Version2.1 2020-12-27T00:54:09Z 10.1021/jm300687e Gaussian16 RevisionB.01 CFLINN 15-Nov-2020 #N HF/6-31G(d) OPT=(MaxStep=1) FREQ IOp(6/10=2,6/11=2,6/12=2) DUDE Cc1ccc(c(c1)[N+](=O)[O-])NC(=O)[C@H](c2ccccc2)OC(=O)c3cccc(c3)NC(=O)N C14599640 RHF 6-31G(d) (6D,7F) Cc1ccc(c(c1)[N+](=O)[O-])NC(=O)[C@H](c2ccccc2)OC(=O)c3cccc(c3)NC(=O)N C01[X(C23H20N4O6)] 153 C1 535 NC(=O)Nc1cccc(c1)C(=O)O[C@H](C(=O)Nc1ccc(cc1[N+](=O)[O-])C)c1ccccc1 NC(=O)Nc1cccc(c1)C(=O)O[C@H](C(=O)Nc1ccc(cc1[N+](=O)[O-])C)c1ccccc1 Cc1ccc(NC(=O)[C@@H](OC(=O)c2cccc(NC(N)=O)c2)c3ccccc3)c(c1)[N+]([O-])=O InChIKey=IRQGNKXDURUXBO-FQEVSTJZSA-N InChI=1S/C23H20N4O6/c1-14-10-11-18(19(12-14)27(31)32)26-21(28)20(15-6-3-2-4-7-15)33-22(29)16-8-5-9-17(13-16)25-23(24)30/h2-13,20H,1H3,(H,26,28)(H3,24,25,30)/t20-/m0/s1 InChI=1/C23H20N4O6/c1-14-10-11-18(19(12-14)27(31)32)26-21(28)20(15-6-3-2-4-7-15)33-22(29)16-8-5-9-17(13-16)25-23(24)30/h2-13,20H,1H3,(H,26,28)(H3,24,25,30)/t20-/m0/s1/f/h25-26H,24H2 Cc1ccc(c(c1)[N+](=O)[O-])NC(=O)[C@H](c2ccccc2)OC(=O)c3cccc(c3)NC(=O)N C01[X(C23H20N4O6)] 153 C01 535 NC(=O)Nc1cccc(c1)C(=O)O[C@H](C(=O)Nc1ccc(cc1[N+](=O)[O-])C)c1ccccc1 NC(=O)N[C]1[CH][CH][CH][C]([CH]1)C(=O)O[C@H](C(=O)N[C]1[CH][CH][C]([CH][C]1[N]([O])[O])C)[C]1[CH][CH][CH][CH][CH]1 C[C]1[CH][CH][C](NC(=O)[C@@H](OC(=O)[C]2[CH][CH][CH][C]([CH]2)NC(N)=O)[C]3[CH][CH][CH][CH][CH]3)[C]([CH]1)N([O])[O] InChIKey=IRQGNKXDURUXBO-FQEVSTJZSA-N InChI=1S/C23H20N4O6/c1-14-10-11-18(19(12-14)27(31)32)26-21(28)20(15-6-3-2-4-7-15)33-22(29)16-8-5-9-17(13-16)25-23(24)30/h2-13,20H,1H3,(H,26,28)(H3,24,25,30)/t20-/m0/s1 InChI=1/C23H20N4O6/c1-14-10-11-18(19(12-14)27(31)32)26-21(28)20(15-6-3-2-4-7-15)33-22(29)16-8-5-9-17(13-16)25-23(24)30/h2-13,20H,1H3,(H,26,28)(H3,24,25,30)/t20-/m0/s1/f/h25-26H,24H2 3144.9390878117 -1549.5491313 1-A 21860.4695 117 418 535 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38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 6 6 6 6 6 6 6 7 8 8 7 6 8 6 1 6 6 6 6 6 6 8 6 8 6 6 6 6 6 6 7 6 8 7 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 12.00000 12.00000 12.00000 12.00000 12.00000 12.00000 12.00000 14.00307 15.99491 15.99491 14.00307 12.00000 15.99491 12.00000 1.00783 12.00000 12.00000 12.00000 12.00000 12.00000 12.00000 15.99491 12.00000 15.99491 12.00000 12.00000 12.00000 12.00000 12.00000 12.00000 14.00307 12.00000 15.99491 14.00307 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 7519.2310 35208.3276 37657.3462 0.99998 0.00342 0.00449 -0.00343 0.99999 0.00138 -0.00448 -0.00140 0.99999 1 0.01152 0.00246 0.00230 0.24002 0.05126 0.04793 11.03 15.95 28.29 36.04 40.37 46.57 52.58 56.65 73.78 94.65 100.83 114.22 137.53 142.13 166.29 225.47 255.58 259.51 280.96 310.73 333.51 369.60 404.48 409.78 443.67 500.91 543.42 544.89 547.27 584.14 605.73 616.47 624.47 652.27 655.69 688.90 692.14 736.47 761.13 793.92 832.67 861.46 873.01 892.74 897.13 911.77 970.60 985.86 1026.77 1053.47 