Version2.3 2021-03-30T14:19:30Z 10.1021/jm300687e Gaussian16 RevisionB.01 PWARBURT 16-Jan-2021 #N HF/6-31G(d) OPT=(MaxStep=1) FREQ IOp(6/10=2,6/11=2,6/12=2) DUDE c1cc(ccc1C(=O)N[C@H](CCC(=O)N)C(=O)OCC(=O)Nc2cc(ccc2C#N)Cl)F C03291356 RHF 6-31G(d) (6D,7F) c1cc(ccc1C(=O)N[C@H](CCC(=O)N)C(=O)OCC(=O)Nc2cc(ccc2C#N)Cl)F C01[X(C21H18Cl1F1N4O5)] 144 C1 520 N#Cc1ccc(cc1NC(=O)COC(=O)[C@H](NC(=O)c1ccc(cc1)F)CCC(=O)N)Cl N#Cc1ccc(cc1NC(=O)COC(=O)[C@H](NC(=O)c1ccc(cc1)F)CCC(=O)N)Cl NC(=O)CC[C@@H](NC(=O)c1ccc(F)cc1)C(=O)OCC(=O)Nc2cc(Cl)ccc2C#N InChIKey=RGVCAXNAOICWJD-MRXNPFEDSA-N InChI=1S/C21H18ClFN4O5/c22-14-4-1-13(10-24)17(9-14)26-19(29)11-32-21(31)16(7-8-18(25)28)27-20(30)12-2-5-15(23)6-3-12/h1-6,9,16H,7-8,11H2,(H2,25,28)(H,26,29)(H,27,30)/t16-/m1/s1 InChI=1/C21H18ClFN4O5/c22-14-4-1-13(10-24)17(9-14)26-19(29)11-32-21(31)16(7-8-18(25)28)27-20(30)12-2-5-15(23)6-3-12/h1-6,9,16H,7-8,11H2,(H2,25,28)(H,26,29)(H,27,30)/t16-/m1/s1/f/h26-27H,25H2 c1cc(ccc1C(=O)N[C@H](CCC(=O)N)C(=O)OCC(=O)Nc2cc(ccc2C#N)Cl)F C01[X(C21H18Cl1F1N4O5)] 144 C01 520 N#Cc1ccc(cc1NC(=O)COC(=O)[C@H](NC(=O)c1ccc(cc1)F)CCC(=O)N)Cl N#C[C]1[CH][CH][C]([CH][C]1NC(=O)COC(=O)[C@H](NC(=O)[C]1[CH][CH][C]([CH][CH]1)F)CCC(=O)N)Cl NC(=O)CC[C@@H](NC(=O)[C]1[CH][CH][C](F)[CH][CH]1)C(=O)OCC(=O)N[C]2[CH][C](Cl)[CH][CH][C]2C#N InChIKey=RGVCAXNAOICWJD-MRXNPFEDSA-N InChI=1S/C21H18ClFN4O5/c22-14-4-1-13(10-24)17(9-14)26-19(29)11-32-21(31)16(7-8-18(25)28)27-20(30)12-2-5-15(23)6-3-12/h1-6,9,16H,7-8,11H2,(H2,25,28)(H,26,29)(H,27,30)/t16-/m1/s1 InChI=1/C21H18ClFN4O5/c22-14-4-1-13(10-24)17(9-14)26-19(29)11-32-21(31)16(7-8-18(25)28)27-20(30)12-2-5-15(23)6-3-12/h1-6,9,16H,7-8,11H2,(H2,25,28)(H,26,29)(H,27,30)/t16-/m1/s1/f/h26-27H,25H2 3013.7672351723 -1956.8250507 1-A 28060.3063 119 401 520 |A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A| -104.84508 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12.0778 9.3908 12.6994 1.0641 1.0646 1.0586 1.0994 1.0909 1.1079 1.0980 1.0903 1.0919 1.0919 1.0961 1.0967 1.0953 1.0936 1.0467 1.0786 1.0778 1.1059 0.0001 0.0004 0.0018 0.0028 0.0026 0.0024 0.0101 0.0082 0.0170 0.0183 0.0323 0.0144 0.0154 0.0533 0.0591 0.0246 0.0955 0.1004 0.0636 0.1712 0.0269 0.1387 0.1910 0.3091 0.2297 0.2771 0.4310 0.4786 0.4768 0.6333 0.9739 1.2381 0.6918 0.7912 0.5115 0.4417 0.4647 0.5936 0.4638 0.2278 0.5757 0.3388 0.5149 0.3891 0.5781 0.8934 0.6561 0.9679 1.6829 1.1271 0.5846 1.1195 1.3541 1.9106 2.0122 1.3668 2.1877 1.8025 2.3327 1.6951 2.1606 0.8731 2.8651 0.7015 0.6459 1.6347 1.1904 1.9975 3.7873 0.8850 1.6793 3.0122 0.9463 0.9488 3.3195 1.3788 1.2240 1.6079 2.6446 3.2477 2.1576 1.3840 2.4401 1.7938 2.1811 3.4228 5.2384 2.2396 1.2507 1.9814 3.3648 2.4585 1.7488 1.6362 2.7148 2.4416 3.8736 1.2748 2.3534 1.9437 1.6042 1.6634 2.1127 1.9166 3.1257 4.2414 4.7819 2.5481 2.7848 1.7017 1.7645 3.6855 1.7650 3.8305 4.6008 4.1684 