Version2.4
2021-05-29T02:44:25Z
10.1021/jm300687e
Gaussian16
RevisionB.01
PWARBURT
04-Nov-2020
#N HF/6-31G(d) OPT=(MaxStep=1) FREQ IOp(6/10=2,6/11=2,6/12=2)
DUDE COc1cc(cc(c1OC)OC)C(=O)N[C@@H]2C(=c3cc(ccc3=[NH+]C2=O)Br)c4ccccc4 C39707617
RHF
6-31G(d)
(6D,7F)
COc1cc(cc(c1OC)OC)C(=O)N[C@@H]2C(=c3cc(ccc3=[NH+]C2=O)Br)c4ccccc4
C01[X(C25H22Br1N2O5)]
159
C1
554
COc1cc(cc(c1OC)OC)C(=O)N[C@H]1C(=O)[NH+]=c2c(=C1c1ccccc1)cc(cc2)Br
COc1cc(cc(c1OC)OC)C(=O)N[C@H]1C(=O)[NH+]=c2c(=C1c1ccccc1)cc(cc2)Br
COc1cc(cc(OC)c1OC)C(=O)N[C@H]2C(=O)[NH+]=C3C=CC(=CC3=C2c4ccccc4)Br
InChIKey=BNBUNSNWZDVZQS-JOCHJYFZSA-O
InChI=1S/C25H21BrN2O5/c1-31-19-11-15(12-20(32-2)23(19)33-3)24(29)28-22-21(14-7-5-4-6-8-14)17-13-16(26)9-10-18(17)27-25(22)30/h4-13,22H,1-3H3,(H,28,29)/p+1/t22-/m1/s1
InChI=1/C25H21BrN2O5/c1-31-19-11-15(12-20(32-2)23(19)33-3)24(29)28-22-21(14-7-5-4-6-8-14)17-13-16(26)9-10-18(17)27-25(22)30/h4-13,22H,1-3H3,(H,28,29)/p+1/t22-/m1/s1/fC25H22BrN2O5/h27-28H/q+1
COc1cc(cc(c1OC)OC)C(=O)N[C@@H]2C(=c3cc(ccc3=[NH+]C2=O)Br)c4ccccc4
C01[X(C25H22Br1N2O5)]
159
C01
554
COc1cc(cc(c1OC)OC)C(=O)N[C@H]1C(=O)[NH+]=c2c(=C1c1ccccc1)cc(cc2)Br
CO[C]1[CH][C]([CH][C]([C]1OC)OC)C(=O)N[C@H]1C(=O)N[C]2[C]([C]1[C]1[CH][CH][CH][CH][CH]1)[CH][C]([CH][CH]2)Br
CO[C]1[CH][C]([CH][C](OC)[C]1OC)C(=O)N[C@@H]2[C]([C]3[CH][CH][CH][CH][CH]3)[C]4[CH][C](Br)[CH][CH][C]4NC2=O
InChIKey=WNWFKWDUOATAPW-JOCHJYFZSA-N
InChI=1S/C25H22BrN2O5/c1-31-19-11-15(12-20(32-2)23(19)33-3)24(29)28-22-21(14-7-5-4-6-8-14)17-13-16(26)9-10-18(17)27-25(22)30/h4-13,22H,1-3H3,(H,27,30)(H,28,29)/t22-/m1/s1
InChI=1/C25H22BrN2O5/c1-31-19-11-15(12-20(32-2)23(19)33-3)24(29)28-22-21(14-7-5-4-6-8-14)17-13-16(26)9-10-18(17)27-25(22)30/h4-13,22H,1-3H3,(H,27,30)(H,28,29)/t22-/m1/s1/f/h27-28H
3729.2201904837
-4012.3809629
1-A
23983.1591
130
424
554
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-10.4523 2.1118 -1.3219
10.7451
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-131.7678 -149.8831 -194.4724 -16.5165 10.6698 1.6785
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|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|
13.5683 15.6075 19.1595 49.5324 55.3852 63.8672 70.1055 72.1948 76.6969 81.4764 91.0346 102.7245 108.8986 136.4941 155.4656 157.2689 161.1888 179.6607 201.0614 205.2430 230.1699 234.3385 255.5725 258.2605 281.4393 296.3288 304.7336 319.8285 330.3159 347.9462 357.3001 368.0371 393.3427 411.0128 428.3973 444.9185 461.8184 493.5734 515.4062 522.1105 537.3599 567.9425 571.9900 581.7119 584.9527 592.7132 647.8200 653.6049 657.2407 671.0044 673.7397 708.8249 725.0874 736.4646 742.8215 767.2604 777.3404 802.6477 820.6927 836.4019 855.7869 859.2287 881.7507 897.6683 944.6463 949.7863 956.0229 972.7242 979.0194 1005.3423 1034.7268 1043.7359 1069.2341 1082.6923 1086.8259 1100.3988 1121.0327 1139.0105 1139.4047 1141.7107 1153.4709 1161.9158 1180.4871 1189.7571 1208.6961 1224.2025 1226.3902 1243.3951 1263.7340 1277.7079 1287.3509 1293.1520 1293.3386 1304.0678 1308.1047 1313.8390 1322.7197 1331.4157 1335.9272 1346.5541 1354.7046 1356.6333 1374.7762 1385.8530 1405.3192 1416.9283 1426.2509 1456.8839 1462.2973 1486.5015 1504.7527 1513.2220 1554.8112 1588.8628 1605.1689 1619.2842 1632.2112 1639.8930 1641.5687 1646.1892 1647.7107 1651.4484 1652.0316 1652.5013 1656.6873 1657.4572 1659.1852 1681.7285 1707.2453 1743.0269 1759.1240 1779.2829 1779.8709 1786.1641 1798.2503 1933.4440 2041.8675 3158.6464 3208.0376 3213.9279 3227.5283 3271.5756 3279.5680 3298.7412 3339.4115 3343.8498 3344.7472 3384.8751 3392.5731 3393.2219 3402.1259 3409.8877 3410.2113 3414.9871 3422.2630 3436.7187 3447.9255 3815.6860 3884.6981