1066.09 1075.43 1102.56 1117.91 1122.55 1132.20 1192.74 1217.73 1229.96 1243.13 1261.00 1281.60 1314.33 1320.45 1349.29 1376.78 1379.72 1387.34 1461.65 1488.24 1495.45 1503.14 1510.41 1521.95 1565.36 1568.06 1579.02 1589.72 1592.09 1603.31 1609.88 1625.20 1627.83 1628.90 1677.40 1699.28 1708.03 1723.70 1741.45 1753.70 1758.61 1796.66 1800.36 1806.29 1860.19 1876.87 1878.16 1909.58 1913.31 1925.63 1955.60 1976.10 1981.94 2057.44 2073.13 2083.82 2092.89 2111.39 2164.19 2221.32 2244.24 2261.20 2308.37 2312.50 2338.85 2345.79 2358.55 2377.96 2391.53 2404.44 2453.90 2481.56 2566.40 2573.42 2585.75 2604.29 2606.72 2613.23 2613.78 2682.01 2858.69 2866.53 2874.91 4612.95 4689.34 4730.02 4748.52 4820.28 4833.38 4840.53 4845.78 4857.87 4864.76 4871.69 4881.88 4921.46 4948.14 4974.38 5008.21 5482.96 5561.26 5563.78 5644.49 0.439202 0.467180 0.468124 0.372435 -1549.109930 -1549.081951 -1549.081007 -1549.176696 3.209425D-04 MUNgauss RevisionA2.0 retrievium 27-Dec-2020 DUDE Cc1ccc(c(c1)[N+](=O)[O-])NC(=O)[C@H](c2ccccc2)OC(=O)c3cccc(c3)NC(=O)N C14599640 RHF 6-31G(d) (6D,10F) C1 448.138285 |X|Y|Z| 132.246014 53.473537 38.885366 65.028324 23 6 7 8 21 1 1 |36.858105| |12.616607|36.858105| |7.524206|13.652763|36.858105| |5.001260|7.844546|13.864186|36.858105| |4.368606|6.682170|7.877499|13.592330|36.858105| |4.998300|7.884150|6.967704|8.000780|13.574827|36.858105| |7.554928|13.874556|8.076773|6.913587|7.793869|13.648518|36.858105| |3.866958|5.151915|4.550375|5.079000|7.580382|13.082652|7.904999|53.358707| |3.847574|4.762901|3.961755|4.097268|5.355240|8.380454|7.246089|21.790023|73.516695| |3.164948|4.056921|3.858433|4.533003|6.765069|8.293648|5.437068|21.538768|16.113827|73.516695| |3.311935|4.490639|5.155809|7.813075|13.692344|7.786653|5.114416|8.825678|8.230592|12.851282|53.358707| |2.847609|3.657457|4.369804|6.377328|7.657247|5.084094|3.865113|6.037562|6.192278|8.752507|18.956464|36.858105| |2.859846|3.615720|4.565487|6.661205|6.482962|4.403261|3.596652|5.034869|5.379297|6.901439|11.370010|15.971660|73.516695| |2.353512|2.889926|3.257731|4.249221|5.061718|3.958304|3.110367|5.225946|5.540384|8.085709|10.792733|12.425294|14.135514|36.858105| |2.307755|2.822576|3.083458|3.916593|4.860087|4.018878|3.120002|5.610009|5.946476|9.066705|10.142221|8.861820|10.722194|17.638765|0.500000| |2.223321|2.687181|2.971495|3.735156|4.383140|3.612633|2.899064|4.889075|5.263045|7.647814|8.421910|7.587060|10.228457|12.553630|0.247489|36.858105| |2.092286|2.492998|2.652748|3.204952|3.842823|3.413201|2.756768|4.932803|5.402927|8.048476|6.937254|5.322169|7.439166|7.556140|0.204322|13.748345|36.858105| |1.945341|2.270035|2.386686|2.790777|3.230384|2.965534|2.484987|4.278505|4.844900|6.705085|5.374667|4.028796|6.041814|5.015016|0.133126|7.922040|13.730378|36.858105| |1.909211|2.207866|2.354208|2.732126|3.036428|2.746057|2.356931|3.806252|4.348484|5.701380|4.888885|3.778572|5.952230|4.435