Version2.4 2021-06-01T22:05:03Z 10.1021/jm300687e Gaussian16 RevisionB.01 PWARBURT 03-Dec-2020 #N HF/6-31G(d) OPT=(MaxStep=1) FREQ IOp(6/10=2,6/11=2,6/12=2) DUDE CCOC(=O)[C@H]1[C@H](SC=C1c2ccc(o2)C)NC(=O)CSc3nc(c(nn3)CCC(=O)[O-])[O-] C39703924 RHF 6-31G(d) (6D,7F) CCOC(=O)[C@H]1[C@H](SC=C1c2ccc(o2)C)NC(=O)CSc3nc(c(nn3)CCC(=O)[O-])[O-] C01[X(C20H20N4O7S2)] 153 C1 543 CCOC(=O)[C@H]1[C@H](SC=C1c1ccc(o1)C)NC(=O)CSc1nnc(c(n1)[O-])CCC(=O)[O-] CCOC(=O)[C@H]1[C@H](SC=C1c1ccc(o1)C)NC(=O)CSc1nnc(c(n1)[O-])CCC(=O)[O-] CCOC(=O)[C@H]1[C@@H](NC(=O)CSc2nnc(CCC([O-])=O)c([O-])n2)SC=C1c3oc(C)cc3 InChIKey=DZHLHGXKGOMYGA-AEFFLSMTSA-L InChI=1S/C20H22N4O7S2/c1-3-30-19(29)16-11(13-6-4-10(2)31-13)8-32-18(16)21-14(25)9-33-20-22-17(28)12(23-24-20)5-7-15(26)27/h4,6,8,16,18H,3,5,7,9H2,1-2H3,(H,21,25)(H,26,27)(H,22,24,28)/p-2/t16-,18+/m1/s1 InChI=1/C20H22N4O7S2/c1-3-30-19(29)16-11(13-6-4-10(2)31-13)8-32-18(16)21-14(25)9-33-20-22-17(28)12(23-24-20)5-7-15(26)27/h4,6,8,16,18H,3,5,7,9H2,1-2H3,(H,21,25)(H,26,27)(H,22,24,28)/p-2/t16-,18+/m1/s1/fC20H20N4O7S2/h21H/q-2 CCOC(=O)[C@H]1[C@H](SC=C1c2ccc(o2)C)NC(=O)CSc3nc(c(nn3)CCC(=O)[O-])[O-] C01[X(C20H20N4O7S2)] 153 C01 543 CCOC(=O)[C@H]1[C@H](SC=C1c1ccc(o1)C)NC(=O)CSc1nnc(c(n1)[O-])CCC(=O)[O-] CCOC(=O)[C@H]1[C@H](SC=C1C1=[CH][CH]=C(O1)C)NC(=O)CS[C]1[N]N=C([C]([N]1)=O)CC[C]([O])[O] CCOC(=O)[C@H]1[C@@H](NC(=O)CS[C]2[N]N=C(CC[C]([O])[O])C(=O)[N]2)SC=C1c3oc(C)cc3 InChIKey=NKUIKADUVZLADK-AEFFLSMTSA-N InChI=1S/C20H20N4O7S2/c1-3-30-19(29)16-11(13-6-4-10(2)31-13)8-32-18(16)21-14(25)9-33-20-22-17(28)12(23-24-20)5-7-15(26)27/h4,6,8,16,18H,3,5,7,9H2,1-2H3,(H,21,25)/t16-,18+/m1/s1 InChI=1/C20H20N4O7S2/c1-3-30-19(29)16-11(13-6-4-10(2)31-13)8-32-18(16)21-14(25)9-33-20-22-17(28)12(23-24-20)5-7-15(26)27/h4,6,8,16,18H,3,5,7,9H2,1-2H3,(H,21,25)/t16-,18+/m1/s1/f/h21H 3850.7523162530 -2305.8559148 1-A 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43 44 45 46 47 48 49 50 51 52 53 6 6 8 6 8 6 1 6 1 16 6 6 6 6 6 6 8 6 7 6 8 6 16 6 7 6 6 7 7 6 6 6 8 8 8 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 12.00000 12.00000 15.99491 12.00000 15.99491 12.00000 1.00783 12.00000 1.00783 31.97207 12.00000 12.00000 12.00000 12.00000 12.00000 12.00000 15.99491 12.00000 14.00307 12.00000 15.99491 12.00000 31.97207 12.00000 14.00307 12.00000 12.00000 14.00307 14.00307 12.00000 12.00000 12.00000 15.99491 15.99491 15.99491 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 15013.1657 18879.0255 29824.4763 0.99929 0.03671 0.00828 -0.03677 0.99930 0.00720 -0.00801 -0.00749 0.99994 1 0.00577 0.00459 0.00290 0.12021 0.09560 0.06051 12.24 26.58 36.97 48.18 57.40 60.48 64.49 81.61 92.48 105.79 123.01 124.07 146.02 150.53 160.39 176.74 200.59 212.71 231.14 232.59 243.58 260.44 290.91 299.21 307.36 336.70 369.07 397.56 411.93 428.87 448.82 474.70 480.20 517.93 567.36 571.84 577.13 628.43 680.02 703.07 711.46 769.07 781.07 807.02 863.78 880.01 892.26 948.55 987.34 994.34 1010.32 