6.5539 12.7884 2.3452 6.4168 10.8597 21.6751 22.0644 28.4842 22.6108 50.2061 6.5243 6.5953 6.5895 6.9014 6.9599 7.1043 7.0610 7.3567 7.4171 7.4367 7.4959 7.5552 7.5488 7.8068 9.0830 9.3651 9.5557 10.2530 0.0173 0.0508 4.1614 0.9397 0.2523 0.9632 3.3436 1.8070 0.1998 3.5312 1.7496 4.3424 7.2878 2.8941 3.3359 1.4642 6.0907 5.7020 1.3740 12.2507 283.5785 15.9468 1.3018 5.0964 4.2540 0.4398 21.9438 14.9728 14.0899 6.8970 3.2225 0.4752 3.8874 10.2002 9.1106 5.3432 3.5389 5.8191 14.0282 4.8579 3.1066 26.9805 103.2452 51.1175 9.8060 44.8057 11.1604 21.7550 0.9883 31.6449 16.7201 19.8413 5.3531 0.1690 47.4123 13.1233 20.5605 7.4227 12.2554 20.0170 45.8738 17.4849 5.1138 32.4703 1.7840 7.2103 37.5962 40.4978 54.5601 32.4249 3.4970 7.3792 0.5688 0.4428 4.9722 4.5823 0.4009 0.6752 2.6876 39.2318 0.6740 9.0560 10.9697 1.1123 63.5055 27.9361 34.0858 21.7204 96.9315 9.8935 4.6125 480.0134 3.4984 195.8441 284.2608 248.5093 25.5816 9.4307 22.0057 62.2435 2.4452 69.7631 386.3044 60.8842 451.4448 15.6349 46.0706 171.4787 60.7260 14.4204 18.9417 33.8820 3.0404 266.4380 314.7566 79.2824 430.2237 15.3480 148.5526 158.7654 142.9613 306.5079 384.8516 326.6743 149.9316 70.0527 9.0338 18.6490 19.6369 5.6992 2.1428 9.4493 24.8325 10.1729 2.1301 3.0402 3.9524 0.7704 1.7062 16.4561 63.6397 48.1960 60.6190 54.9799 3.9281 1.7558 1.4765 0.6753 2.4291 6.4162 0.1975 2.7948 1.1657 1.0805 0.8621 1.2296 0.6182 0.2211 0.7634 0.5620 0.5419 0.6906 0.2262 3.1369 0.7113 0.6225 0.7823 0.4454 1.1174 0.7891 1.4548 3.9029 1.1635 0.5044 4.1580 4.6628 2.5372 0.7637 0.3615 0.0965 1.9480 0.9108 0.5839 4.1346 0.2435 2.4781 0.9551 6.2199 1.7591 0.9700 1.3921 1.5087 5.6483 1.0743 0.7591 0.5291 1.3555 7.0926 3.1812 0.1581 4.1943 1.7687 8.8048 1.8735 3.2835 0.7710 22.8515 1.2412 2.3274 5.4264 2.1672 5.5487 8.8484 1.3552 7.3897 2.9142 0.9538 1.4299 22.6157 0.1897 0.2474 0.6754 9.2854 2.4206 6.2133 3.9695 22.0638 13.3567 6.8256 10.5794 6.4952 11.5266 4.5182 7.7660 3.3980 10.2645 0.8961 7.3756 54.4214 2.3551 7.5770 11.2568 8.8248 13.2281 1.2790 7.2922 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1.00783 1.00783 1.00783 1.00783 9343.2955 46790.8214 51394.1953 0.99997 0.00780 -0.00195 -0.00779 0.99996 0.00478 0.00199 -0.00477 0.99999 1 0.00927 0.00185 0.00169 0.19316 0.03857 0.03512 4.56 13.33 28.66 32.29 35.47 44.02 58.37 69.48 83.17 97.13 114.19 125.47 132.68 138.95 152.72 167.84 182.23 218.64 237.61 249.33 281.12 320.15 347.85 360.83 375.49 401.71 414.48 474.44 492.96 507.02 539.94 546.38 592.80 622.66 667.47 672.86 684.66 695.53 718.73 779.78 814.36 837.68 839.14 845.28 856.97 911.11 931.59 937.71 953.34 955.57 981.81 983.51 989.59 1001.21 1078.05 1101.62 1155.74 1174.06 1197.86 1228.55 1235.17 1253.57 1297.05 1339.78 1342.44 1359.28 1385.86 1389.92 1431.73 1487.14 1492.18 1522.52 1560.55 1574.82 1578.44 1600.43 