8.9944 5.3397 6.5121 4.2733 3.6029 8.4534 5.8558 3.0703 4.1554 5.0276 3.8435 5.7075 5.5500 6.2594 1.0818 5.9084 5.9873 5.6756 4.4974 3.7670 1.5482 4.9093 5.5456 4.9137 1.2529 5.2584 6.6458 1.9643 5.6717 5.4476 5.1245 6.2098 4.5213 4.9285 5.6401 3.8912 3.6946 5.1100 4.8283 4.4871 6.5417 4.3179 3.7764 2.0654 4.2446 3.7451 2.3032 4.3644 4.6530 4.5095 5.1883 4.7179 5.1274 2.2625 6.2674 2.8556 2.7891 5.7287 5.4629 4.6118 2.1889 3.4223 4.6706 5.3722 2.1073 2.5140 1.5716 1.2388 1.4862 5.7960 6.0390 5.9225 1.4903 5.1459 5.3573 1.3894 3.1721 2.6524 1.7953 3.2608 1.4070 1.3528 2.8691 6.3575 1.7743 2.4844 2.6099 2.0246 5.8434 2.7605 1.2521 1.2655 1.2655 2.4114 2.0311 1.3273 1.5434 1.4096 1.6226 1.8603 2.0261 2.1259 2.6478 2.8784 1.8265 2.5662 1.8950 2.7012 1.9925 1.4420 3.0454 4.2945 2.3158 2.5936 2.2099 1.2612 2.0540 1.2407 1.3555 4.3734 1.0803 1.0525 1.0487 1.0513 1.0555 1.0680 2.1020 1.8269 3.5748 3.6995 4.2761 4.6911 4.6815 7.0776 5.3673 9.3844 10.3499 1.0790 1.0354 1.0346 1.0313 1.1075 1.1079 1.1082 1.1050 1.1011 1.1020 1.0891 1.0916 1.0925 1.0946 1.0912 1.0981 1.0965 1.0969 1.0918 1.0936 1.0793 1.0784
0.0010 0.0008 0.0014 0.0062 0.0065 0.0203 0.0170 0.0094 0.0144 0.0197 0.0188 0.0355 0.0388 0.0687 0.0154 0.0861 0.0917 0.1079 0.1071 0.0935 0.0483 0.1588 0.2134 0.1931 0.0585 0.2721 0.3636 0.1184 0.3646 0.3886 0.3854 0.4956 0.4121 0.4905 0.6099 0.4538 0.4643 0.7335 0.7557 0.7207 1.1129 0.8206 0.7280 0.4118 0.8557 0.7752 0.5695 1.0985 1.1842 1.1963 1.3876 1.3966 1.5883 0.7230 2.0376 0.9905 0.9930 2.1745 2.1679 1.9009 0.9445 1.4886 2.1395 2.5505 1.1079 1.3362 0.8463 0.6906 0.8393 3.4515 3.8095 3.8013 1.0039 3.5540 3.7284 0.9912 2.3487 2.0274 1.3732 2.5043 1.1029 1.0760 2.3557 5.3022 1.5272 2.1937 2.3128 1.8442 5.4983 2.6552 1.2226 1.2468 1.2472 2.4161 2.0477 1.3499 1.5910 1.4722 1.7062 1.9874 2.1908 2.3052 2.9485 3.2572 2.1253 3.0356 2.2712 3.3780 2.5102 1.8774 4.0628 5.7939 3.2985 3.8577 3.3548 1.9483 3.2241 1.9658 2.1522 6.9827 1.7280 1.6913 1.6862 1.6914 1.7068 1.7287 3.4093 3.0442 6.1389 6.6222 7.7964 8.7502 8.7380 13.3040 10.2261 20.6689 25.4237 6.3426 6.2783 6.2966 6.3293 6.9841 7.0206 7.1053 7.2602 7.2538 7.2636 7.3518 7.4021 7.4112 7.4646 7.4753 7.5242 7.5345 7.5688 7.5976 7.6601 9.2580 9.5883
0.4500 0.2743 0.1126 1.2004 8.1435 1.7494 0.6611 8.3403 4.9182 1.0594 0.7979 1.8312 4.0646 1.6460 0.2751 6.4721 0.9098 0.5122 8.2639 5.1288 0.5370 0.4843 1.1775 7.2098 4.0811 0.9968 2.7603 1.3220 6.4244 2.5563 1.1265 9.4696 3.7595 12.0639 3.7935 20.4434 10.3050 10.0349 37.1676 12.1065 52.2225 14.8615 15.5389 32.2348 11.1322 29.3877 63.2210 5.8674 28.9571 0.1806 8.7274 12.5617 1.6039 72.4144 22.7800 62.9330 26.4466 25.1014 7.2294 67.6972 23.3124 64.3623 0.3120 5.9571 51.8704 44.3383 10.8632 25.3633 18.3775 40.7091 1.0802 24.0820 23.1937 7.5009 46.2036 12.2464 5.2494 70.7023 18.6647 76.3739 2.7088 1.7651 196.2167 6.4383 13.0295 14.9772 675.4555 53.1059 110.4483 22.8667 1.2741 5.7990 0.4824 177.2146 111.6235 66.2302 103.7699 73.0316 80.9546 90.8677 111.0652 81.5815 412.4124 47.1022 273.7733 49.8030 71.5292 0.9698 27.3852 49.1769 195.8084 486.0114 652.5686 253.9676 182.1778 51.6323 135.6512 1.7450 10.7460 236.3440 1.7340 5.2027 2.1400 7.0710 43.9444 31.8384 56.3320 524.1112 73.4236 312.6801 5.6296 15.6785 167.6588 233.5313 325.4731 303.5493 571.5333 94.7407 44.4133 42.5011 54.9053 48.8148 46.7904 37.3490 37.6210 31.2666 33.3033 0.5230 1.1371 1.0377 6.1304 4.1418 4.3346 0.9495 7.9841 1.0077 2.9151 163.0160 49.3820