1035.29 1047.16 1051.93 1094.38 1106.76 1120.82 1130.60 1190.31 1194.38 1220.17 1268.52 1276.38 1279.60 1280.78 1290.21 1316.41 1350.50 1376.11 1388.73 1407.08 1420.09 1441.23 1458.05 1489.51 1540.99 1552.68 1570.02 1586.15 1600.06 1609.90 1613.40 1625.65 1676.25 1690.33 1729.08 1730.13 1770.42 1783.39 1798.08 1846.45 1870.63 1872.60 1911.01 1944.16 1953.30 1972.01 1975.19 1989.73 1999.84 2029.19 2035.69 2043.64 2063.87 2079.25 2094.57 2156.33 2174.26 2184.35 2187.15 2220.39 2227.24 2237.06 2256.52 2277.64 2310.82 2328.29 2339.03 2339.75 2355.51 2356.48 2370.81 2399.86 2411.73 2507.76 2514.49 2584.32 2604.21 2634.13 2687.48 2708.62 2782.36 2872.91 4543.53 4589.65 4612.94 4626.95 4697.20 4697.85 4701.53 4704.72 4716.84 4725.18 4732.01 4764.45 4771.11 4780.48 4798.37 4849.84 4885.29 4924.99 4950.97 5368.91 0.424747 0.455197 0.456141 0.357521 -2305.431167 -2305.400718 -2305.399774 -2305.498394 3.307731D-04 MUNgauss RevisionA2.1 retrievium 01-Jun-2021 DUDE CCOC(=O)[C@H]1[C@H](SC=C1c2ccc(o2)C)NC(=O)CSc3nc(c(nn3)CCC(=O)[O-])[O-] C39703924 RHF 6-31G(d) (6D,10F) C1 492.077343 |X|Y|Z| 84.210244 95.044666 35.836378 65.948602 20 6 7 8 16 13 4 1 2 |36.858105| |12.604502|36.858105| |7.999549|13.195436|73.516695| |5.274942|8.026662|25.888414|36.858105| |4.570749|6.995681|15.235118|16.017205|73.516695| |4.074739|5.144026|14.527222|12.452421|14.073883|36.858105| |4.162547|4.970335|13.916019|8.960464|10.671590|17.608975|0.500000| |3.137923|3.863839|9.173833|7.345358|11.596628|12.384758|0.246073|36.858105| |2.828299|3.324374|7.698052|5.487236|8.553791|8.938128|0.226226|17.670444|0.500000| |2.734414|3.288502|7.249285|5.462990|9.840400|6.994709|0.145235|10.201497|0.224125|388.023441| |3.073227|3.587138|8.260297|5.835780|9.329390|7.959074|0.163730|7.505867|0.184341|77.147516|36.858105| |3.737057|4.378399|11.178231|7.699738|10.487948|12.488775|0.243979|7.836669|0.190674|51.620087|14.363258|36.858105| |4.033989|4.320113|10.553502|5.884471|8.157842|7.301421|0.187905|5.007708|0.131919|33.571788|7.729157|13.034771|36.858105| |3.740937|3.810041|8.336117|4.508476|6.781863|4.937607|0.127819|3.805315|0.100757|27.694926|5.989008|7.390097|14.162912|36.858105| |3.751183|3.535853|7.409233|3.759493|5.666716|4.024619|0.112143|3.166024|0.085955|21.934131|4.243295|5.179639|8.559929|13.240215|36.858105| |4.062230|3.774375|8.236206|4.032442|5.846964|4.462887|0.133472|3.399377|0.093846|22.008364|4.124895|5.369074|8.719713|8.567460|14.194825|36.858105| |4.259196|4.279697|10.403400|5.237558|7.138652|6.405763|0.198917|4.451717|0.122632|27.232674|5.308023|7.940692|14.112332|8.654190|8.666264|14.173984|73.516695| |3.800441|3.367052|6.970114|3.363863|4.982743|3.638208|0.113334|2.900143|0.081388|18.351685|3.199565|3.965342|5.333961|5.143157|7.317404|12.791914|14.049711|36.858105| |2.996976|3.754202|8.298965|6.425968|11.473746|7.618549|0.181992|13.429988|0.260298|48.604151|4.951505|5.118953|3.776349|3.046