1604.35 1618.27 1661.70 1695.51 1701.70 1716.54 1723.87 1742.51 1753.52 1764.35 1818.98 1838.70 1847.00 1872.13 1873.78 1885.27 1901.86 1962.85 1984.21 1997.18 2008.85 2025.89 2045.23 2047.04 2078.38 2086.92 2114.95 2182.22 2197.98 2251.45 2259.71 2277.26 2282.63 2318.59 2352.99 2361.32 2368.09 2429.46 2473.91 2477.26 2558.99 2569.57 2585.11 2605.54 2613.67 2775.46 2838.65 2878.56 2908.54 3726.96 4641.34 4665.55 4676.51 4696.23 4734.51 4746.52 4753.31 4869.04 4885.29 4891.75 4901.73 4919.84 4920.92 5008.20 5521.57 5523.31 5581.21 5707.38 0.401581 0.430800 0.431744 0.331938 -1956.423470 -1956.394251 -1956.393307 -1956.493113 3.347510D-04 MUNgauss RevisionA2.1 retrievium 30-Mar-2021 DUDE c1cc(ccc1C(=O)N[C@H](CCC(=O)N)C(=O)OCC(=O)Nc2cc(ccc2C#N)Cl)F C03291356 RHF 6-31G(d) (6D,10F) C1 460.094976 |X|Y|Z| 151.175861 61.778419 37.277097 70.348327 20 6 7 8 17 2 1 |36.858105| |13.766697|36.858105| |8.025941|13.823835|36.858105| |6.861984|7.886502|13.807413|36.858105| |7.942159|6.863688|8.028869|13.791526|36.858105| |13.698906|7.898510|6.920656|7.900180|13.689044|36.858105| |7.482713|5.001333|4.482108|5.070615|7.711237|12.708309|36.858105| |5.287310|4.007464|3.847502|4.566403|6.806875|8.074193|15.822976|73.516695| |6.556625|4.452570|3.779265|3.952034|5.211497|7.839201|14.042938|15.097035|53.358707| |4.378510|3.327775|2.947604|3.103820|3.902434|5.028080|7.783595|12.233320|17.916795|36.858105| |3.932556|3.079980|2.832647|3.081959|3.933434|4.768449|7.515286|14.133137|12.548545|17.620982|0.500000| |3.722549|2.936099|2.597283|2.684045|3.246877|4.039572|5.567105|9.371206|10.390367|12.374397|0.245410|36.858105| |3.644742|2.915447|2.630454|2.762078|3.359978|4.064982|5.528775|10.190329|8.489100|7.483507|0.191175|12.498912|36.858105| |2.972694|2.489684|2.261155|2.332185|2.717183|3.162730|3.889841|7.091251|5.819802|4.887643|0.126720|7.553970|12.546124|36.858105| |2.708704|2.299873|2.074615|2.107307|2.410490|2.800611|3.350954|5.932019|5.186963|4.424071|0.111686|6.860989|7.954233|15.886215|73.516695| |2.731288|2.346404|2.174501|2.259614|2.599216|2.922726|3.460978|6.508744|4.844024|3.839039|0.104103|5.085765|7.872568|14.056403|15.133976|53.358707| |3.793870|3.015134|2.667078|2.743655|3.290934|4.073600|5.344883|8.365245|10.823641|12.559671|0.249859|7.643819|4.930315|3.800616|6.608639|4.172384|36.858105| |4.011336|3.214147|2.783875|2.788476|3.262867|4.070810|4.894302|7.303339|9.653960|7.925431|0.169394|5.666146|4.033261|3.261012|5.754455|3.673908|16.013277|73.516695| |3.022310|2.503480|2.274174|2.359160|2.777079|3.260785|4.138014|7.011466|7.278736|8.104524|0.209351|6.460930|4.416020|3.599948|6.409053|3.985003|14.412157|15.300308|73.516695| |2.630313|2.248001|2.052043|2.101130|2.402491|2.756101|3.282645|5.532575|5.502754|5.202424|0.136155|4.525724|3.376398|2.928593|5.351532|3.338450|8.196766|12.874174|24.