Version2.4 2021-05-21T11:40:41Z 10.1021/jm300687e Gaussian16 RevisionB.01 SBUNGAY 08-Jul-2020 #N HF/6-31G(d) OPT=(MaxStep=1) FREQ IOp(6/10=2,6/11=2,6/12=2) DUDE CCN(c1nc2ccccc2s1)C(=O)C[NH+](C)CC(=O)Nc3ccccc3Br C15449989 RHF 6-31G(d) (6D,7F) CCN(c1nc2ccccc2s1)C(=O)C[NH+](C)CC(=O)Nc3ccccc3Br C01[X(C20H22Br1N4O2S1)] 144 C1 483 CCN(c1nc2c(s1)cccc2)C(=O)C[NH+](CC(=O)Nc1ccccc1Br)C CCN(c1nc2c(s1)cccc2)C(=O)C[NH+](CC(=O)Nc1ccccc1Br)C CCN(C(=O)C[NH+](C)CC(=O)Nc1ccccc1Br)c2sc3ccccc3n2 InChIKey=OSKVHDJNEGBXON-UHFFFAOYSA-O InChI=1S/C20H21BrN4O2S/c1-3-25(20-23-16-10-6-7-11-17(16)28-20)19(27)13-24(2)12-18(26)22-15-9-5-4-8-14(15)21/h4-11H,3,12-13H2,1-2H3,(H,22,26)/p+1 InChI=1/C20H21BrN4O2S/c1-3-25(20-23-16-10-6-7-11-17(16)28-20)19(27)13-24(2)12-18(26)22-15-9-5-4-8-14(15)21/h4-11H,3,12-13H2,1-2H3,(H,22,26)/p+1/fC20H22BrN4O2S/h22,24H/q+1 CCN(c1nc2ccccc2s1)C(=O)C[NH+](C)CC(=O)Nc3ccccc3Br C01[X(C20H22Br1N4O2S1)] 144 C01 483 CCN(c1nc2c(s1)cccc2)C(=O)C[NH+](CC(=O)Nc1ccccc1Br)C CC[N]([C](=O)C[NH](C[C]([NH][C]1[CH][CH][CH][CH][C]1Br)=O)C)C1=N[C]2[C]([CH][CH][CH][CH]2)S1 CCN(C(=O)C[NH](C)CC(=O)N[C]1[CH][CH][CH][CH][C]1Br)C2=N[C]3[CH][CH][CH][CH][C]3S2 InChIKey=LPSKXWGJTMIKCP-UHFFFAOYSA-N InChI=1S/C20H22BrN4O2S/c1-3-25(20-23-16-10-6-7-11-17(16)28-20)19(27)13-24(2)12-18(26)22-15-9-5-4-8-14(15)21/h4-11,24H,3,12-13H2,1-2H3,(H,22,26) InChI=1/C20H22BrN4O2S/c1-3-25(20-23-16-10-6-7-11-17(16)28-20)19(27)13-24(2)12-18(26)22-15-9-5-4-8-14(15)21/h4-11,24H,3,12-13H2,1-2H3,(H,22,26)/f/h22H 3037.9326094766 -4104.9301491 1-A 26404.5741 118 365 483 |A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A| -490.17074 -92.06665 -64.58193 -58.72117 -58.71940 -58.71913 -20.69260 -20.68848 -15.85487 -15.75263 -15.74483 -15.66008 -11.51947 -11.51658 -11.46473 -11.46253 -11.45065 -11.43326 -11.40508 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|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A| 0.00401 0.01299 0.03722 0.04617 0.06069 0.06624 0.06903 0.07829 0.09191 0.09552 0.09923 0.11496 0.12993 0.13344 0.14141 0.14432 0.16325 0.16606 0.17028 0.17333 0.17846 0.18985 0.19330 0.20150 0.20506 0.20950 0.21709 0.22011 0.22748 0.23295 0.23607 0.24518 0.25597 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2.54585 2.56013 2.56492 2.57519 2.58542 2.59263 2.60010 2.61204 2.63045 2.64818 2.66573 2.68048 2.70022 2.72958 2.75240 2.76699 2.77999 2.79734 2.80209 2.81972 2.83406 2.87445 2.87852 2.89283 2.90050 2.90889 2.92199 2.93478 2.95318 2.95405 2.97973 2.99724 3.00496 3.00863 3.01264 3.02256 3.04069 3.04917 3.05612 3.09469 3.11470 3.18701 3.22313 3.23911 3.24694 3.27501 3.31471 3.33669 3.52350 3.54739 3.58493 3.71714 3.75046 4.28539 4.29913 4.37511 4.39840 4.41500 4.43421 4.43556 4.44810 4.45050 4.46486 4.47891 4.48307 4.51609 4.54187 4.60187 4.63965 4.64912 4.65678 4.66202 4.69103 4.73462 4.76990 4.82324 4.83961 4.88854 5.04854 5.07209 9.19875 74.82546 10.69236 -2.1717 -5.2804 -1.5246 5.9096 |XX|YY|ZZ|XY|XZ|YZ| -91.3412 -155.6020 -177.4608 -9.7397 0.2551 2.8556 |XX|YY|ZZ|XY|XZ|YZ| 50.1268 -14.1340 -35.9928 -9.7397 0.2551 2.8556 |XXX|YYY|ZZZ|XYY|XXY|XXZ|XZZ|YZZ|YYZ|XYZ| -114.7040 -36.0413 -34.8185 -69.8214 146.8719 56.5779 -76.9525 -30.9669 5.9416 -34.6696 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3351.5629 3370.3380 3373.8168 3375.5992 3384.4409 3385.7385 3395.4301 3397.2924 3400.5464 3403.4622 3414.0028 3457.1070 3566.4764 3840.7430 7.5192 6.3922 5.5908 5.1569 5.8796 6.8068 7.3043 4.8831 3.7473 3.4312 7.1578 2.7509 4.8036 4.8449 4.7616 4.1126 2.0614 4.2912 1.6252 1.2685 4.5143 5.8384 4.7967 3.9902 7.2227 3.8285 3.3073 2.5059 7.7138 6.0101 4.3182 3.2657 3.6714 3.3968 3.0823 8.3868 2.7459 3.9489 5.1564 3.1053 3.0507 4.3269 3.2439 1.9523 7.0080 6.8408 6.2545 6.4868 3.4742 4.3122 3.9824 3.2618 1.5079 1.4286 1.2437 3.9586 4.3782 3.6314 1.3704 4.3136 1.3951 3.4219 3.6463 2.3290 1.3548 2.0980 1.3659 2.2809 2.3785 6.2921 1.3277 1.3707 2.2385 3.7615 4.0236 3.5249 2.0012 3.5518 1.7658 1.5940 1.4964 1.6930 1.7749 1.2695 1.8636 1.6811 2.1367 2.9792 1.5815 2.9441 1.7250 1.4779 1.8318 1.4983 1.2821 1.4514 1.4284 1.3792 1.3182 1.4167 1.1666 1.2887 1.8015 1.3608 1.8732 1.8249 1.0884 1.6525 1.2088 2.2155 1.1023 1.2445 1.0589 1.1033 2.7639 7.2201 7.2811 5.0657 5.9512 3.1149 10.9830 8.6964 1.0447 1.0550 1.0410 1.0953 1.0670 1.0662 1.0986 1.1092 1.1081 1.0992 1.0881 1.1076 1.0917 1.0897 1.0959 1.1101 1.0945 1.0983 1.0973 1.0936 1.0763 1.0784 0.0001 0.0008 0.0015 0.0033 0.0059 0.0119 0.0192 0.0144 0.0196 0.0222 0.0535 0.0256 0.0701 0.0815 0.1014 0.0946 0.0555 0.1242 0.0515 0.0477 0.2047 0.2937 0.2761 0.2663 0.5095 0.2825 0.3028 0.2574 0.9030 0.7102 0.5643 0.4663 0.5275 0.4995 0.5023 1.5141 0.5358 0.8256 1.0796 0.7203 0.7184 1.0597 0.8150 0.5317 2.0609 2.0645 1.9466 2.2819 1.3205 1.6650 1.5732 1.2891 0.6461 0.6218 0.5507 1.8680 2.1554 1.9295 0.7754 2.4760 0.8328 2.1833 2.3966 1.5526 0.9345 1.4728 0.9792 1.6560 1.7462 4.6561 0.9920 1.0629 1.7590 3.0202 3.3150 2.9605 1.7255 3.0715 1.5676 1.4557 1.3760 1.5811 1.6689 1.2418 1.9271 1.7426 2.3019 3.2865 1.7945 3.4268 2.0401 1.7544 2.2000 1.8468 1.5953 1.8271 1.9345 1.9284 1.9195 2.0711 1.7489 1.9724 2.7614 2.0929 2.8984 2.8413 1.6976 2.5883 1.9097 3.5130 1.7589 1.9945 1.7219 1.7972 4.9459 13.0698 13.4898 9.5682 11.4310 5.9979 23.9844 19.5923 6.3417 6.6444 6.5675 6.9190 6.7804 6.8311 7.1616 7.2526 7.3337 7.3565 7.2976 7.4358 7.3675 7.3594 7.4440 7.5491 7.4568 7.4955 7.5355 7.7011 8.0662 9.3726 2.9115 0.7613 0.4168 0.8550 5.2453 1.1309 4.6652 3.1184 0.8965 3.1695 0.5980 2.0508 7.2263 1.7057 1.5021 2.1489 9.3888 1.8339 5.3111 1.4876 8.3672 5.3162 0.6724 42.0774 36.1520 2.1637 6.9270 6.6284 0.2342 2.9428 2.9903 16.3908 2.5740 72.2105 2.0155 0.0349 16.9254 0.1768 13.3813 2.6150 37.8323 14.3925 11.0986 15.9437 9.1610 11.4826 12.3850 3.2608 0.3698 5.4803 2.8831 6.7268 9.2346 65.8154 76.9610 0.1745 8.4143 31.9533 