715|0.110931|6.859387|7.940015|13.774930|36.858105| |2.005641|2.337342|2.566477|3.036380|3.279542|2.843775|2.441656|3.782016|4.270305|5.547527|5.328408|4.379075|7.121246|5.022643|0.116519|7.924450|6.878822|7.940549|13.722550|36.858105| |2.168607|2.583849|2.907368|3.594446|3.926843|3.231991|2.698862|4.212383|4.638879|6.239955|6.836403|6.212719|9.797442|7.560427|0.155538|13.688007|7.937858|6.873760|7.936271|13.783518|36.858105| |2.115106|2.528068|2.874980|3.620871|3.961461|3.185862|2.636204|4.149973|4.581422|6.127557|7.304712|8.103403|12.936900|13.532258|0.259893|7.869500|5.427248|4.075213|3.817794|4.440134|6.374009|73.516695| |1.874066|2.193728|2.429467|2.938664|3.218747|2.729555|2.302169|3.675937|4.160315|5.450656|5.628292|5.355827|8.672879|8.106595|0.213380|6.040516|4.906653|3.799607|3.476413|3.821008|4.940543|25.449076|36.858105| |1.812946|2.114638|2.289714|2.732291|3.076342|2.693287|2.260689|3.757229|4.279554|5.702360|5.364921|4.704390|7.257841|7.166792|0.225560|5.805008|5.325267|4.041555|3.503579|3.632727|4.470934|15.273150|16.023818|73.516695| |1.711106|1.965215|2.183100|2.574910|2.704951|2.324021|2.020685|3.086613|3.566855|4.439813|4.456738|4.117596|7.297518|5.201569|0.134985|4.315194|3.634872|3.048236|2.918566|3.240626|3.966937|14.456694|12.778989|14.245713|36.858105| |1.746385|1.997605|2.259135|2.657714|2.690808|2.281187|2.011854|2.951823|3.417527|4.152906|4.315557|4.054564|7.775306|4.620421|0.114536|3.867712|3.178861|2.733598|2.707526|3.099428|3.793570|12.453261|7.582580|9.384805|13.706016|36.858105| |1.583814|1.779575|1.995035|2.284486|2.279294|1.974743|1.777382|2.561176|3.012867|3.557923|3.531144|3.161211|6.079527|3.460842|0.088496|3.045085|2.608677|2.319763|2.322470|2.616898|3.050720|8.259537|5.056736|7.116374|7.981142|13.787453|36.858105| |1.440284|1.604578|1.768857|1.999201|2.021003|1.787223|1.615585|2.356699|2.800291|3.285689|3.114196|2.701112|5.021118|3.015056|0.079651|2.718418|2.415936|2.176039|2.157850|2.367334|2.682831|6.875014|4.490676|6.780453|6.922064|7.940543|13.761573|36.858105| |1.420060|1.587269|1.731131|1.962425|2.026036|1.806955|1.619722|2.422734|2.879856|3.420826|3.163933|2.716975|4.880740|3.156048|0.085551|2.857573|2.596279|2.323095|2.258429|2.426333|2.739124|7.146226|5.089221|8.053238|7.945125|6.825207|7.904147|13.719927|36.858105| |1.534263|1.736969|1.896035|2.185155|2.300430|2.034333|1.792279|2.747829|3.229860|3.943581|3.694931|3.226892|5.641104|3.966990|0.108612|3.505933|3.159120|2.739890|2.606989|2.794506|3.238358|9.398971|7.742841|12.009466|13.731575|7.874767|6.863158|7.950862|13.729344|36.858105| |1.293654|1.431855|1.543065|1.724749|1.784239|1.619374|1.464585|2.192299|2.636156|3.085628|2.746209|2.292323|4.077828|2.627269|0.072589|2.435715|2.283464|2.083785|2.019326|2.124036|2.334067|5.623967|3.880477|6.598130|5.140752|4.535023|5.172187|7.920148|13.502218|7.777379|53.358707| |1.233883|1.362586|1.455681