Version2.4 2021-04-30T14:59:51Z 10.1021/jm300687e Gaussian16 RevisionB.01 SBUNGAY 31-Oct-2018 #N HF/6-31G(d) OPT=(MaxStep=1) FREQ IOp(6/10=2,6/11=2,6/12=2) DUDE CCN(c1ccccc1F)[C@@H](C[NH3+])c2ccc(s2)Br C50011353 RHF 6-31G(d) (6D,7F) CCN(c1ccccc1F)[C@@H](C[NH3+])c2ccc(s2)Br C01[X(C14H17Br1F1N2S1)] 102 C1 338 CCN(c1ccccc1F)[C@H](c1ccc(s1)Br)C[NH3+] CCN(c1ccccc1F)[C@H](c1ccc(s1)Br)C[NH3+] CCN([C@@H](C[NH3+])c1sc(Br)cc1)c2ccccc2F InChIKey=WFDSKONMGICBFP-LBPRGKRZSA-O InChI=1S/C14H16BrFN2S/c1-2-18(11-6-4-3-5-10(11)16)12(9-17)13-7-8-14(15)19-13/h3-8,12H,2,9,17H2,1H3/p+1/t12-/m0/s1 InChI=1/C14H16BrFN2S/c1-2-18(11-6-4-3-5-10(11)16)12(9-17)13-7-8-14(15)19-13/h3-8,12H,2,9,17H2,1H3/p+1/t12-/m0/s1/fC14H17BrFN2S/h17H/q+1 CCN(c1ccccc1F)[C@@H](C[NH3+])c2ccc(s2)Br C01[X(C14H17Br1F1N2S1)] 102 C01 338 CCN(c1ccccc1F)[C@H](c1ccc(s1)Br)C[NH3+] [NH3]C[C@H](N([C]1[CH][CH][CH][CH][C]1F)CC)C1=[CH][CH]=C(S1)Br CCN([C]1[CH][CH][CH][CH][C]1F)[C@@H](C[NH3])c2sc(Br)cc2 InChIKey=KXBWIZANSPKCOH-LBPRGKRZSA-N InChI=1S/C14H17BrFN2S/c1-2-18(11-6-4-3-5-10(11)16)12(9-17)13-7-8-14(15)19-13/h3-8,12H,2,9H2,1,17H3/t12-/m0/s1 InChI=1/C14H17BrFN2S/c1-2-18(11-6-4-3-5-10(11)16)12(9-17)13-7-8-14(15)19-13/h3-8,12H,2,9H2,1,17H3/t12-/m0/s1 2037.4936486455 -3715.5397373 1-A 7379.6768 87 251 338 |A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A| -490.16838 -92.08989 -64.57998 -58.71943 -58.71737 -58.71730 -26.44872 -15.85820 -15.70914 -11.45349 -11.44228 -11.43672 -11.42148 -11.39187 -11.38916 -11.38044 -11.36263 -11.35350 -11.35080 -11.34980 -11.34954 -11.34249 -11.33950 -9.82842 -9.09990 -7.57822 -7.56836 -7.56826 -6.78240 -6.78141 -6.77961 -3.31743 -3.31261 -3.31256 -3.30108 -3.30108 -1.76050 -1.48900 -1.38950 -1.30468 -1.27232 -1.20955 -1.15820 -1.15446 -1.13800 -1.10705 -1.10293 -1.07245 -1.01492 -0.98885 -0.96207 -0.94661 -0.94174 -0.93042 -0.87801 -0.85575 -0.85070 -0.83033 -0.82462 -0.82083 -0.79767 -0.79388 -0.77948 -0.76307 -0.74445 -0.72708 -0.72279 -0.70771 -0.69291 -0.68797 -0.67050 -0.66053 -0.65076 -0.64713 -0.64143 -0.62376 -0.61999 -0.61686 -0.60736 -0.58894 -0.53780 -0.52011 -0.50654 -0.46826 -0.44909 -0.44607 -0.42670 |A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A| 0.00279 0.01355 0.02287 0.03562 0.05570 0.07220 0.08056 0.10344 0.10542 0.11199 0.12639 0.13616 0.14619 0.16345 0.16986 0.17881 0.18403 0.19591 0.19668 0.20517 0.21544 0.22337 0.22551 0.23283 0.24448 0.25168 0.25549 0.26460 0.26812 0.28279 0.29763 0.31726 0.32232 0.33732 0.35126 0.37039 0.38389 0.39366 0.41353 0.42941 0.43160 0.46299 0.46678 0.49246 0.50494 0.53726 0.55880 