0.7410 11.2246 1.8300 72.2382 10.8354 6.2020 1.3634 26.4561 3.6130 47.6069 5.8972 38.0749 0.0076 0.3428 6.2396 2.9286 8.9296 13.3593 4.3574 7.1736 1.9161 1.9108 34.7626 8.8628 107.1079 51.9325 10.3666 7.9620 9.0486 36.6096 85.3354 362.8909 4.3300 17.4871 15.0764 26.1436 42.6694 343.0682 170.9005 192.6455 81.6911 259.0715 17.5099 12.2126 35.0555 50.7511 42.3110 95.1859 9.4395 22.4627 1.6182 24.7946 3.2423 36.7305 34.5151 27.2776 419.0798 131.7434 76.9940 1.4660 56.1392 297.6938 383.1620 336.3179 29.8194 6.2834 12.2295 27.4505 27.1338 15.8391 20.2619 0.6573 1.1305 4.6214 0.3737 1.2217 4.6315 1.6643 15.5524 0.0481 6.8111 14.4249 3.4692 1.2902 124.4877 97.2111 0.4859 2.1521 2.1989 6.4139 1.1473 1.6138 0.3943 1.7149 2.6268 0.8659 0.8081 0.2021 2.9388 1.8773 1.0426 1.4826 0.1494 1.5939 0.4030 0.1036 1.2276 2.0639 2.8524 1.1667 4.3957 2.4879 1.7767 1.3426 3.8150 1.5012 1.1204 0.4542 0.3019 2.7292 0.8374 11.1223 0.6829 0.0592 3.8860 1.6498 4.4578 2.1200 3.8094 3.2995 5.3505 3.5343 2.3390 7.4404 4.6795 1.7846 1.7190 2.6817 4.0840 0.3010 0.7190 2.5410 2.4632 12.4845 1.9905 7.7818 2.4313 4.8016 16.1950 2.7444 0.0678 6.0639 0.3479 8.6844 23.4342 12.6298 0.4343 0.6077 19.6098 7.4517 3.2612 19.2050 2.8253 32.8391 2.2649 5.6561 0.9484 43.9887 2.0311 0.2902 20.6166 4.2306 30.4658 15.8555 24.5376 84.0295 2.5520 9.2183 77.3755 16.8511 6.2574 10.4265 19.4956 4.1844 4.5999 5.3735 5.5243 5.3607 3.6069 4.2260 11.6250 35.8825 18.6876 29.1398 22.9742 7.9030 16.0022 12.4082 10.0860 13.8334 4.5969 408.1740 36.6856 85.0907 8.9902 25.1702 52.7860 53.7425 88.7561 5.6532 97.9745 109.7547 22.6039 166.0873 38.3221 21.8492 34.4396 31.1101 41.1314 57.9144 110.0957 57.5839 93.1288 45.3875 121.6887 261.1533 164.5028 63.1654 41.6855 58.1203 0.7392 0.7452 0.7500 0.7471 0.6724 0.7208 0.6857 0.7018 0.7052 0.7248 0.7372 0.7219 0.5456 0.5937 0.7154 0.3757 0.6396 0.7462 0.3829 0.2887 0.3988 0.2801 0.7490 0.6878 0.2646 0.2423 0.1590 0.0936 0.6382 0.6032 0.4914 0.7259 0.3716 0.7487 0.2159 0.3437 0.6161 0.4041 0.7206 0.6022 0.7091 0.2548 0.6386 0.4889 0.7413 0.1592 0.1976 0.1304 0.3902 0.6734 0.7405 0.7427 0.3683 0.7358 0.7284 0.4488 0.7481 0.0679 0.7499 0.1075 0.6879 0.4295 0.3031 0.3862 0.6732 0.1747 0.6734 0.6187 0.1339 0.2350 0.7484 0.6590 0.1216 0.2620 0.7432 0.4724 0.1100 0.6484 0.2517 0.0735 0.6902 0.2863 0.6146 0.4579 0.2412 0.2425 0.1638 0.2751 0.2595 0.2951 0.6757 0.7488 0.3063 0.3818 0.4360 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0.6072 0.4271 0.6103 0.7636 0.6892 0.8193 0.7473 0.8407 0.3097 0.7917 0.5472 0.5854 0.8504 0.5489 0.6929 0.5660 0.8382 0.7207 0.8542 0.5916 0.5746 0.5291 0.2380 0.7202 0.8515 0.5492 0.3981 0.4040 0.1074 0.7156 0.0857 0.5911 0.7371 0.1023 0.8077 0.8502 0.8133 0.6654 0.8508 0.7203 0.8556 0.8451 0.5894 0.8543 0.5841 0.2048 0.2665 0.3355 0.2873 0.2575 298.150 1.00000 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 6 6 7 6 7 6 6 6 6 6 6 16 6 8 6 7 1 6 