|1.621058|1.692275|1.551663|1.403056|2.124885|2.566267|3.007985|2.604946|2.142403|3.749644|2.483874|0.069346|2.366105|2.276952|2.108507|2.031423|2.095729|2.258442|5.154179|3.555664|6.355584|4.328249|3.698292|3.946093|5.252531|7.702158|6.256753|18.876133|36.858105| |1.263584|1.401553|1.494316|1.672587|1.763303|1.617253|1.452388|2.230838|2.685115|3.189132|2.741984|2.254169|3.888801|2.676499|0.074961|2.599941|2.537874|2.358330|2.255103|2.300496|2.463379|5.509462|3.876148|7.156597|4.517560|3.686292|3.719270|4.614366|6.633714|6.477785|11.397552|15.933070|73.516695| |1.137496|1.245443|1.322249|1.456284|1.513596|1.402065|1.279816|1.923174|2.343699|2.702207|2.296871|1.860227|3.265629|2.110950|0.059158|2.024178|1.968186|1.846997|1.785764|1.828604|1.944191|4.270910|2.840345|5.107932|3.322890|2.973324|3.214610|4.126688|5.232070|4.358568|11.317025|13.846799|15.001605|53.358707| |17.548159|8.844183|6.692383|4.586518|3.922834|4.286514|5.881640|4.631842|6.014240|5.069222|4.166405|2.700280|4.903888|2.239853|0.061104|2.087077|1.953140|1.808647|1.775778|1.873341|2.035857|3.641564|1.824784|3.125004|1.683981|1.730426|1.579962|1.436006|1.408909|1.513078|1.748641|1.219894|2.208850|1.534384|0.500000| |17.586193|8.847939|5.559204|4.158899|3.913776|4.731673|7.237061|5.315270|7.291213|5.603332|4.157570|2.607109|4.565071|2.207528|0.060934|2.101799|2.014017|1.883831|1.833937|1.897965|2.032021|3.515746|1.773689|3.084402|1.616036|1.633578|1.485774|1.362815|1.352375|1.461574|1.687400|1.188603|2.167226|1.496291|0.301905|0.500000| |17.546853|8.842704|6.675496|4.582996|3.926172|4.292670|5.892109|4.638364|5.965239|5.112026|4.169914|2.691535|4.859121|2.241927|0.060350|2.155730|2.025302|1.908664|1.899957|2.004859|2.142256|3.604409|1.794919|3.075193|1.648796|1.691446|1.540764|1.400152|1.375453|1.479805|1.706832|1.197687|2.181707|1.504587|0.302122|0.301875|0.500000| |6.980925|8.902298|17.699781|9.042388|5.639454|4.999861|5.705555|4.926939|5.778424|5.648426|5.706891|3.820131|7.427492|2.925887|0.076205|2.689388|2.391327|2.179640|2.183303|2.401457|2.694714|4.746604|2.272655|3.773914|2.086525|2.194909|1.964205|1.735466|1.679939|1.817990|2.040620|1.408837|2.557194|1.747961|0.190031|0.140134|0.189091|0.500000| |4.095607|5.623262|8.987299|17.855966|8.938818|5.682661|4.984114|5.599245|6.036011|6.916966|9.761337|7.119005|15.733091|4.539598|0.111183|3.916487|3.226350|2.800827|2.793164|3.203883|3.892115|7.151002|3.171726|5.090042|2.814915|2.982770|2.540889|2.179559|2.110399|2.344642|2.494052|1.706501|3.120500|2.075715|0.108467|0.095977|0.108288|0.219166|0.500000| |6.955412|8.957174|5.696912|4.980237|5.613328|8.986684|17.798969|10.178999|14.994460|9.056627|5.680410|3.261053|5.374449|2.749279|0.077804|2.603176|2.541144|2.325742|2.192879|2.230255|2.418866|4.185443|2.099049|3.711790|1.852436|1.831024|1.632366|1.499599|1.510957|1.665383|1.876583|1.328540|2.445696|1.658700|0.151375|0.220338|0.151