184|2.638606|2.833117|6.273272|2.518240|53.358707| |2.506329|3.004456|6.310366|4.427111|7.958040|5.143828|0.134526|7.903360|0.210772|38.317386|3.951478|3.938415|3.087618|2.572362|2.280806|2.444320|5.249777|2.227223|19.199278|36.858105| |2.253257|2.624118|5.505564|3.744792|6.577520|4.552875|0.120997|6.925805|0.218823|37.737920|3.898757|3.759942|2.980176|2.502951|2.224489|2.375506|5.066352|2.168076|11.526643|15.786366|73.516695| |2.353274|2.802979|5.577445|3.734879|6.950495|3.928981|0.105761|5.068716|0.133092|27.883661|3.077936|3.107063|2.565817|2.199213|1.990929|2.126975|4.437538|1.979943|10.703032|12.561945|14.214277|36.858105| |2.347258|2.717384|5.316917|3.339786|5.927579|3.474200|0.100093|4.028238|0.110548|21.803086|2.622395|2.755757|2.377735|2.044968|1.904811|2.074801|4.278289|1.988963|7.395810|6.777943|9.626123|10.482972|388.023441| |2.835004|3.352740|6.370015|3.884646|6.884524|3.734021|0.108925|3.955272|0.102911|21.134645|2.645126|2.876013|2.520992|2.164490|2.030046|2.227067|4.587222|2.145052|7.103682|5.269559|7.329676|6.708920|75.192721|36.858105| |2.686739|3.045977|5.606314|3.251466|5.678958|3.119099|0.092681|3.184088|0.084837|17.713854|2.288625|2.497305|2.262506|1.973361|1.888097|2.079413|4.191404|2.048952|5.288263|3.932977|5.875097|4.740412|52.204749|14.560993|53.358707| |2.972605|3.322478|5.835477|3.244410|5.656902|2.983505|0.088609|2.907098|0.076374|16.526141|2.192519|2.420175|2.240734|1.974613|1.908999|2.102451|4.179563|2.089783|4.641014|3.284049|4.977030|3.744060|34.953921|8.426326|19.076277|36.858105| |3.692123|4.332897|7.255337|3.965599|7.007509|3.401487|0.099199|3.195037|0.081070|18.132374|2.425776|2.711958|2.502316|2.198345|2.105727|2.307962|4.617772|2.256099|5.082323|3.382650|5.026137|3.722121|30.931813|7.389430|10.755770|12.792754|36.858105| |3.919598|5.025401|8.704979|5.062285|9.248414|4.143239|0.117249|3.918721|0.095701|21.603754|2.823736|3.160517|2.816335|2.432547|2.273829|2.477200|5.078410|2.355201|6.524986|4.119886|5.863849|4.491744|34.570377|8.466094|9.440217|7.885785|14.920060|53.358707| |3.303715|4.153239|7.902062|5.010392|9.179375|4.478101|0.125968|4.635639|0.113243|24.261515|3.014713|3.310678|2.841454|2.416662|2.228663|2.429266|5.072185|2.290029|8.673777|5.633192|7.473902|6.572890|50.971091|14.686658|10.950906|6.908983|8.292525|19.014769|53.358707| |4.099345|4.541740|6.940531|3.579684|6.322310|3.001917|0.086863|2.732829|0.069559|16.174717|2.229141|2.496907|2.380041|2.140271|2.082138|2.264529|4.408409|2.237473|4.132045|2.732701|4.187381|2.909085|23.004333|4.660707|6.818814|7.317440|12.618716|10.842678|7.062975|36.858105| |4.718763|4.674367|7.142642|3.460699|5.808601|2.967244|0.088426|2.611541|0.067591|15.438649|2.199677|2.513181|2.477501|2.236263|2.233309|2.473563|4.734523|2.513524|3.788453|2.497872|3.914948|2.565403|20.334042|3.870951|5.702125|5.674213|7.433328|7.666322|5.670298|12.392622|36.858105| |5.131491|4.581959|6.577961|3