1.1591 5.1526 1.3433 1.2924 1.0037 3.7072 3.4515 1.9613 4.4653 2.9821 2.0962 2.4571 8.0567 2.8670 0.1323 0.4591 1.3489 6.6515 2.4154 0.7870 2.2969 3.3305 1.1518 5.0237 0.6315 2.6967 7.8349 0.6968 1.3230 1.9348 1.6109 0.8787 5.8943 2.1952 1.3833 13.3226 9.7460 3.7529 7.8463 2.4563 3.5087 11.2395 1.6275 0.3393 1.2063 7.7100 2.7274 1.8664 8.7011 0.4714 11.9476 5.2369 0.8728 1.3625 18.3422 5.3033 8.1968 12.2948 9.1820 13.4623 13.2289 4.7326 2.3523 2.5544 6.9673 15.0535 7.1999 32.0147 1.8260 4.0124 1.8838 50.2286 1.7753 7.4807 76.3762 0.5896 24.2408 24.1301 14.3589 7.9345 0.6821 4.4082 12.9148 14.0235 2.6132 9.8048 64.2290 30.8467 11.3617 46.8030 4.8983 1.8941 6.1831 14.8551 47.8844 127.7323 4.0019 2.9416 106.7176 88.9872 25.6751 57.7285 11.6315 83.9854 1.2061 32.9484 124.8958 150.0483 30.4692 23.4327 144.2943 53.3542 79.8329 7.9394 5.9062 21.0723 42.2906 10.9480 3.5406 57.4740 23.6277 14.9276 35.6271 15.5258 9.9134 16.1497 70.1657 11.2909 49.9925 36.6117 7.1665 329.6500 730.0230 3.6979 165.0446 96.2364 44.6437 71.0904 82.5755 92.4883 92.1994 36.4259 37.8424 34.2270 146.8950 140.9687 147.5982 20.9653 101.2068 101.5670 95.6360 53.3530 181.6433 183.8281 115.8094 38.3941 12.7394 111.8758 27.2868
0.7100 0.7497 0.6687 0.6468 0.7364 0.7415 0.7221 0.5247 0.4675 0.6731 0.6336 0.6613 0.5126 0.1995 0.7487 0.7429 0.7458 0.4591 0.2679 0.7295 0.7113 0.7012 0.5833 0.7360 0.7043 0.6066 0.1450 0.1440 0.6645 0.7046 0.6875 0.6064 0.1389 0.6162 0.6980 0.4149 0.3952 0.6844 0.2697 0.5560 0.2568 0.2329 0.5051 0.4563 0.7174 0.4466 0.5998 0.1490 0.5257 0.6517 0.5297 0.0795 0.4134 0.1599 0.1522 0.7178 0.2276 0.2654 0.3774 0.1365 0.1304 0.4254 0.4206 0.7025 0.3358 0.4260 0.3099 0.3526 0.7295 0.1137 0.6003 0.1881 0.3382 0.2000 0.1285 0.7409 0.3474 0.5228 0.2999 0.5124 0.5772 0.4950 0.6645 0.3463 0.4314 0.3556 0.2092 0.7371 0.5942 0.2055 0.7500 0.7411 0.7479 0.1905 0.3537 0.5041 0.3799 0.4935 0.3849 0.4517 0.2644 0.3475 0.7430 0.6263 0.4262 0.2486 0.2399 0.2896 0.7092 0.6688 0.7219 0.0853 0.4061 0.4298 0.7368 0.6219 0.3081 0.2295 0.2156 0.2739 0.7417 0.6495 0.7322 0.7255 0.6472 0.5088 0.2692 0.7475 0.2603 0.7470 0.4382 0.3762 0.4856 0.6046 0.5615 0.2591 0.2825 0.4724 0.0255 0.0226 0.0071 0.7454 0.7444 0.7391 0.5115 0.4855 0.4222 0.7488 0.7169 0.4217 0.6662 0.1706 0.1412 0.2488 0.1442 0.2128 0.1771 0.2324 0.1341
0.8304 0.8570 0.8015 0.7855 0.8482 0.8516 0.8386 0.6883 0.6372 0.8046 0.7757 0.7961 0.6778 0.3326 0.8563 0.8525 0.8544 0.6293 0.4226 0.8436 0.8313 0.8244 0.7368 0.8479 0.8265 0.7552 0.2533 0.2518 0.7985 0.8267 0.8148 0.7549 0.2440 0.7625 0.8221 0.5865 0.5665 0.8126 0.4249 0.7146 0.4086 0.3778 0.6712 0.6267 0.8354 0.6174 0.7498 0.2594 0.6892 0.7891 0.6926 0.1473 0.5849 0.2758 0.2641 0.8357 0.3709 0.4195 0.5479 0.2402 0.2307 0.5969 0.5921 0.8253 0.5027 0.5974 0.4732 0.5213 0.8436 0.2042 0.7502 0.3166 0.5054 0.3333 0.2277 0.8512 0.5157 0.6866 0.4614 0.6776 0.7319 0.6622 0.7984 0.5145 0.6028 0.5246 0.3460 0.8487 0.7454 0.3409 0.8571 0.8513 0.8557 0.3200 0.5226 0.6703 0.5507 0.6609 0.5559 0.6223 0.4182 0.5158 0.8525 0.7702 0.5976 0.3982 0.3869 0.4491 0.8298 0.8015 0.8385 0.1572 0.5776 0.6012 0.8485 0.7669 0.4710 0.3733 0.3547 0.4300 0.8517 0.7875 0.8454 0.8409 0.7858 0.6745 0.4242 0.8555 0.4131 0.8552 0.6093 0.5467 0.6538 0.7536 0.7192 0.4116 0.4406 0.6417 0.0498 0.0443 0.0141 0.8541 0.8535 0.8500 0.6768 0.6537 0.5938 0.8564 0.8351 0.5932 0.7996 0.2914 0.2474 0.3985 0.2521 0.3510 0.3010 0.3771 0.2365
