Version2.4 2021-05-21T08:15:07Z 10.1021/jm300687e Gaussian16 RevisionB.01 SBUNGAY 14-Jul-2020 #N HF/6-31G(d) OPT=(MaxStep=1) FREQ IOp(6/10=2,6/11=2,6/12=2) DUDE c1ccc(c(c1)NC(=O)c2cc3n(n2)[C@@H](C[C@@H](N3)c4ccco4)C(F)(F)F)Br C00918725 RHF 6-31G(d) (6D,7F) c1ccc(c(c1)NC(=O)c2cc3n(n2)[C@@H](C[C@@H](N3)c4ccco4)C(F)(F)F)Br C01[X(C18H14Br1F3N4O2)] 120 C1 463 O=C(c1cc2n(n1)[C@@H](C[C@@H](N2)c1ccco1)C(F)(F)F)Nc1ccccc1Br O=C(c1cc2n(n1)[C@@H](C[C@@H](N2)c1ccco1)C(F)(F)F)Nc1ccccc1Br FC(F)(F)[C@@H]1C[C@@H](Nc2cc(nn12)C(=O)Nc3ccccc3Br)c4occc4 InChIKey=MDKKNNOPYIXTLF-DOMZBBRYSA-N InChI=1S/C18H14BrF3N4O2/c19-10-4-1-2-5-11(10)24-17(27)13-9-16-23-12(14-6-3-7-28-14)8-15(18(20,21)22)26(16)25-13/h1-7,9,12,15,23H,8H2,(H,24,27)/t12-,15+/m1/s1 InChI=1/C18H14BrF3N4O2/c19-10-4-1-2-5-11(10)24-17(27)13-9-16-23-12(14-6-3-7-28-14)8-15(18(20,21)22)26(16)25-13/h1-7,9,12,15,23H,8H2,(H,24,27)/t12-,15+/m1/s1/f/h24H c1ccc(c(c1)NC(=O)c2cc3n(n2)[C@@H](C[C@@H](N3)c4ccco4)C(F)(F)F)Br C01[X(C18H14Br1F3N4O2)] 120 C01 463 O=C(c1cc2n(n1)[C@@H](C[C@@H](N2)c1ccco1)C(F)(F)F)Nc1ccccc1Br O=C([C]1[CH][C]2[N@@]([N]1)[C@@H](C[C@@H](N2)C1=[CH][CH]=CO1)C(F)(F)F)N[C]1[CH][CH][CH][CH][C]1Br FC(F)(F)[C@@H]1C[C@@H](N[C]2[CH][C]([N]N12)C(=O)N[C]3[CH][CH][CH][CH][C]3Br)c4occc4 InChIKey=MDKKNNOPYIXTLF-DOMZBBRYSA-N InChI=1S/C18H14BrF3N4O2/c19-10-4-1-2-5-11(10)24-17(27)13-9-16-23-12(14-6-3-7-28-14)8-15(18(20,21)22)26(16)25-13/h1-7,9,12,15,23H,8H2,(H,24,27)/t12-,15+/m1/s1 InChI=1/C18H14BrF3N4O2/c19-10-4-1-2-5-11(10)24-17(27)13-9-16-23-12(14-6-3-7-28-14)8-15(18(20,21)22)26(16)25-13/h1-7,9,12,15,23H,8H2,(H,24,27)/t12-,15+/m1/s1/f/h24H 3086.9607277554 -3925.5003735 1-A 17088.4965 114 349 463 |A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A| -490.06502 -64.47617 -58.61537 -58.61363 -58.61337 -26.34566 -26.34387 -26.34039 -20.64530 -20.53590 -15.66085 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|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A| 0.11255 0.13752 0.14783 0.16147 0.17290 0.20191 0.21760 0.22855 0.24703 0.25510 0.26574 0.27229 0.27412 0.28381 0.28922 0.29209 0.30366 0.30795 0.31506 0.32145 0.32306 0.33111 0.34231 0.35798 0.36307 0.36648 0.37411 0.37661 0.39295 0.40097 0.40854 0.41606 0.43265 0.44999 0.46249 0.46363 0.47144 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3.02322 3.03612 3.07006 3.08408 3.09714 3.10314 3.11843 3.12069 3.14050 3.14157 3.15168 3.15898 3.18910 3.21031 3.23008 3.23696 3.25914 3.28921 3.32281 3.36707 3.37565 3.39794 3.41943 3.43113 3.45082 3.49295 