.123521|5.298335|2.655545|0.077560|2.316153|0.059906|14.205482|2.062750|2.341991|2.368330|2.199306|2.225998|2.422223|4.492821|2.470449|3.274170|2.155033|3.430293|2.182431|16.686968|2.992908|4.272753|3.923292|4.858111|5.674909|4.429790|7.333457|12.252506|36.858105| |5.781040|5.242292|6.960967|3.301440|5.739882|2.711992|0.077195|2.355031|0.060029|14.712522|2.138744|2.413596|2.432851|2.282890|2.279821|2.430087|4.506525|2.415771|3.319311|2.157879|3.421268|2.176426|16.157322|2.871926|3.967391|3.538468|4.540666|5.663167|4.387014|6.657696|8.011663|15.330593|73.516695| |4.333239|3.718790|5.609716|2.689034|4.524440|2.364789|0.069617|2.077171|0.054541|12.864253|1.882757|2.128266|2.186307|2.054304|2.119063|2.311388|4.197985|2.417953|2.902606|1.937959|3.131008|1.954912|15.040381|2.615163|3.783440|3.390230|3.883797|4.580643|3.761415|5.246785|8.041339|15.445649|15.213154|73.516695| |2.720724|2.917897|5.042497|2.749269|4.776612|2.553956|0.075946|2.472257|0.065832|14.444461|1.943940|2.136036|2.017368|1.804255|1.768252|1.943651|3.789713|1.963123|3.824565|2.736038|4.273154|3.066083|27.882878|5.607056|11.449060|15.688435|8.073492|7.397779|6.530265|6.575637|5.586165|3.943827|6.110237|6.286754|73.516695| |17.510321|8.838332|12.559995|4.911276|7.550371|3.965977|0.110643|3.036087|0.076601|19.465543|3.196483|3.895674|4.462163|4.350063|4.460185|4.659417|8.255512|4.209662|3.828756|2.362611|3.837358|2.186397|15.283668|2.513387|3.228379|2.565416|3.077902|4.474660|3.933452|3.324171|3.734296|4.057451|7.995833|6.441251|4.207519|0.500000| |17.611370|8.957433|10.213287|4.273378|7.016322|3.375059|0.095050|2.731493|0.068840|17.246068|2.656001|3.111985|3.297730|3.137684|3.163574|3.349867|6.108324|3.221669|3.638978|2.282699|3.652802|2.191142|15.664248|2.675065|3.515522|2.917528|3.639263|5.082986|4.195220|4.301843|5.011702|6.137459|13.637643|8.984008|4.838101|0.296419|0.500000| |17.576035|8.893176|13.157418|4.929757|7.334840|4.070142|0.122150|3.129297|0.079998|18.799214|2.963907|3.655337|3.986968|3.602364|3.737952|4.289274|8.001549|4.244480|4.072170|2.529719|4.060947|2.374772|17.284053|2.952190|3.870158|3.165612|3.857158|5.401479|4.579629|4.243836|5.273013|5.500154|9.882907|8.496004|5.185512|0.300071|0.303555|0.500000| |8.830552|17.690220|16.507514|7.027912|11.817138|4.695881|0.128808|3.749440|0.089833|22.121687|3.221781|3.815971|3.635583|3.194225|2.993582|3.227104|6.505700|2.977802|5.262538|3.127772|4.762136|3.015962|21.224468|3.881713|4.809789|3.985021|5.624475|9.067321|6.754459|6.019468|5.831200|5.362421|10.981623|7.287161|6.086122|0.173061|0.217317|0.209204|0.500000| |8.802126|17.625089|16.458177|7.375528|13.284904|4.729889|0.119925|3.701158|0.087434|23.847970|3.642691|4.257880|4.140318|3.800051|3.418093|3.473549|6.875697|3.033199|4.877774|2.878053|4.491476|2.687838|17.991262|3.039663|3.733417|2.948187|3.767861|5.998761|5.116244|3.943089|3.879203|3.926792|8.268626|5.784386|4.639826|0.214072|