162769|36.858105| |2.217424|1.933196|1.798087|1.856779|2.103446|2.344575|2.761145|4.834187|4.383076|4.060230|0.113436|3.772397|3.000842|2.697039|4.952983|3.138603|5.284363|8.224456|14.315162|12.517134|36.858105| |2.154467|1.877449|1.763800|1.843345|2.102352|2.318459|2.768219|4.991804|4.291802|4.044373|0.118791|3.825585|3.132137|2.818120|5.110584|3.302818|4.822371|7.173695|12.844915|7.968433|16.029702|73.516695| |1.978154|1.756698|1.638205|1.675687|1.864042|2.055643|2.346549|4.078892|3.663455|3.213359|0.088406|3.046254|2.504184|2.312062|4.291457|2.737967|4.052913|6.814091|9.461702|7.955604|13.890833|14.900159|53.358707| |1.733887|1.560323|1.469882|1.506394|1.660259|1.802586|2.031589|3.577060|3.092643|2.653987|0.074147|2.565341|2.189161|2.062230|3.826214|2.489025|3.158231|5.326199|6.993877|5.067510|7.644381|11.582730|18.560362|36.858105| |1.647679|1.484915|1.410453|1.457452|1.609771|1.731315|1.960768|3.514711|2.936155|2.529815|0.072270|2.473958|2.160504|2.050739|3.780308|2.501856|2.890369|4.756153|6.385379|4.234380|6.324208|11.795260|10.568409|13.688264|36.858105| |1.472284|1.341284|1.281524|1.322251|1.446677|1.540676|1.720862|3.092688|2.540691|2.141450|0.061125|2.110680|1.886506|1.814848|3.342811|2.249060|2.389522|3.990301|5.066771|3.250193|4.340626|8.044317|7.018502|7.967936|13.789706|36.858105| |1.384352|1.271011|1.213706|1.244041|1.349283|1.434706|1.581736|2.817878|2.333481|1.933455|0.054529|1.903868|1.705604|1.647913|3.045601|2.049987|2.165846|3.695483|4.480190|2.905444|3.663979|6.421440|6.167331|6.782726|7.843927|13.752492|36.858105| |1.434244|1.317212|1.250876|1.274084|1.378715|1.474575|1.618503|2.850554|2.410097|1.987831|0.055347|1.945309|1.720298|1.654573|3.070751|2.043810|2.272424|3.944448|4.678167|3.138152|3.879938|6.397576|7.040342|7.849913|6.851161|8.044603|13.836302|36.858105| |1.596034|1.453525|1.370657|1.394162|1.518045|1.639787|1.813735|3.170471|2.741379|2.287846|0.063218|2.219194|1.920036|1.826824|3.398882|2.226733|2.693884|4.689623|5.664279|4.010677|5.127322|7.870785|10.801643|13.585320|7.926081|6.960145|7.924577|13.707779|36.858105| |1.635600|1.495076|1.400962|1.411719|1.527968|1.659026|1.814886|3.126373|2.764071|2.270201|0.061624|2.187408|1.878293|1.782078|3.324382|2.165878|2.719181|4.893847|5.550609|4.016302|4.613723|6.765865|9.348087|7.749550|5.116681|4.560316|5.129169|7.789341|13.225749|36.858105| |1.658239|1.522674|1.420345|1.420027|1.527941|1.663774|1.801079|3.070072|2.752109|2.225027|0.059662|2.135566|1.831028|1.735297|3.239359|2.108809|2.679976|4.954834|5.309783|3.819729|4.048613|5.921303|7.520091|5.486241|3.968730|3.584899|3.956799|5.446029|7.392217|16.749092|53.358707| |1.378971|1.260789|1.214142|1.260588|1.378110|1.453175|1.622150|2.956572|2.356233|1.975426|0.057167|1.964534|1.801403|1.748391|3.194327|2.200688|2.132329|3.524959|4.446261|2.706854