3.51977 3.53094 3.56399 3.61276 3.70766 3.75831 3.83406 4.31830 4.42793 4.48998 4.51664 4.53716 4.54672 4.55614 4.56691 4.58472 4.63239 4.69359 4.71367 4.73222 4.75720 4.76556 4.78810 4.82146 4.87093 4.91130 4.97067 5.05428 5.09833 5.16065 5.19156 5.22490 5.35571 5.85147 9.30776 74.98283 11.32610 -5.6476 -0.5701 -2.6794 6.2769 |XX|YY|ZZ|XY|XZ|YZ| -124.3541 -177.9016 -171.0435 6.3023 7.8256 0.0975 |XX|YY|ZZ|XY|XZ|YZ| 33.4123 -20.1352 -13.2771 6.3023 7.8256 0.0975 |XXX|YYY|ZZZ|XYY|XXY|XXZ|XZZ|YZZ|YYZ|XYZ| -46.1789 107.9743 -1.8589 16.2348 -34.0038 -10.8916 -18.6238 38.0783 -4.7113 -9.8053 |XXXX|YYYY|ZZZZ|XXXY|XXXZ|YYYX|YYYZ|ZZZX|ZZZY|XXYY|XXZZ|YYZZ|XXYZ|YYXZ|ZZXY| -14974.1833 -2960.3374 -461.6497 251.9796 -92.0493 202.2752 -5.0618 -68.7344 13.6846 -3477.6621 -3104.2629 -570.6005 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102.3127 2.9805 22.3470 129.3435 94.3356 14.0607 194.2940 9.9062 65.8902 90.1786 111.9635 281.3211 82.4655 121.5664 46.3366 23.9940 25.4148 15.2224 30.6570 96.2095 75.8051 10.2333 62.3135 14.2003 18.7443 339.0146 455.0418 272.9832 7.4328 433.8204 1.7963 279.5427 37.5465 17.5522 8.2770 10.9797 5.6872 23.1964 12.8218 5.8330 1.3511 4.8573 3.5971 2.4051 30.7752 72.9411 1.5822 2.1703 0.3068 3.0629 0.2018 0.5463 3.1064 2.1808 3.7917 0.1406 2.1927 2.4676 1.9090 2.0158 2.1423 0.3848 2.4465 1.2196 2.2771 3.1068 4.2260 1.2581 3.2405 2.8991 0.8896 1.1089 0.3040 0.4498 0.4427 1.2606 0.8196 0.2870 2.0963 2.2998 2.4579 2.4811 0.2666 3.7851 5.3095 0.4887 2.6784 1.9299 4.4501 1.1870 1.2949 5.2809 4.9406 0.3055 1.9138 4.5755 0.2662 14.6066 2.0922 1.3199 5.4536 2.6896 2.4590 2.5266 5.8947 4.9883 0.2521 6.9288 5.0499 6.8582 15.4369 0.6362 13.9557 9.3750 7.7764 6.3279 33.8531 4.5046 2.2442 2.6215 4.2353 2.4746 4.2872 11.9247 1.3542 20.4691 3.3882 6.8723 13.2887 22.6514 10.0622 33.5748 3.2464 1.8934 6.7884 6.8698 13.3287 16.6234 39.0349 8.9736 18.5398 7.4064 18.8505 16.3178 120.9719 47.6075 15.0445 14.9158 70.5026 60.8147 40.7360 90.5813 52.2119 71.5716 60.4895 54.6147 69.2723 161.0724 159.9724 70.8540 98.8785 52.3916 59.8190 132.7093 68.7086 70.4328 0.7498 0.7498 0.7463 0.7494 0.7365 0.7496 0.7500 0.7481 0.7465 0.6986 0.7301 0.7335 0.2698 0.7437 0.7261 0.4523 0.1539 0.4107 0.6922 0.2994 0.1612 0.2147 0.4591 0.7216 0.4825 0.7442 0.7499 0.2906 0.7044 0.4887 0.4107 0.7499 0.7486 0.6679 0.5785 0.5144 0.5880 0.3126 0.1731 0.5822 0.4490 0.3302 0.4408 0.4269 0.7476 0.0869 0.7264 0.7028 0.7481 0.1278 0.6711 0.2050 0.7243 0.2186 0.7404 0.5368 0.7500 0.7384 