0.207231|0.173414|0.301357|0.500000| |2.782090|3.137962|6.868971|4.528952|7.489779|5.566767|0.126167|5.333121|0.139676|54.853168|17.740570|8.961062|6.869705|6.223927|4.312343|3.962238|8.457962|3.063825|5.320005|3.297532|5.912006|2.658071|16.326588|2.302438|2.759226|1.953844|2.143692|3.332565|3.512380|2.000668|1.986047|1.890628|3.491310|3.098691|3.120303|0.081892|0.067717|0.074249|0.078190|0.089753|0.500000| |3.383560|3.510442|7.344805|4.130511|6.556203|4.363224|0.109019|3.557616|0.093009|27.813223|5.972890|6.373820|8.826319|17.797715|8.440320|5.840383|10.471413|4.034049|3.930878|2.456362|4.260065|2.112475|13.765595|2.035314|2.520742|1.850869|2.061708|3.114260|3.099570|2.013231|2.072902|2.053777|3.832954|3.405002|3.011291|0.108663|0.080937|0.088313|0.082545|0.101226|0.188941|0.500000| |3.389287|3.119927|6.210767|3.162949|4.921885|3.294325|0.091599|2.695717|0.073360|19.001090|3.519490|4.055691|5.835251|8.441624|17.785540|8.831293|10.479490|6.323218|3.135672|2.023575|3.519821|1.792920|12.255500|1.833493|2.343864|1.749692|1.919930|2.789659|2.718820|1.921111|2.065626|2.092466|3.817753|3.583289|2.909915|0.112627|0.081848|0.093170|0.074341|0.084958|0.101548|0.192898|0.500000| |4.443054|3.764815|7.669752|3.540010|5.199143|3.694360|0.117547|2.907696|0.080543|17.928463|3.039252|3.799264|4.849255|4.500836|5.812372|8.952111|12.488210|17.561307|3.511771|2.270702|3.871776|2.043261|14.818101|2.297693|3.013900|2.292239|2.493257|3.503081|3.344612|2.501159|2.887657|2.841722|4.871146|4.962804|3.836672|0.133797|0.103194|0.146194|0.092719|0.091251|0.079233|0.100781|0.141735|0.500000| |3.264854|2.997029|6.255814|3.130028|4.667679|3.513701|0.111719|2.886311|0.083227|18.067831|3.098831|3.776557|4.816240|4.466329|5.777052|8.922517|12.460667|17.542725|3.409736|2.251565|3.949123|1.992666|14.350034|2.139925|2.789689|2.063802|2.186142|3.095000|3.061130|2.134781|2.381253|2.296556|3.948172|4.011445|3.452900|0.096906|0.078284|0.101494|0.075521|0.075180|0.082358|0.099808|0.140720|0.301701|0.500000| |3.447443|3.003904|5.954320|2.908964|4.431617|3.069187|0.092722|2.519531|0.070413|16.414510|2.829635|3.371887|4.424579|4.618140|6.833217|8.980824|10.217584|17.582202|3.019510|1.983728|3.444907|1.783801|12.722251|1.922830|2.518481|1.896196|2.040538|2.876174|2.782746|2.050788|2.301434|2.310986|4.037964|4.076316|3.199241|0.107896|0.083572|0.104482|0.074141|0.076758|0.076983|0.104992|0.189641|0.300414|0.300295|0.500000| |3.306528|4.312822|9.308098|7.317376|13.921377|7.136674|0.174014|9.010993|0.183581|39.518283|4.397497|4.719417|3.627593|2.964287|2.595844|2.789933|6.100622|2.500778|25.813697|9.424794|10.858328|7.588807|40.054737|6.203334|6.002682|3.929423|4.513384|8.539231|11.990176|3.557699|3.163443|2.690077|4.882231|4.160151|5.594486|0.084129|0.082248|0.090964|0.128280|0.113367|0.098375|0.078059|0.063256|0.072387|0.068203|0.061359|0.500000| |2.453677|2.981725|5.785945|3.911958|7.657195|3.862010|0.101