0.56050 0.56905 0.57262 0.57544 0.58428 0.59242 0.60914 0.61406 0.61945 0.63497 0.64620 0.65060 0.66150 0.67007 0.68056 0.68671 0.69184 0.70236 0.71578 0.71902 0.72082 0.72762 0.73338 0.74080 0.74892 0.75429 0.75843 0.76685 0.78899 0.79240 0.79496 0.80895 0.82058 0.84106 0.85104 0.86963 0.87080 0.90499 0.92192 0.93142 0.93628 0.94044 0.94860 0.96317 0.97042 0.97895 0.99095 0.99666 1.00171 1.01398 1.01423 1.02286 1.02926 1.03854 1.04579 1.05001 1.05242 1.05453 1.05624 1.07001 1.08085 1.09592 1.09887 1.10783 1.11801 1.12456 1.13614 1.14091 1.16067 1.16496 1.18313 1.19302 1.20261 1.22738 1.24492 1.26267 1.27356 1.28902 1.29267 1.31900 1.33615 1.35434 1.38970 1.40383 1.41422 1.43748 1.45164 1.47431 1.49326 1.52953 1.55220 1.56266 1.57404 1.58777 1.59229 1.62192 1.62697 1.63601 1.65430 1.66389 1.68509 1.69989 1.71152 1.74674 1.75885 1.77473 1.78908 1.84970 1.87710 1.90609 1.93027 1.95669 1.97780 1.98770 1.99557 2.00595 2.02007 2.03474 2.04500 2.05967 2.07304 2.08350 2.11301 2.12637 2.14439 2.15613 2.16210 2.16277 2.18180 2.19924 2.20791 2.22056 2.23130 2.26226 2.29563 2.30283 2.32690 2.33619 2.36219 2.37052 2.38143 2.41897 2.43142 2.43262 2.45158 2.46348 2.48219 2.48269 2.48965 2.51313 2.52372 2.52658 2.54924 2.56263 2.57002 2.58948 2.59560 2.62281 2.65375 2.66624 2.69407 2.74017 2.74634 2.80228 2.80745 2.85033 2.87101 2.88013 2.90285 2.91654 2.93525 2.96572 2.97670 3.01298 3.05154 3.08734 3.11878 3.13229 3.19186 3.22207 3.31577 3.38558 3.48578 3.72293 4.05585 4.24746 4.39200 4.41512 4.42257 4.43264 4.44931 4.50303 4.52538 4.60688 4.65685 4.69081 4.71750 4.78064 4.80333 4.94281 5.01080 5.95117 9.18118 74.51269 11.68692 9.9120 -6.0023 3.8828 12.2210 |XX|YY|ZZ|XY|XZ|YZ| -95.6292 -95.9466 -105.5813 -14.5112 19.4975 -9.1923 |XX|YY|ZZ|XY|XZ|YZ| 3.4231 3.1058 -6.5289 -14.5112 19.4975 -9.1923 |XXX|YYY|ZZZ|XYY|XXY|XXZ|XZZ|YZZ|YYZ|XYZ| 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12.1771 1.7225 4.6326 13.0662 5.0382 5.4531 1.5104 1.0084 7.9943 5.5611 4.9088 0.5342 17.7343 3.8806 2.2439 4.6608 5.1807 11.6313 18.9710 5.9757 4.7294 9.9356 14.1489 12.1484 28.4077 45.8503 9.5786 65.4324 4.0982 5.2244 20.9497 14.8426 0.5462 15.9479 36.1110 0.8846 44.0315 0.1317 9.8955 0.4182 33.6297 8.9365 7.0927 29.5497 16.5444 56.5976 16.7636 25.8787 27.2639 33.1816 12.9974 41.3545 1.4083 6.2709 5.9737 33.1846 9.3276 6.6598 9.5955 2.2534 16.7730 18.5430 108.2166 7.4274 6.4184 16.9551 27.5955 210.1501 71.9549 1.2829 14.4329 39.8718 19.0184 42.1579 26.0841 18.4604 30.0862 22.7120 21.1922 3.9519 24.5358 2.5016 0.7764 6.4742 6.1300 4.2430 