298.150
1.00000
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55
6 8 6 6 6 6 6 6 8 6 8 6 6 8 7 6 1 6 6 6 6 6 6 6 7 1 6 8 35 6 6 6 6 6 6 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1
12.00000 15.99491 12.00000 12.00000 12.00000 12.00000 12.00000 12.00000 15.99491 12.00000 15.99491 12.00000 12.00000 15.99491 14.00307 12.00000 1.00783 12.00000 12.00000 12.00000 12.00000 12.00000 12.00000 12.00000 14.00307 1.00783 12.00000 15.99491 78.91834 12.00000 12.00000 12.00000 12.00000 12.00000 12.00000 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783
7464.7452 40523.0129 44515.2840
0.99998 -0.00479 0.00304 0.00484 0.99986 -0.01579 -0.00296 0.01580 0.99987
1
0.01160 0.00214 0.00195
0.24177 0.04454 0.04054
19.52 22.46 27.57 71.27 79.69 91.89 100.87 103.87 110.35 117.23 130.98 147.80 156.68 196.38 223.68 226.27 231.91 258.49 289.28 295.30 331.16 337.16 367.71 371.58 404.93 426.35 438.44 460.16 475.25 500.62 514.08 529.52 565.93 591.36 616.37 640.14 664.45 710.14 741.55 751.20 773.14 817.14 822.97 836.95 841.62 852.78 932.07 940.39 945.62 965.43 969.36 1019.84 1043.24 1059.61 1068.75 1103.92 1118.42 1154.83 1180.79 1203.40 1231.29 1236.24 1268.64 1291.54 1359.14 1366.53 1375.50 1399.53 1408.59 1446.46 1488.74 1501.70 1538.39 1557.75 1563.70 1583.23 1612.92 1638.78 1639.35 1642.67 1659.59 1671.74 1698.46 1711.80 1739.04 1761.35 1764.50 1788.97 1818.23 1838.34 1852.21 1860.56 1860.83 1876.26 1882.07 1890.32 1903.10 1915.61 1922.10 1937.39 1949.12 1951.89 1978.00 1993.93 2021.94 2038.64 2052.06 2096.13 2103.92 2138.74 2165.00 2177.19 2237.03 2286.02 2309.48 2329.79 2348.39 2359.44 2361.85 2368.50 2370.69 2376.07 2376.90 2377.58 2383.60 2384.71 2387.20 2419.63 2456.35 2507.83 2530.99 2559.99 2560.84 2569.89 2587.28 2781.79 2937.79 4544.59 4615.65 4624.13 4643.69 4707.07 4718.57 4746.15 4804.67 4811.05 4812.35 4870.08 4881.16 4882.09 4894.90 4906.07 4906.53 4913.40 4923.87 4944.67 4960.80 5489.92 5589.21
0.461594
0.490033
0.490977
0.398598
-4011.919369
-4011.890930
-4011.889986
-4011.982365
3.098407D-04
MUNgauss
RevisionA2.1
retrievium
29-May-2021
DUDE COc1cc(cc(c1OC)OC)C(=O)N[C@@H]2C(=c3cc(ccc3=[NH+]C2=O)Br)c4ccccc4 C39707617
RHF
6-31G(d)
(6D,10F)
C1
509.071208
|X|Y|Z|
33.482790 57.065968 140.022521
64.436544
24
|36.858105|
|13.577835|73.516695|
|8.018035|25.306194|36.858105|
|6.736323|14.039638|13.718794|36.858105|
|4.523929|9.280925|7.956399|13.755670|36.858105|
|3.786128|8.211266|6.830450|7.876223|13.711156|36.858105|
|3.977642|9.406109|7.884895|6.836197|7.951693|13.717056|36.858105|
|5.262434|14.641602|13.663008|7.906085|6.891785|7.901347|13.660944|36.858105|
|4.703811|12.785686|8.026769|5.238378|4.637471|5.240220|8.036583|14.164500|73.516695|
|4.209223|10.500180|5.976296|4.295897|3.858117|4.276832|5.938048|8.129810|23.967706|36.858105|
|3.217101|7.324056|5.290633|4.620452|5.215513|7.893490|14.220708|8.234854|12.812036|5.853521|73.516695|
|2.661169|5.718919|3.976451|3.785060|4.514854|6.725978|8.012241|5.262662|8.380408|4.172799|24.173627|36.858105|