0.0917 0.2931 0.7499 0.1561 0.2409 0.6718 0.2810 0.7487 0.1276 0.0214 0.3793 0.6041 0.7482 0.4715 0.3914 0.6242 0.5960 0.2716 0.7264 0.2025 0.4221 0.5662 0.6653 0.1217 0.2001 0.7046 0.2400 0.2691 0.7216 0.6260 0.4948 0.6034 0.7496 0.4555 0.2832 0.7175 0.3410 0.4900 0.5330 0.2674 0.2340 0.2433 0.5313 0.5960 0.5712 0.4140 0.3189 0.1882 0.2364 0.2213 0.1066 0.6085 0.7007 0.3507 0.1603 0.6990 0.2939 0.1972 0.2897 0.1659 0.2341 0.2020 0.8570 0.8570 0.8547 0.8568 0.8482 0.8569 0.8571 0.8559 0.8548 0.8226 0.8440 0.8463 0.4250 0.8530 0.8413 0.6229 0.2667 0.5823 0.8181 0.4609 0.2776 0.3535 0.6293 0.8383 0.6509 0.8534 0.8571 0.4503 0.8266 0.6565 0.5823 0.8571 0.8562 0.8009 0.7330 0.6794 0.7405 0.4763 0.2951 0.7359 0.6197 0.4965 0.6119 0.5983 0.8556 0.1599 0.8415 0.8255 0.8559 0.2266 0.8032 0.3402 0.8401 0.3587 0.8509 0.6986 0.8571 0.8495 0.1680 0.4534 0.8571 0.2700 0.3883 0.8037 0.4387 0.8563 0.2263 0.0419 0.5500 0.7532 0.8560 0.6409 0.5626 0.7686 0.7469 0.4272 0.8416 0.3368 0.5936 0.7230 0.7990 0.2169 0.3334 0.8267 0.3871 0.4240 0.8383 0.7700 0.6620 0.7526 0.8569 0.6259 0.4414 0.8355 0.5085 0.6577 0.6954 0.4220 0.3793 0.3914 0.6939 0.7469 0.7271 0.5856 0.4835 0.3168 0.3824 0.3624 0.1926 0.7566 0.8240 0.5193 0.2764 0.8228 0.4543 0.3294 0.4492 0.2846 0.3794 0.3361 298.150 1.00000 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 6 6 6 6 6 6 7 6 8 6 6 6 7 7 6 1 6 6 1 7 6 6 6 6 8 6 9 9 9 35 1 1 1 1 1 1 1 1 1 1 1 1 12.00000 12.00000 12.00000 12.00000 12.00000 12.00000 14.00307 12.00000 15.99491 12.00000 12.00000 12.00000 14.00307 14.00307 12.00000 1.00783 12.00000 12.00000 1.00783 14.00307 12.00000 12.00000 12.00000 12.00000 15.99491 12.00000 18.99840 18.99840 18.99840 78.91834 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 5320.0720 27682.8688 31970.7356 0.99994 -0.01005 0.00526 0.01005 0.99995 -0.00069 -0.00525 0.00074 0.99999 1 0.01628 0.00313 0.00271 0.33923 0.06519 0.05645 12.34 27.89 47.45 60.59 76.77 82.23 90.08 101.28 125.76 136.93 198.16 236.09 269.79 279.35 311.10 338.75 381.22 392.11 443.35 463.50 478.20 490.98 526.85 555.54 596.98 629.68 714.92 730.38 736.00 804.33 834.57 868.30 873.15 909.02 949.55 951.13 1016.23 1027.09 1043.48 1049.69 1082.29 1084.56 1122.89 1156.46 1185.43 1200.88 1226.77 1240.28 1245.80 1287.96 1294.80 1326.43 1369.26 1385.37 1399.61 1400.83 1444.49 1457.89 1486.94 1500.83 1571.78 1583.12 1588.94 1603.30 1607.97 1635.63 1662.08 1675.87 1736.69 1739.57 1745.63 1769.68 1798.37 1848.08 1881.79 1896.49 1907.19 1918.36 1930.07 