1.8377 0.1048 117.1613 213.1291 94.1463 3.3221 3.1442 1.6541 2.0180 1.8202 1.9862 1.1945 0.6349 2.4034 1.1041 1.1972 0.1269 1.3549 1.3155 2.5912 2.7755 2.4752 1.0457 2.9052 0.5377 1.3391 1.0224 1.7227 2.0560 1.4091 1.1381 2.2526 1.3678 5.8368 1.0247 19.9813 4.7016 6.8972 0.4740 2.9550 2.9625 2.6813 2.7043 1.4091 1.0536 1.8630 11.0344 8.3795 3.6057 3.3038 2.6502 0.8976 9.1927 0.5332 16.7047 10.3079 7.4450 3.4137 1.5810 2.6552 3.1207 7.2756 2.1856 5.3069 2.0739 2.1920 5.8616 11.1430 2.4867 14.1705 5.1530 10.0727 12.4069 3.4399 2.3845 6.8127 2.9471 0.5565 182.1213 34.9330 14.9405 10.5538 1.8565 3.2384 2.3461 13.1267 9.5134 14.1819 19.0552 6.0228 77.8944 53.8073 65.2200 73.9492 104.0937 63.7438 42.3653 28.6219 35.5528 80.4220 68.6230 40.7143 222.9395 119.0249 58.6903 41.3889 46.4563 0.7191 0.7385 0.7115 0.7400 0.7346 0.7500 0.6710 0.7454 0.6934 0.4436 0.6152 0.2416 0.7353 0.7368 0.2207 0.1935 0.6389 0.7500 0.2193 0.6157 0.7500 0.7333 0.7490 0.4015 0.7450 0.6734 0.6296 0.6377 0.3411 0.5750 0.0642 0.0416 0.2956 0.7427 0.0746 0.4891 0.3372 0.3547 0.5019 0.5617 0.7431 0.4037 0.5239 0.7275 0.6709 0.6754 0.6800 0.7394 0.0971 0.0419 0.4324 0.2695 0.3580 0.7036 0.3477 0.7045 0.6406 0.4590 0.5768 0.5736 0.5330 0.5798 0.0697 0.4470 0.2465 0.5223 0.6068 0.5975 0.6054 0.7228 0.7385 0.7172 0.7256 0.2632 0.6441 0.7407 0.7493 0.3572 0.7499 0.7371 0.4065 0.7360 0.7411 0.5517 0.7245 0.0204 0.1883 0.4471 0.2406 0.5608 0.1293 0.3353 0.7124 0.7489 0.3804 0.7410 0.6075 0.1219 0.2564 0.0551 0.2620 0.7312 0.8366 0.8496 0.8314 0.8506 0.8470 0.8571 0.8031 0.8541 0.8190 0.6146 0.7618 0.3892 0.8474 0.8485 0.3616 0.3242 0.7797 0.8571 0.3597 0.7621 0.8571 0.8461 0.8565 0.5730 0.8539 0.8049 0.7727 0.7788 0.5087 0.7302 0.1206 0.0799 0.4563 0.8523 0.1388 0.6569 0.5043 0.5236 0.6683 0.7193 0.8526 0.5752 0.6876 0.8423 0.8030 0.8062 0.8096 0.8501 0.1770 0.0804 0.6037 0.4246 0.5272 0.8260 0.5160 0.8267 0.7810 0.6292 0.7316 0.7290 0.6954 0.7340 0.1303 0.6178 0.3955 0.6862 0.7553 0.7481 0.7542 0.8391 0.8496 0.8353 0.8409 0.4167 0.7836 0.8510 0.8567 0.5264 0.8570 0.8487 0.5780 0.8479 0.8513 0.7111 0.8403 0.0401 0.3169 0.6179 0.3878 0.7186 0.2289 0.5022 0.8320 0.8564 0.5512 0.8512 0.7558 0.2174 0.4082 0.1045 0.4152 0.8447 298.150 1.00000 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 6 6 7 6 6 6 6 6 6 9 6 1 6 7 1 1 1 6 6 6 6 16 35 1 1 1 1 1 1 1 1 1 1 1 1 1 12.00000 12.00000 14.00307 12.00000 12.00000 12.00000 12.00000 12.00000 12.00000 18.99840 12.00000 1.00783 12.00000 14.00307 1.00783 1.00783 1.00783 12.00000 12.00000 12.00000 12.00000 31.97207 78.91834 