|3.729129|6.966622|5.102138|7.778170|12.805891|7.580568|5.046102|4.481404|6.053818|2.979896|6.877652|3.659482|36.858105|
|3.749508|6.589058|4.518200|6.700989|8.022984|5.329743|4.021008|3.811607|5.356829|2.716891|5.695960|3.021824|15.847570|73.516695|
|3.007684|5.656500|3.981042|5.258835|7.803360|6.530537|4.452440|3.774382|5.329541|2.627968|6.504265|3.693835|13.822854|15.179451|53.358707|
|2.548418|4.665619|3.125447|3.925317|5.097088|4.513328|3.398160|2.971983|4.382220|2.227869|5.239393|3.049024|7.874824|12.494379|18.216003|36.858105|
|2.623160|4.701486|3.107503|3.961901|4.921241|4.148415|3.195696|2.878072|4.253818|2.194148|4.888857|2.784394|7.867668|15.305237|12.774088|17.426907|0.500000|
|2.295741|4.131299|2.680176|3.256533|3.916874|3.523002|2.821391|2.541810|3.852711|1.956059|4.451995|2.583548|5.366319|9.152304|10.331204|12.521528|0.254500|36.858105|
|1.977319|3.546111|2.255777|2.654623|3.098602|2.882522|2.389748|2.166499|3.355979|1.732866|3.873637|2.277895|3.967571|6.990465|6.913623|7.626091|0.185282|13.566719|36.858105|
|1.809256|3.205972|1.998280|2.310849|2.600068|2.417933|2.065430|1.910837|3.007454|1.558998|3.376404|1.966939|3.195037|5.757476|5.200930|4.987527|0.130878|7.675978|13.294238|36.858105|
|1.611948|2.858260|1.764415|2.004960|2.230301|2.109042|1.833501|1.701365|2.710940|1.420257|3.040841|1.781743|2.659873|4.803089|4.205511|3.884296|0.104325|5.129023|7.850262|14.075285|36.858105|
|1.544845|2.761010|1.709722|1.930466|2.165226|2.081242|1.811450|1.665993|2.660602|1.405137|3.033770|1.799189|2.559773|4.587277|4.046066|3.763188|0.101152|4.542121|6.827890|7.973825|13.501564|36.858105|
|1.635900|2.950226|1.848933|2.100554|2.405029|2.332108|2.000759|1.813233|2.872616|1.518495|3.350541|2.009503|2.876972|5.093359|4.647020|4.504185|0.119161|5.117554|7.800504|6.818054|7.854835|13.917365|36.858105|
|1.852578|3.354732|2.136312|2.478131|2.913983|2.794294|2.328658|2.085492|3.248770|1.699865|3.837895|2.300208|3.633009|6.346406|6.197341|6.709112|0.167918|7.776256|13.367114|7.777015|6.796833|7.956054|13.636894|36.858105|
|1.951989|3.586044|2.319655|2.698369|3.271299|3.208027|2.620086|2.293600|3.538735|1.857715|4.325523|2.636786|4.084233|6.915482|7.101580|7.748287|0.186947|6.753295|7.872223|5.143959|4.577438|5.250453|8.005670|14.017588|53.358707|
|1.823620|3.367010|2.164582|2.469295|2.957908|2.975079|2.481747|2.168077|3.383259|1.795324|4.178414|2.583387|3.532644|5.978844|5.859914|5.675454|0.143529|4.999587|5.744984|4.243667|4.029679|4.854126|7.427317|9.315325|25.920723|0.500000|
|2.243608|4.176132|2.776885|3.315491|4.256232|4.170695|3.224258|2.748687|4.131385|2.142312|5.193906|3.165811|5.589316|8.865316|10.723445|12.450927|0.252311|7.481236|6.640794|4.432064|3.751848|3.957816|5.184536|7.870014|18.852813|0.262399|36.858105|
|2.281022|4.336391|2.922966|3.425551|4.503626|4.735386|3.618556|2.978465|4.457540|2.326532|5.919941|3.726798|5.447341|8.265609|9.615146|7.987737|0.183237|5.278875|4.723672|3.487846|3.068834|3.263172|4.132918|5.471171|11.587728|0.217833|16.108365|73.516695|
|1.452170|2.553179|1.549810|1.733971|1.880150|1.779112|1.581234|1.490985|2.408199|1.266744|2.638389|1.531721|2.177688|3.961487|3.318252|2.876091|0.078644|3.589079|4.558655|6.731105|10.116043|6.676928|4.596079|4.066549|4.290680|0.080453|2.746331|4.192717|2539.412838|