6 6 8 7 6 6 6 6 6 6 35 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 12.00000 12.00000 14.00307 12.00000 14.00307 12.00000 12.00000 12.00000 12.00000 12.00000 12.00000 31.97207 12.00000 15.99491 12.00000 14.00307 1.00783 12.00000 12.00000 12.00000 15.99491 14.00307 12.00000 12.00000 12.00000 12.00000 12.00000 12.00000 78.91834 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 4325.1196 47347.6515 50358.2692 0.99992 -0.01286 0.00073 0.01286 0.99986 -0.01063 -0.00060 0.01064 0.99994 1 0.02003 0.00183 0.00172 0.41727 0.03812 0.03584 7.09 20.53 30.90 47.33 59.23 78.39 96.16 101.63 135.68 150.64 162.04 180.86 226.51 243.16 273.59 284.26 307.68 318.93 333.76 363.57 399.19 420.42 449.68 484.20 497.85 509.13 567.18 600.81 641.31 644.36 677.60 708.30 710.49 718.76 756.66 796.43 828.02 857.08 857.68 902.75 909.62 927.62 939.53 978.24 1016.47 1029.74 1045.71 1111.75 1155.62 1164.73 1178.10 1178.38 1226.99 1236.63 1247.34 1287.62 1315.19 1366.32 1409.99 1420.10 1448.20 1497.24 1519.63 1530.40 1556.76 1570.54 1587.07 1597.14 1606.06 1612.43 1620.24 1650.63 1661.61 1679.61 1701.38 1717.80 1740.50 1743.07 1766.08 1791.27 1797.41 1811.44 1817.57 1853.86 1906.09 1908.41 1945.54 1968.71 1996.61 2022.25 2038.44 2042.29 2054.19 2081.03 2090.87 2103.10 2181.39 2216.38 2261.88 2266.35 2295.06 2318.99 2320.70 2324.55 2331.62 2338.85 2340.95 2345.89 2356.06 2360.36 2367.79 2372.97 2390.22 2392.35 2507.44 2521.92 2551.37 2576.10 2597.82 2601.05 2769.96 2813.46 4618.32 4704.03 4708.03 4711.02 4725.23 4744.46 4785.79 4792.95 4822.15 4849.16 4854.17 4856.73 4869.46 4871.32 4885.27 4887.95 4892.63 4896.82 4911.99 4974.01 5131.36 5525.97 0.432858 0.457695 0.458639 0.372058 -4104.497292 -4104.472454 -4104.471510 -4104.558091 2.903941D-04 MUNgauss RevisionA2.1 retrievium 21-May-2021 DUDE CCN(c1nc2ccccc2s1)C(=O)C[NH+](C)CC(=O)Nc3ccccc3Br C15449989 RHF 6-31G(d) (6D,10F) C1 461.064684 |X|Y|Z| 46.090767 23.037755 154.111492 54.696941 22 6 7 16 17 4 1 |36.858105| |12.503381|36.858105| |7.605476|12.859155|53.358707| |5.911789|7.759731|18.324609|36.858105| |5.879646|7.083386|11.210512|15.059676|53.358707| |4.216963|4.674286|7.351560|8.693659|18.688891|36.858105| |3.583888|3.781797|5.442668|5.414763|10.517361|13.682970|36.858105| |2.879558|3.004898|4.390817|4.178856|7.032693|8.008192|13.837660|36.858105| |2.650656|2.794015|4.258023|4.073881|6.261348|6.905022|7.888330|13.618881|36.858105| |2.867798|3.088460|4.977204|4.992441|7.126781|7.861132|6.764223|7.881423|13.819463|36.858105| |3.582140|3.980279|6.767831|7.841235|11.094629|13.726838|7.901109|6.933181|8.035918|13.710326|36.858105| |3.950919|4.612391|9.234804|10.840329|10.032362|7.406964|4.872166|4.253130|4.695144|6.718324|10.891566|388.023441| |5.668991|7.669930|19.292385|7.932223|7.330107|4.150298|3.220654|2.743360|2.752768|3.251870|4.176478|43.568223|36.858105| |4.333057|5.278769|11.466402|6.862787|6.426429|3.964613|3.076876|2.707