373|4.782101|0.118687|27.470825|3.035261|3.059210|2.533000|2.191291|1.975179|2.090615|4.333383|1.936721|10.060384|8.829371|10.602473|17.645755|56.706780|6.794020|6.451203|3.887703|4.033117|6.895591|10.188217|3.138285|2.683464|2.289932|4.116645|3.601657|5.596125|0.062882|0.063967|0.067778|0.090521|0.080506|0.072945|0.058929|0.049562|0.055772|0.053500|0.048695|0.227869|0.500000| |2.079564|2.428173|4.770818|3.136279|5.841525|3.326956|0.089485|4.250890|0.115718|25.352976|2.795899|2.758837|2.310062|2.011367|1.827536|1.936159|3.983580|1.809559|7.962882|9.076715|13.564348|17.616006|57.506865|5.120887|5.427320|3.209823|3.129768|4.929192|6.606016|2.529262|2.254013|1.949190|3.456468|3.139834|4.836857|0.054239|0.054198|0.058183|0.071725|0.065394|0.068487|0.054097|0.046079|0.051478|0.050820|0.045659|0.151250|0.299307|0.500000| |4.534001|5.250936|7.478399|3.850140|7.016082|3.091526|0.087112|2.787317|0.069718|16.817480|2.322127|2.591205|2.463816|2.232238|2.149075|2.303625|4.478678|2.236781|4.186199|2.713996|4.145206|2.855732|21.512523|4.205239|5.749651|5.508463|9.025280|10.500082|6.774836|17.636771|8.914982|7.154184|13.960237|8.789424|8.672579|0.100740|0.135874|0.123157|0.204263|0.129711|0.057919|0.058814|0.055124|0.069035|0.058608|0.057178|0.101180|0.087217|0.069041|0.500000| |3.393898|3.649779|5.683380|2.992799|5.356845|2.578948|0.074195|2.402536|0.061855|14.519923|1.988093|2.191109|2.095735|1.908450|1.864412|2.011011|3.866816|2.000447|3.635350|2.468372|3.828580|2.674830|21.356300|4.168740|6.383093|6.882540|8.963185|8.186640|5.967463|17.536276|8.852367|6.374500|10.211220|8.804666|12.579615|0.079011|0.100401|0.096909|0.126404|0.091413|0.050086|0.050241|0.048248|0.061560|0.053348|0.051486|0.085336|0.080071|0.065823|0.301719|0.500000| |3.857038|3.759930|6.055740|3.004763|5.030592|2.682537|0.080836|2.406680|0.063421|14.254728|2.024245|2.295074|2.270365|2.055857|2.072493|2.306387|4.380148|2.388214|3.492438|2.358140|3.739933|2.441611|19.904872|3.716474|5.769174|5.825600|6.429817|6.487521|5.140238|8.766063|17.592712|8.762556|10.434137|13.612000|11.374034|0.088673|0.111846|0.121363|0.123396|0.088928|0.051074|0.052904|0.053546|0.076003|0.063784|0.061021|0.079562|0.069907|0.060209|0.174767|0.219677|0.500000| |5.648658|5.570842|8.765799|4.058739|6.525060|3.467395|0.106054|2.951268|0.076252|17.006678|2.458794|2.878733|2.851858|2.525492|2.527758|2.859504|5.560132|2.908011|4.216775|2.723544|4.256928|2.727395|21.503433|4.089947|5.803296|5.438756|7.145794|8.146685|6.122862|8.851920|17.456017|8.932716|12.124111|11.780844|8.909888|0.120267|0.155187|0.189311|0.192099|0.120713|0.061034|0.064040|0.064040|0.094614|0.076162|0.072535|0.097864|0.078359|0.065830|0.204221|0.174741|0.303324|0.500000| 2303.488697 -13192.196875 4978.205440 -246.105824 -6156.608563 3850.752593 -2305.855969 2.001028 4075000000000033 453596A4BEB05EEB 44B596A4BEB05EEB 41641B3900000000 402FFFFFFFFFFFFE 4360FB36D2309ECA