253389|5.738819|5.575956|4.904625|5.617960|8.954835|17.746294|8.793489|43.626882|16.690889|3.737590|2.172466|3.411045|2.189170|1.984998|1.962211|2.134822|17.047606|0.045409|0.047826|0.044526|0.057589|0.052114|0.052345|0.057909|0.073099|0.062752|0.060429|0.069577|0.064175|0.061541|0.068188|0.091701|0.106734|0.124491|0.500000| |1.797401|2.025765|2.277040|2.627142|2.982803|6.080641|3.856651|3.665701|3.772931|4.098001|4.362086|4.213101|4.120355|0.109582|4.730116|3.671842|3.012359|4.535564|4.326334|2.689189|3.204630|2.088634|1.836382|1.673778|1.691824|1.874715|2.112679|18.041561|3.456902|5.980564|6.776700|11.897912|8.976802|17.759255|8.567708|5.728672|37.843972|0.046564|0.047611|0.050906|0.053740|0.058578|0.065645|0.059034|0.067802|0.078428|0.088977|0.074190|0.090477|0.094147|0.106825|0.111305|0.049747|0.042806|0.051316|0.500000| |2.029624|2.331753|2.541253|2.963091|3.115823|6.251184|3.509872|3.107337|2.913251|3.010917|3.372859|3.688898|3.201287|0.093012|3.284794|2.666641|2.361371|3.661590|3.492821|2.306478|2.762479|1.876328|1.662488|1.556050|1.609880|1.795621|1.964138|16.690967|3.348707|4.345658|4.026445|6.665968|5.708898|8.583515|17.727789|8.914363|37.753430|0.053102|0.052386|0.057483|0.061466|0.070115|0.073154|0.063474|0.075904|0.094419|0.091856|0.074457|0.079730|0.072573|0.076286|0.107115|0.044354|0.039896|0.050421|0.200671|0.500000| |1.947281|2.273335|2.399731|2.871194|2.890480|6.061286|3.306111|2.773729|2.600299|2.791366|3.341507|3.740730|3.417709|0.108562|3.331390|2.703177|2.473991|3.840930|3.747065|2.525595|2.955777|2.043138|1.783443|1.686392|1.785668|2.039745|2.217012|19.525954|3.720293|4.320933|3.803031|5.922881|5.390537|5.684767|8.761253|17.779087|55.272924|0.051788|0.050424|0.053573|0.062211|0.068381|0.065942|0.060352|0.077969|0.091332|0.079377|0.070070|0.069991|0.063870|0.070837|0.120829|0.046723|0.042826|0.058566|0.122396|0.203588|0.500000|
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