718|0.124646|0.108171|0.500000| |3.056792|4.018835|4.298785|5.790862|9.446240|7.415374|4.814540|10.270164|9.180851|18.122572|26.066724|9.420686|10.838867|7.796422|0.233182|6.522461|5.931640|4.419206|3.801935|3.940776|4.900942|8.991024|4.113573|7.345094|3.183978|2.982594|2.456872|2.209942|2.286717|2.695175|2.729304|1.926220|3.637829|2.312991|0.078055|0.080525|0.078522|0.098694|0.145830|0.114527|0.500000| |2.071214|2.464756|2.577538|3.085341|3.783739|3.466579|2.775799|5.242041|5.763955|8.920283|6.816940|4.975816|6.882202|7.006349|0.226553|8.915982|17.714785|8.918404|5.650147|4.955062|5.642869|9.030016|4.865504|10.150870|3.554383|3.041913|2.513432|2.361015|2.575376|3.158001|3.116161|2.294989|4.549301|2.708227|0.053877|0.055887|0.055073|0.064120|0.084736|0.071901|0.171672|0.500000| |1.838543|2.118761|2.186025|2.502848|2.895422|2.750904|2.337586|4.077875|4.728332|6.386086|4.667738|3.393761|5.158681|4.091950|0.114015|5.642927|8.920466|17.722521|8.915621|5.643909|4.952823|6.086759|3.306380|6.415822|2.712526|2.425455|2.097025|1.998692|2.148828|2.507627|2.672072|2.011462|4.008612|2.424421|0.047482|0.049993|0.050047|0.055529|0.068853|0.061834|0.107875|0.215574|0.500000| |1.785455|2.031116|2.142360|2.428812|2.656179|2.456359|2.156170|3.415278|3.983845|5.020313|4.125735|3.133419|5.059530|3.547516|0.090832|4.944857|5.645542|8.922271|17.716444|8.905104|5.646305|5.612729|2.941548|5.290351|2.552799|2.392287|2.099813|1.972994|2.058774|2.331319|2.543813|1.895378|3.732407|2.294601|0.046138|0.047903|0.049697|0.055677|0.068595|0.056374|0.088598|0.124218|0.214842|0.500000| |1.931798|2.218664|2.446551|2.837226|2.958735|2.583566|2.274582|3.384508|3.878687|4.836895|4.613034|3.777676|6.460531|4.096413|0.096368|5.640663|4.955099|5.646823|8.902577|17.718235|8.936222|6.789536|3.328608|5.544514|2.960866|2.919200|2.524680|2.279900|2.297744|2.581167|2.753166|1.990667|3.850055|2.383639|0.050270|0.050612|0.054239|0.064704|0.083994|0.057857|0.092705|0.107561|0.124082|0.214703|0.500000| |2.213589|2.634734|3.049516|3.805999|3.945449|3.159513|2.680638|3.978290|4.403040|5.714592|6.679350|6.532522|11.599743|7.033568|0.141163|8.907513|5.648143|4.952522|5.642815|8.920430|17.718929|11.947645|4.920515|7.447067|4.161551|4.232110|3.364767|2.861040|2.835733|3.297977|3.238463|2.258351|4.309150|2.645741|0.058208|0.056904|0.060990|0.079880|0.120003|0.066037|0.125100|0.124135|0.107524|0.124114|0.215320|0.500000| |1.908777|2.205827|2.546379|3.051079|3.032702|2.504693|2.200030|3.172755|3.635757|4.432176|4.881551|4.801364|9.833604|5.166013|0.121738|4.200948|3.313368|2.826915|2.832499|3.332394|4.217611|14.185906|6.983710|8.659734|8.900303|17.767928|8.902148|5.643607|4.931096|5.623447|4.917617|3.070126|5.500813|3.469314|0.052506|0.049128|0.051414|0.068918|0.097845|0.054945|0.090975|0.086668|0.068778|0.068940|0.087436|0.137511|0.500000| |1.579652|1.762686|1.988491|2.254642|2.204100|1.909589|1.738