|3.453206|6.782994|5.048380|4.786338|7.098521|10.974028|7.073536|4.804508|4.258964|3.221574|3.677994|448.794386| |5.319906|8.183703|14.367580|8.176366|5.321054|4.670802|3.416453|5.419314|4.089202|2.451653|0.065772|2.208457|2.236512|1.974134|3.257790|2.610098|2.269595|4.225966|3.513330|1.815799|1.610623|2.805633|2.022464|1.345528|1.292166|1.183392|1.127510|1.162325|1.265600|1.296747|1.794645|9.021513|97.533100| |17.733945|8.995538|5.701572|4.948115|5.636578|8.866240|6.835805|8.594979|9.812087|4.761776|0.112498|4.146892|3.914397|3.206793|5.280099|3.906448|4.185424|8.068498|5.778937|2.824596|2.340382|3.998712|2.840922|1.813821|1.710162|1.521516|1.432541|1.491715|1.669698|1.721270|2.385113|11.359903|9.651318|0.500000| |8.855118|17.748221|8.959449|5.638349|4.949994|5.613878|4.059090|5.934946|5.232143|2.988079|0.076074|2.707526|2.663677|2.334722|3.898944|2.994568|2.782063|5.353424|4.148237|2.131240|1.836252|3.148601|2.296759|1.503071|1.424183|1.291436|1.231160|1.280856|1.411273|1.461339|2.038184|9.718514|16.737303|0.215128|0.500000| |4.948892|5.639458|8.956342|17.746195|8.860162|5.613483|4.123279|6.993485|4.497622|2.713963|0.076136|2.379474|2.463925|2.116187|3.410783|2.826461|2.430133|4.361650|3.798921|1.923079|1.725178|3.060770|2.132277|1.421199|1.382475|1.262120|1.189102|1.213514|1.319625|1.331964|1.820014|9.716873|16.728309|0.107490|0.124572|0.500000| |5.660727|4.950674|5.683115|8.924484|17.759963|8.954575|7.250526|13.639558|6.591270|3.859444|0.113505|3.202550|3.369047|2.711380|4.236960|3.567660|3.218371|5.514437|4.947943|2.392228|2.127674|3.834530|2.550770|1.678001|1.642643|1.476901|1.369542|1.390057|1.525620|1.521554|2.056110|11.379906|9.613733|0.124169|0.107533|0.212588|0.500000| |7.294550|4.866837|3.935875|3.923995|4.911816|7.407003|9.368770|10.906871|26.055486|9.169285|0.185456|6.200621|4.962857|3.718222|6.140289|4.256819|7.828870|15.034015|9.057527|4.080352|3.161745|5.343920|3.671194|2.262077|2.113107|1.832415|1.700506|1.775328|2.029061|2.079557|2.854213|13.498523|7.053711|0.246569|0.118971|0.090379|0.121479|0.500000| |3.098432|2.531460|2.280108|2.361893|2.802951|3.344797|4.398346|7.739141|7.614491|8.859135|0.212223|17.599339|8.893282|6.954327|12.420664|6.491714|7.133406|9.214570|12.980553|5.033465|4.370685|8.093455|4.666271|2.872345|2.794971|2.349508|2.089850|2.122745|2.434466|2.361328|3.093789|17.512863|4.439602|0.094164|0.065551|0.059158|0.077972|0.134222|0.500000| |3.803583|3.010638|2.597982|2.609884|3.080447|3.882422|4.964625|7.886262|9.469853|8.832578|0.173748|17.569382|8.876811|6.918559|12.562776|6.423746|6.970677|10.326934|10.084981|4.318173|3.525273|6.122474|4.007301|2.476324|2.347703|2.018031|1.846150|1.907199|2.179541|2.185918|2.942946|14.937187|5.000306|0.123322|0.078723|0.063936|0.082177|0.175899|0.303652|0.500000| |4.330787|3.376963|3.007259|3.149462|3.884