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 4218.5160 11018.7507 12658.2895 0.99996 -0.00904 0.00055 0.00904 0.99996 0.00131 -0.00057 -0.00130 1.00000 1 0.02053 0.00786 0.00684 0.42781 0.16379 0.14257 37.48 60.18 64.54 93.85 125.04 163.10 167.57 212.01 245.49 252.07 294.69 315.89 347.01 354.51 413.59 417.87 435.17 495.90 527.80 538.94 616.86 683.99 764.34 793.02 807.59 830.61 853.63 901.39 918.78 943.90 1022.28 1078.90 1132.52 1176.65 1210.21 1239.71 1251.62 1272.22 1349.69 1362.27 1413.23 1427.42 1473.67 1492.26 1495.65 1536.44 1572.32 1595.10 1629.55 1637.70 1650.10 1683.49 1728.23 1731.85 1758.90 1762.64 1811.01 1838.20 1874.69 1897.48 1924.91 1958.66 1997.11 2035.23 2063.21 2095.73 2116.69 2154.18 2210.51 2218.96 2252.23 2263.29 2332.94 2350.14 2362.32 2362.50 2363.31 2386.06 2397.44 2411.58 2538.26 2565.30 2605.70 2615.59 2627.31 4606.14 4617.07 4681.05 4702.43 4730.29 4752.43 4765.84 4848.44 4869.88 4877.67 4884.77 4898.09 4909.56 4935.65 5171.48 5340.38 5409.65 0.315086 0.332837 0.333782 0.267177 -3715.224651 -3715.206900 -3715.205956 -3715.272561 2.233943D-04 MUNgauss RevisionA2.1 retrievium 30-Apr-2021 DUDE CCN(c1ccccc1F)[C@@H](C[NH3+])c2ccc(s2)Br C50011353 RHF 6-31G(d) (6D,10F) C1 343.027985 |X|Y|Z| 41.446247 28.724611 69.550150 43.585879 13 6 7 16 11 1 1 |36.858105| |12.490708|36.858105| |7.620223|12.908560|53.358707| |5.135033|7.797413|18.078940|36.858105| |4.264984|6.383249|10.422098|13.680806|36.858105| |3.320331|4.438992|6.917761|7.884067|13.776569|36.858105| |3.012838|3.795777|6.127053|6.805440|7.933540|13.734842|36.858105| |3.266236|4.024447|6.958941|7.832830|6.866881|7.940970|13.772707|36.858105| |4.162889|5.337052|10.634873|13.773581|8.059730|6.979471|8.040833|13.843401|36.858105| |4.191939|4.831458|9.451799|8.107372|5.292970|4.669455|5.302688|8.158918|14.107486|97.533100| |6.026693|7.727090|17.645919|7.695653|5.688147|4.150088|3.735907|4.150536|5.700033|12.428349|36.858105| |7.079208|7.746798|12.675972|5.707671|4.575935|3.474631|3.138791|3.429005|4.478722|10.152186|17.595868|0.500000| |4.617841|5.133226|10.579172|6.072919|4.475418|3.615335|3.521303|4.145564|5.607767|14.196214|12.411970|0.250112|36.858105| |5.043591|4.990769|9.386837|5.309742|3.872897|3.221279|3.238935|3.937488|5.334202|15.808697|7.742505|0.198041|12.682504|53.358707| |5.340437|4.805251|8.058228|4.434010|3.411726|2.849251|2.816706|3.305107|4.277780|11.822407|6.821928|0.204054|9.060868|25.702980|0.500000| |5.899148|5.928877|11.622171|6.386025|4.371301|3.573297|3.606307|4.500095|6.506107|20.608821|7.591060|0.188492|9