885|2.449193|2.892332|3.361713|3.345924|2.968694|5.861726|3.116062|0.079170|2.774143|2.377491|2.141132|2.171020|2.462512|2.839855|7.134500|4.103656|5.936510|5.659723|8.926658|17.725124|8.940447|5.638035|4.947584|5.717875|3.326012|5.557402|3.850488|0.043988|0.040982|0.042872|0.055064|0.070243|0.044299|0.063991|0.063294|0.053877|0.054968|0.067083|0.088386|0.214130|0.500000| |1.350369|1.490037|1.635438|1.824532|1.830341|1.634084|1.493062|2.153718|2.579512|2.979715|2.774793|2.364059|4.410322|2.582821|0.068589|2.366934|2.132025|1.950383|1.946433|2.122009|2.359709|5.666335|3.581625|5.595600|4.975501|5.651230|8.931680|17.692348|8.914948|5.650337|9.927991|4.941462|7.410947|5.666169|0.037520|0.035547|0.036567|0.044864|0.055032|0.038668|0.054726|0.057931|0.050193|0.050020|0.057418|0.069767|0.124165|0.216247|0.500000| |1.499137|1.695933|1.829259|2.100166|2.247030|2.015133|1.769163|2.770224|3.268830|4.018153|3.620909|3.083510|5.234268|3.873266|0.110270|3.494462|3.280983|2.844536|2.644133|2.754492|3.140034|8.608501|7.236199|13.490748|8.945620|5.633688|4.954497|5.648669|8.892368|17.813069|9.599839|6.699971|13.756147|6.250630|0.040919|0.039931|0.040081|0.048386|0.061678|0.045978|0.074928|0.093302|0.073377|0.065822|0.069852|0.086100|0.124182|0.107561|0.124071|0.500000| |1.243601|1.367826|1.473580|1.634173|1.675301|1.525483|1.391085|2.055592|2.483754|2.868865|2.546869|2.112502|3.798263|2.366646|0.065146|2.196512|2.056937|1.891504|1.846816|1.947287|2.127060|5.003461|3.325425|5.609954|4.302958|4.066930|4.882918|7.532880|9.325896|5.789306|26.059715|9.439357|10.914714|10.830358|0.034437|0.033092|0.033533|0.039999|0.048257|0.036429|0.051388|0.057147|0.049635|0.047792|0.051989|0.060681|0.092217|0.115566|0.228164|0.144677|0.500000| |1.122118|1.225136|1.299507|1.425795|1.476868|1.371011|1.256288|1.876932|2.294252|2.623800|2.227549|1.797663|3.169598|2.015055|0.056661|1.910180|1.850983|1.729517|1.670189|1.714380|1.830860|4.067192|2.678367|4.791455|3.133629|2.855464|3.126415|4.012656|4.900038|4.026038|10.444982|9.321152|10.991693|26.024718|0.031001|0.030130|0.030241|0.035128|0.041443|0.033260|0.045646|0.052178|0.046347|0.043782|0.045659|0.051096|0.068350|0.077317|0.115285|0.115454|0.231487|0.500000| |1.103421|1.206102|1.273669|1.399052|1.460866|1.362001|1.244027|1.880360|2.299436|2.647647|2.213721|1.776601|3.095085|2.020490|0.056961|1.959992|1.933499|1.830017|1.762149|1.783401|1.877142|4.019236|2.658364|4.875324|3.004436|2.668749|2.814027|3.461849|4.295880|3.833403|8.197618|9.584487|14.010802|26.018684|0.030309|0.029718|0.029798|0.034288|0.040479|0.033028|0.045787|0.054526|0.049469|0.046470|0.047378|0.051650|0.064604|0.069462|0.095735|0.115928|0.156579|0.316462|0.500000| 1547.184863 -9919.304191 3880.381999 -202.751166 -4694.488496 3144.939314 -1549.549182 2.001528 3D4B00000000000B 4508DDA333BDB74F 448B341DC273A7B9 41E0F023FFFFFFFE B389B604819B87C1 43A0D1138C4CBCD9