019|2.812959|3.423793|4.312023|49.611477|15.855094|73.516695| |5.279004|6.625339|10.497275|5.019782|5.422774|3.189968|2.633628|2.281844|2.263972|2.579584|3.138343|29.173272|12.406785|14.490115|36.858105| |3.798038|4.387111|7.017901|3.934741|4.343927|2.711965|2.279471|2.034643|2.060890|2.356256|2.771571|25.793778|7.796765|13.260430|12.777313|53.358707| |3.656064|4.109283|6.949113|4.076660|4.414041|2.802868|2.333508|2.099693|2.156916|2.502277|2.939039|28.261911|7.928091|16.238243|9.339405|25.474107|0.500000| |3.157209|3.768981|5.988348|3.562730|4.000551|2.556836|2.168920|1.958787|1.998315|2.282233|2.643298|24.274978|6.064101|11.070162|7.693283|17.285888|0.262339|36.858105| |3.364691|3.616694|5.305824|3.115357|3.610766|2.295727|1.984035|1.788669|1.801396|2.019718|2.320473|20.499063|5.098381|8.639010|7.639068|17.437856|0.260712|7.701645|36.858105| |2.759238|2.903580|4.351828|2.711666|3.169945|2.078637|1.811871|1.663637|1.699054|1.908456|2.146599|18.852047|4.059847|7.518351|5.065249|10.612334|0.218416|6.170575|12.418692|36.858105| |2.694612|2.852406|4.445323|2.838674|3.272037|2.172704|1.878279|1.736707|1.797194|2.044483|2.291761|20.555119|4.215987|8.395075|4.803583|9.953732|0.248676|6.076390|8.111424|15.877444|73.516695| |2.415771|2.494948|3.616097|2.296920|2.753281|1.824151|1.617394|1.494978|1.520499|1.684939|1.869331|15.914642|3.204418|5.809901|3.911286|7.127134|0.141275|4.588918|7.908923|14.272190|14.858774|53.358707| |2.074757|2.123323|3.079343|2.013116|2.441560|1.646091|1.474044|1.378310|1.409669|1.555011|1.698723|14.242556|2.660196|4.911209|3.070620|5.285634|0.109169|3.598932|5.022961|7.682511|11.439253|18.274007|36.858105| |1.980194|2.020883|2.981863|1.988168|2.406166|1.642350|1.469809|1.385558|1.430502|1.585149|1.716970|14.424246|2.570568|4.879526|2.841510|4.835219|0.104969|3.314991|4.219473|6.321943|11.529645|10.522910|13.716818|36.858105| |1.737433|1.763954|2.581452|1.749924|2.145170|1.480971|1.339308|1.273113|1.316464|1.447943|1.549008|12.776774|2.175148|4.114207|2.355884|3.850174|0.082849|2.705078|3.237115|4.339295|7.937825|6.972527|7.935416|13.762614|36.858105| |1.610342|1.631370|2.350184|1.591965|1.971304|1.360657|1.240178|1.179174|1.212334|1.322226|1.411146|11.487258|1.953619|3.632611|2.134752|3.419915|0.071721|2.430928|2.901763|3.687536|6.397168|6.166941|6.836425|7.915208|13.774324|36.858105| |1.659115|1.682802|2.395512|1.603784|1.989590|1.362138|1.242179|1.174229|1.199109|1.304042|1.400315|11.388899|1.990705|3.643146|2.225137|3.565336|0.072959|2.533806|3.124501|3.904675|6.376686|7.019250|7.887431|6.863830|7.969726|13.772225|36.858105| |1.866169|1.901214|2.704839|1.780974|2.192162|1.484316|1.343947|1.260509|1.283197|1.401409|1.520526|12.508530|2.280351|4.143067|2.620644|4.305843|0.086762|3.015680|3.981743|5.172044|7.854313|10.733261|13.683058|7.958155|6.926642|7.968800|13.793960|36.858105| 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