|2.408755|4.287986|2.750887|3.332486|3.852527|3.396503|2.784082|2.569795|3.912785|1.956447|4.359126|2.474211|5.025365|8.565217|8.834711|7.384084|0.172835|13.129775|7.617351|6.434798|4.423155|3.714340|3.862613|5.033500|6.103378|0.101290|4.960245|7.101449|116.912500|36.858105|
|2.137954|3.824986|2.411346|2.802337|3.159407|2.914822|2.479221|2.298118|3.581896|1.792507|3.986778|2.285036|3.785846|6.372888|6.384359|5.069824|0.120811|7.714216|6.274969|6.246137|4.474783|3.647021|3.620320|4.396708|5.200581|0.089812|3.992292|5.962317|124.298941|13.556966|36.858105|
|2.139300|3.795106|2.349003|2.678591|2.908063|2.679471|2.346755|2.225430|3.514905|1.749306|3.783044|2.133268|3.323987|5.644531|5.238487|3.881680|0.096801|5.099973|4.352828|4.530615|3.564885|2.958641|2.888522|3.340061|4.086305|0.072929|3.156457|4.926283|108.641455|7.890029|13.819202|36.858105|
|2.405474|4.189651|2.565086|2.946719|3.092150|2.760211|2.436269|2.368694|3.728613|1.842475|3.858035|2.122961|3.495875|6.049031|5.198311|3.682496|0.095190|4.507305|3.727610|3.781803|3.042186|2.579879|2.547054|2.943048|3.702344|0.066456|2.928406|4.646973|94.383432|6.863225|7.962389|13.721353|36.858105|
|2.806084|4.808907|2.975711|3.567720|3.713314|3.144617|2.713783|2.660847|4.095317|2.017035|4.179287|2.265102|4.373276|7.780652|6.248928|4.313938|0.114677|5.091819|3.948700|3.818823|3.024233|2.600808|2.622918|3.105379|3.977766|0.070538|3.240163|5.110202|91.072071|7.912671|6.856505|7.896289|13.713533|36.858105|
|2.818975|4.902129|3.130231|3.913229|4.331031|3.578759|2.948391|2.809113|4.230028|2.095741|4.490149|2.465280|5.694373|10.199850|8.647000|6.197746|0.162819|7.667265|5.188892|4.649760|3.499673|3.018311|3.124538|3.888916|4.982838|0.085487|4.178152|6.323635|99.056463|13.572639|7.858887|6.832541|7.942438|13.821195|36.858105|
|17.565827|16.434187|7.031278|6.732189|4.584286|3.729858|3.778384|4.760935|7.421745|3.605921|5.430471|2.574422|3.905716|7.015885|4.311036|2.671885|0.076107|2.448557|2.086121|1.919151|1.695028|1.607004|1.691234|1.923078|2.726805|0.051539|2.300220|4.092645|52.077199|2.632798|2.332917|2.366245|2.723964|3.231700|3.167586|0.500000|
|17.663616|17.010445|5.896131|4.912610|3.626574|3.183502|3.411655|4.429461|7.644411|4.014043|5.125805|2.407597|3.079362|5.514935|3.501935|2.227521|0.063521|2.036732|1.781610|1.647987|1.482087|1.422592|1.497844|1.677238|2.392735|0.045943|1.991549|3.600940|45.922097|2.136741|1.928667|1.945645|2.178189|2.487888|2.464552|0.300098|0.500000|
|17.569918|16.423290|7.039238|6.740098|4.585918|3.738226|3.791178|4.766296|7.386246|3.909724|5.456671|2.584816|3.903665|7.275237|4.180554|2.638559|0.077080|2.346045|2.027680|1.847958|1.648847|1.586197|1.685749|1.910574|2.751035|0.052451|2.324171|4.197343|50.342054|2.420644|2.119525|2.092062|2.335155|2.751373|2.828962|0.298562|0.299881|0.500000|
|7.449608|12.494327|8.856645|17.799574|8.973927|5.639907|4.939857|5.620638|7.495050|3.631865|6.521845|3.134147|7.299796|13.263313|6.677325|3.857797|0.112358|3.280613|2.676851|2.360018|2.040378|1.945321|2.095887|2.464023|3.583105|0.066471|3.172503|5.649637|60.452126|3.409856|2.831054|2.727355|3.069498|3.836123|4.177050|0.223313|0.145754|0.224231|0.500000|
|3.132307|6.520178|4.936254|5.621392|8.877822|17.774898|8.919949|5.634433|7.522396|3.630523|12.610183|7.516722|6.945636|8.766612|9.656438|4.988979|0.121896|3.778996|3.115451|2.558389|2.236249|2.236241|2.551000|3.090843|4.990605|0.095013|4.935875|10.651715|63.196343|3.500212|3.018816|2.707069|2.706521|3.024178|3.509076|0.086389|0.075088|0.086845|0.124255|0.500000|