.315169|25.531987|0.321706|0.500000| |4.056482|4.015364|7.171318|4.533916|3.430371|2.978435|3.093416|3.821826|4.923500|15.439497|5.687810|0.145179|9.055059|25.693313|0.323937|0.322357|0.500000| |4.438135|5.717430|10.102995|6.227320|5.649286|4.227930|3.641860|3.772617|4.694621|9.535015|12.596692|0.254936|7.600199|6.805919|0.127419|0.133682|0.115506|36.858105| |4.094469|5.001429|7.369189|4.611816|4.563144|3.577788|3.046231|3.052271|3.608797|7.427054|7.492791|0.204097|5.200737|5.318092|0.105591|0.104856|0.092666|14.117578|36.858105| |3.155270|3.757293|5.498050|3.791445|3.982794|3.347262|2.857881|2.778941|3.120356|6.363095|5.032628|0.132673|4.048585|4.276646|0.084235|0.084313|0.077749|8.169027|13.286896|36.858105| |2.874023|3.455338|5.347337|3.938746|4.183797|3.650379|3.154403|3.040766|3.337826|6.704913|4.803356|0.118203|4.143437|4.278833|0.081840|0.084171|0.079408|7.699063|8.290566|14.189756|36.858105| |3.266094|4.056473|7.059423|5.428787|5.368543|4.511853|3.987726|4.006451|4.582256|9.011786|6.624978|0.143152|5.915435|5.553375|0.100754|0.108901|0.102175|10.933286|7.461785|7.431446|11.043078|388.023441| |2.252275|2.620075|3.948800|3.016524|3.264037|3.098693|2.768607|2.611074|2.713397|5.505001|3.308824|0.083645|3.068364|3.367901|0.064733|0.066566|0.064641|4.427252|4.627833|6.607868|10.209410|43.537934|2539.412838| |17.534504|8.691571|9.164543|4.518191|3.777222|2.987856|2.734458|2.969687|3.745910|8.711264|6.433960|0.243234|4.981281|7.367527|0.171823|0.162368|0.118447|4.674903|4.409515|3.314802|2.963347|23.664193|78.175948|0.500000| |17.573206|8.865534|7.569844|4.225781|3.773039|3.031796|2.731865|2.881265|3.503951|7.786769|4.632892|0.148057|3.678059|5.347040|0.115628|0.123381|0.091914|3.754975|3.647564|2.904764|2.619268|20.382012|71.366043|0.303808|0.500000| |17.549583|8.810780|9.406585|4.980823|3.990407|3.213876|3.028087|3.388215|4.345971|10.411857|5.309620|0.161947|4.516349|7.382688|0.158776|0.187857|0.123185|3.877261|3.476368|2.774221|2.601229|21.424628|70.970991|0.299880|0.301977|0.500000| |8.946551|17.642062|12.535687|7.766244|6.915641|4.911735|4.148630|4.300118|5.504173|10.698495|5.686892|0.150899|4.241407|5.759444|0.111277|0.141894|0.099141|4.618120|4.106998|3.298148|3.112588|25.726806|83.393493|0.173063|0.216067|0.214278|0.500000| |8.827483|17.524807|12.210717|6.432696|6.128398|4.283277|3.523872|3.567286|4.467064|8.930042|7.189579|0.208985|4.625079|5.738507|0.114817|0.129788|0.096451|6.261649|6.034219|4.380940|3.834795|30.236227|96.567280|0.208006|0.213952|0.172943|0.303812|0.500000| |4.402761|6.791837|9.539020|8.