032|4.851906|6.551160|11.569440|9.405022|6.794969|0.169518|8.805987|17.560702|8.979562|11.082760|9.668032|4.524835|6.932410|6.880601|3.049259|2.677624|4.885416|3.099767|1.999381|1.960125|1.727595|1.578001|1.598747|1.777524|1.756539|2.351473|13.237061|5.654876|0.128999|0.084583|0.076717|0.105875|0.150853|0.173592|0.211564|0.500000| |3.382217|2.749768|2.553289|2.753661|3.389910|3.935208|5.447189|11.268541|7.648196|6.865570|0.207027|8.819778|17.541632|8.917354|10.869530|9.781372|4.588957|6.589562|7.640515|3.278085|2.999273|5.730672|3.378040|2.191506|2.198499|1.921679|1.721879|1.719392|1.908183|1.844368|2.427420|14.923708|4.897023|0.097072|0.069065|0.069171|0.098009|0.122823|0.210929|0.173502|0.305044|0.500000| |2.801871|2.411772|2.268649|2.396348|2.779686|3.071366|3.642816|7.105368|4.872590|3.774350|0.105558|4.686865|7.388907|9.235837|10.823136|26.104377|2.965885|4.644789|5.010185|2.355334|2.218749|4.174994|2.631097|1.762670|1.779271|1.603730|1.460374|1.451803|1.577172|1.531392|2.028250|12.671332|4.483876|0.080006|0.062084|0.061443|0.079015|0.086163|0.120140|0.117317|0.199453|0.212194|0.500000| |2.421605|2.121455|1.974661|2.035959|2.298638|2.549341|2.936617|5.464850|4.123027|3.255847|0.088253|4.197746|5.711369|9.409794|13.713839|26.058590|2.711708|4.307951|4.677056|2.256766|2.151096|4.018831|2.589491|1.748242|1.763563|1.599268|1.462977|1.454849|1.574304|1.529483|2.026201|12.629835|3.972146|0.070706|0.055899|0.052422|0.064246|0.075730|0.113544|0.111911|0.145690|0.147865|0.309933|0.500000| |2.674397|2.304650|2.113994|2.164466|2.460841|2.798552|3.260340|5.439096|5.360224|4.738096|0.126033|3.912047|3.033516|2.613846|4.700291|3.041053|7.330454|13.164576|16.528239|17.592953|8.892734|11.184265|9.522642|4.706585|3.897501|3.071184|2.801158|3.061103|3.894380|4.023997|5.331992|20.546695|4.215607|0.078908|0.060626|0.055111|0.067908|0.113229|0.114677|0.104413|0.078249|0.082507|0.060315|0.057139|0.500000| |2.583649|2.220410|2.002195|2.017138|2.277913|2.633789|3.070424|5.084370|5.206342|4.738015|0.118007|4.401047|3.266292|2.911956|5.463977|3.297224|7.199525|12.644943|16.552238|17.594647|8.829378|10.783260|9.930926|4.792933|3.895866|3.072068|2.821044|3.111794|3.997871|4.201567|5.616792|20.410593|4.008874|0.078531|0.059281|0.051146|0.062149|0.110290|0.134795|0.123940|0.082523|0.085594|0.063788|0.062432|0.302152|0.500000| |2.008603|1.790060|1.658711|1.680969|1.857639|2.058715|2.319654|3.967875|3.650857|3.133120|0.084238|2.952368|2.414562|2.229891|4.154850|2.639049|4.040507|7.135576|8.939827|7.835151|9.420550|10.864472|26.005219|9.367573|5.756491|4.305679|4.063661|4.894889|7.602971|8.229500|9.585137|25.580672|3.393200|0.059261|0.048075|0.043530|0.051391|0.076162|0.090289|0.081098|0.061754|0.065579|0.051663|0.050974|0.205801|0.226008|0.500000| 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