|3.603810|8.474764|5.194137|4.035252|3.841134|4.458486|6.226048|7.187318|16.426191|17.587932|11.933668|4.791432|2.993737|4.814362|3.635738|2.276434|0.062097|1.975877|1.759975|1.572607|1.437733|1.434108|1.561333|1.747268|2.629331|0.052260|2.234110|4.389613|43.380142|1.945839|1.779989|1.718027|1.788001|1.951420|2.054803|0.087695|0.094128|0.096479|0.094387|0.108017|0.500000|
|4.878506|12.152758|6.293143|4.490333|3.841948|4.011950|5.157189|7.189396|16.423421|17.593229|8.399859|3.567961|3.002480|4.988443|3.522963|2.211658|0.061456|1.939879|1.719510|1.551226|1.413213|1.395691|1.505034|1.683323|2.495283|0.049088|2.108187|4.035487|42.987816|1.939791|1.763665|1.721748|1.827220|2.020520|2.100277|0.110185|0.130747|0.128348|0.108223|0.094156|0.298252|0.500000|
|3.695547|8.687418|4.685980|3.540387|3.216692|3.531811|4.671312|5.915623|16.896202|17.652623|8.646886|3.677955|2.576103|4.215261|3.157750|1.996760|0.054494|1.782272|1.593155|1.446628|1.325265|1.310441|1.407737|1.562527|2.305866|0.045646|1.927718|3.695328|40.554820|1.792981|1.663778|1.636816|1.721434|1.861750|1.911603|0.089631|0.101980|0.094228|0.085843|0.085925|0.299644|0.299663|0.500000|
|2.407922|5.126765|3.411646|3.183301|3.621184|4.907325|5.893049|4.430662|7.662970|3.978772|17.018646|17.663187|3.032123|4.591548|4.172101|2.617825|0.067049|2.274594|2.043199|1.790418|1.640404|1.661561|1.842167|2.072627|3.195905|0.064639|2.736123|5.632867|48.526455|2.190755|2.057029|1.939412|1.925247|2.028064|2.176267|0.064480|0.061659|0.064743|0.075115|0.146673|0.128273|0.093197|0.101459|0.500000|
|2.576975|5.440903|3.782292|3.727929|4.571129|6.725643|7.042003|4.772218|7.457388|3.589198|16.440192|17.555616|3.816464|5.496435|5.510908|3.297115|0.081342|2.822872|2.465835|2.117727|1.904156|1.913769|2.138110|2.468533|3.836694|0.076008|3.406394|7.051519|55.374766|2.720310|2.536187|2.357238|2.318491|2.448749|2.669816|0.070771|0.064549|0.069102|0.086533|0.223278|0.108818|0.087203|0.089494|0.300193|0.500000|
|2.579954|5.439373|3.779771|3.732580|4.572554|6.714150|7.008892|4.748730|7.370605|3.861871|16.425461|17.562636|3.822756|5.635800|5.253608|3.242105|0.082768|2.674927|2.375874|2.027536|1.842967|1.882126|2.130371|2.446457|3.909844|0.079075|3.489032|7.622632|53.403715|2.493726|2.272460|2.089299|2.068359|2.224042|2.463858|0.068968|0.064607|0.071146|0.086769|0.227629|0.125775|0.095041|0.093472|0.300030|0.298402|0.500000|
|2.875351|5.567296|3.959179|4.940930|7.442662|7.469252|4.947369|3.963234|5.603980|2.727072|7.366279|4.336274|9.322251|10.908924|26.065556|9.176031|0.182790|6.304927|4.562108|3.505550|2.898705|2.825002|3.251125|4.237359|6.732139|0.117411|7.345110|13.076743|78.606915|5.615581|4.465657|3.721204|3.609535|4.117473|5.264451|0.083374|0.068983|0.080070|0.121892|0.252741|0.077680|0.073083|0.066998|0.097640|0.138259|0.124486|0.500000|
|1.857196|3.261895|2.018914|2.336869|2.586316|2.373115|2.041083|1.911779|3.013603|1.553927|3.316252|1.908181|3.158626|5.740961|5.030984|4.567045|0.121373|7.031932|8.801175|17.807539|9.064886|5.664972|4.931680|5.576225|5.670095|0.097466|3.849450|5.548924|220.575955|7.212893|7.439385|5.469091|4.499846|4.448351|5.270560|0.055307|0.047022|0.052449|0.067013|0.068590|0.043205|0.043040|0.040139|0.048298|0.057083|0.054078|0.093691|0.500000|