926867|17.739212|8.945018|5.650072|4.950565|5.700068|9.576770|5.597612|0.131118|4.142988|4.839418|0.089947|0.108901|0.086563|6.006469|5.232982|4.531133|4.530432|37.802189|116.940622|0.108980|0.111163|0.108926|0.198484|0.206888|0.500000| |2.951786|3.834224|5.619532|5.629568|8.945364|17.741230|8.909923|5.648823|5.008957|8.317214|3.536429|0.084947|3.081707|3.751340|0.069164|0.083366|0.071234|3.745736|3.337386|3.242523|3.525415|28.805245|106.064520|0.074474|0.076866|0.078514|0.117489|0.107047|0.216343|0.500000| |2.587690|3.143760|4.887120|4.918558|5.644037|8.901054|17.739819|8.942799|5.694283|9.608465|3.099101|0.074206|2.979458|3.778697|0.068107|0.084351|0.074940|3.073088|2.648816|2.546769|2.819587|24.326042|87.915952|0.065893|0.066331|0.072476|0.095004|0.082412|0.124244|0.214428|0.500000| |2.896548|3.392008|5.686168|5.620810|4.951769|5.627033|8.840038|17.746665|8.976770|16.813521|3.550838|0.083733|3.725651|5.000274|0.086148|0.114600|0.103185|3.222467|2.660716|2.451500|2.679760|24.500704|80.475307|0.074116|0.071648|0.084961|0.099581|0.083929|0.107532|0.123669|0.212876|0.500000| |3.920029|4.515374|9.308620|6.451782|4.736952|3.967839|4.013079|4.895823|6.595078|16.635010|8.707403|0.174190|17.670501|12.464031|0.180495|0.217496|0.229182|6.736550|4.615856|3.846440|4.185143|45.960596|108.586980|0.111927|0.089472|0.108664|0.109747|0.113592|0.116189|0.092234|0.093553|0.122463|0.500000| |3.975781|4.217919|7.636410|4.597586|3.694995|3.087920|3.001101|3.418763|4.294772|10.646885|8.736320|0.216770|17.649656|12.300292|0.223715|0.181353|0.210180|6.910358|5.162226|4.120869|4.182016|39.855116|106.254621|0.123817|0.091143|0.106600|0.098069|0.110861|0.098196|0.075323|0.072465|0.087455|0.300760|0.500000| |4.512198|5.223628|6.976494|4.150723|4.050567|3.197996|2.747735|2.770439|3.279961|6.901425|6.717667|0.214320|4.683463|5.130775|0.105998|0.101798|0.088690|8.905473|17.727037|8.627727|5.762005|37.682447|128.156675|0.140116|0.113851|0.102652|0.116329|0.183358|0.130076|0.083461|0.066890|0.067787|0.111812|0.130020|0.500000| |2.844438|3.282002|4.602242|3.181464|3.373650|2.918599|2.512481|2.425387|2.675093|5.513224|4.026462|0.110571|3.343938|3.695268|0.073986|0.073111|0.067972|5.700711|8.569783|17.774104|8.924537|37.639227|207.404387|0.083110|0.074583|0.069595|0.081443|0.106642|0.106960|0.080277|0.063272|0.060189|0.088173|0.095428|0.201953|0.500000| 3714.156487 -12899.609089 3646.827189 -216.622978 -5755.248390 2037.493795 -3717.754595 2.000969 403800000000000D 42F2C9C36D6E8401 427B7BFF29976DB8 4105C50000000002 37B16C2614EA0800 421A57AE99C80000