|1.423724|2.542403|1.562376|1.744707|1.935845|1.873291|1.652413|1.527596|2.460861|1.307563|2.789695|1.654582|2.244972|4.029869|3.476337|3.120930|0.084803|3.616409|4.930653|5.682130|8.865543|17.744269|9.011742|5.660228|5.773889|0.114653|3.310732|5.040334|220.389108|3.084433|3.076457|2.589366|2.284457|2.286062|2.589986|0.040989|0.036647|0.040590|0.048820|0.055683|0.037093|0.036090|0.034026|0.042806|0.048620|0.048034|0.068067|0.124840|0.500000|
|1.557402|2.821525|1.764641|1.984004|2.266296|2.229881|1.930932|1.745209|2.781200|1.482488|3.268934|1.976381|2.656990|4.685313|4.212014|3.933851|0.105212|4.150505|5.576618|4.925448|5.606885|8.973766|17.741323|8.885115|9.932244|0.223395|4.779351|7.173960|130.318602|3.240360|3.050451|2.508540|2.245697|2.314477|2.713453|0.044368|0.039763|0.044655|0.054652|0.068121|0.042598|0.040772|0.038235|0.050658|0.057973|0.058691|0.083093|0.107201|0.217200|0.500000|
|1.941906|3.503669|2.205423|2.522458|2.864715|2.722475|2.332994|2.139016|3.364746|1.697816|3.823194|2.232346|3.376623|5.648678|5.758941|4.739187|0.111484|7.098729|6.740887|6.939244|5.074179|4.119008|4.038758|4.810224|5.503878|0.095781|4.033024|6.004611|136.652980|8.840863|17.740793|8.970005|5.663200|4.945566|5.603990|0.058080|0.049015|0.053595|0.069919|0.079954|0.047190|0.046195|0.043942|0.056234|0.069101|0.061973|0.115564|0.211383|0.095574|0.093352|0.500000|
|1.942935|3.460997|2.120770|2.365343|2.547127|2.400314|2.143247|2.035655|3.264624|1.632759|3.514787|1.994634|2.832960|4.803596|4.413174|3.274457|0.082158|4.144934|3.766875|4.031665|3.341374|2.795369|2.687936|3.010040|3.684687|0.067021|2.791841|4.428896|106.183706|5.623456|8.949692|17.743662|8.895060|5.626920|4.933385|0.059250|0.049642|0.052572|0.066382|0.067673|0.044582|0.044469|0.042781|0.050960|0.061252|0.054029|0.089117|0.131964|0.069160|0.065536|0.216601|0.500000|
|2.329423|4.031027|2.418490|2.709560|2.770038|2.501226|2.264100|2.236564|3.579162|1.771231|3.617842|1.976931|3.021707|5.254311|4.364041|3.063268|0.080357|3.593731|3.092410|3.177138|2.658072|2.283409|2.240004|2.529565|3.211525|0.058609|2.520543|4.077125|85.345478|4.947937|5.662528|8.921398|17.730352|8.917239|5.655076|0.073612|0.059378|0.062176|0.078490|0.067548|0.047435|0.048812|0.046365|0.050306|0.059619|0.053133|0.085497|0.103171|0.057112|0.055599|0.124570|0.214838|0.500000|
|3.108886|5.174066|3.128682|3.736337|3.682188|3.060385|2.696194|2.723418|4.209414|2.072057|4.118388|2.189832|4.177250|7.650332|5.558536|3.750047|0.103150|4.135100|3.323635|3.220276|2.639981|2.311364|2.334701|2.718887|3.543973|0.063771|2.892259|4.663809|81.208280|5.635404|4.945727|5.629496|8.901646|17.744557|8.961461|0.102403|0.076434|0.084124|0.115524|0.079776|0.055055|0.058209|0.053175|0.054667|0.064868|0.059525|0.101957|0.101914|0.057220|0.058077|0.107436|0.123896|0.215037|0.500000|
|3.137422|5.380537|3.468502|4.549737|5.007090|3.887648|3.145239|3.023450|4.475561|2.229406|4.687634|2.539328|7.176249|14.330998|9.648005|6.729766|0.195653|7.021535|4.841588|4.196354|3.256683|2.891375|3.052119|3.815820|5.062227|0.086933|4.370413|6.670116|91.902323|8.839604|5.602256|4.934821|5.656214|8.968937|17.766688|0.097804|0.074851|0.089408|0.140494|0.103788|0.060715|0.062785|0.055892|0.061817|0.075104|0.071304|0.151115|0.126243|0.069308|0.074612|0.123233|0.107257|0.124510|0.216811|0.500000|
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