1943.79 1976.41 1994.37 2002.11 2029.31 2068.24 2075.12 2093.03 2141.34 2163.88 2179.50 2243.26 2246.29 2275.70 2291.41 2312.45 2354.36 2362.09 2406.24 2454.83 2469.82 2501.73 2554.29 2580.72 2590.04 2613.75 2833.14 4561.99 4682.10 4703.03 4781.86 4847.31 4872.78 4898.58 4941.83 4963.13 4992.44 4998.12 5014.71 5513.27 5527.94 0.332385 0.354434 0.355379 0.275668 -3925.167989 -3925.145939 -3925.144995 -3925.224705 2.673487D-04 MUNgauss RevisionA2.1 retrievium 21-May-2021 DUDE c1ccc(c(c1)NC(=O)c2cc3n(n2)[C@@H](C[C@@H](N3)c4ccco4)C(F)(F)F)Br C00918725 RHF 6-31G(d) (6D,10F) C1 454.025222 |X|Y|Z| 50.351749 20.149085 118.943598 49.416311 22 6 7 8 17 4 1 |36.858105| |13.766046|36.858105| |7.996797|13.790244|36.858105| |6.943883|7.958474|13.783819|36.858105| |7.897342|6.784395|7.850910|13.649705|36.858105| |13.782195|7.905994|6.880903|7.982211|13.650480|36.858105| |5.134571|4.529439|5.160927|7.894865|13.621291|7.756808|53.358707| |4.342594|3.675069|3.885936|5.132852|7.671542|6.334044|19.098160|36.858105| |4.514922|3.611879|3.590701|4.413429|6.479487|6.597846|11.367366|15.888960|73.516695| |3.258619|2.912410|3.135418|3.997222|5.080295|4.255727|10.860095|12.751579|14.479353|36.858105| |2.746974|2.452898|2.570610|3.106405|3.788026|3.430495|6.959171|7.373587|11.591191|13.522874|36.858105| |2.376823|2.186723|2.328110|2.786590|3.222694|2.869244|5.727597|5.242014|8.056410|8.749114|13.938098|36.858105| |2.467502|2.317586|2.537793|3.108984|3.509177|2.979664|6.419634|5.387837|7.647908|9.090239|8.703385|14.108300|53.358707| |2.964751|2.767734|3.088161|3.975689|4.645494|3.716943|9.523727|7.809762|9.657310|14.679512|8.456329|8.553726|19.318123|53.358707| |2.161742|2.081478|2.300613|2.758415|2.959110|2.526089|5.079342|3.934321|5.822553|5.474439|5.300173|7.635435|17.944770|10.644698|36.858105| |2.144611|2.082248|2.315284|2.768978|2.925670|2.488030|4.947056|3.730992|5.539490|4.942438|4.638772|6.101736|12.524518|9.393994|17.576170|0.500000| |1.879672|1.802948|1.953752|2.275834|2.440553|2.159915|4.030146|3.196059|4.991255|4.240501|4.603614|6.822663|10.650091|6.983329|12.399301|0.243713|36.858105| |1.855028|1.753097|1.867384|2.158067|2.361562|2.138114|3.885579|3.209406|5.170684|4.274369|5.149424|7.948099|9.440590|6.394858|7.508723|0.178602|12.450416|36.858105| |1.866351|1.766060|1.882120|2.173128|2.372826|2.147978|3.888666|3.190993|5.143605|4.180418|4.886280|6.951339|8.696050|6.249224|6.875885|0.189454|8.854331|17.475926|0.500000| |2.034685|1.888949|1.993320|2.321373|2.614289|2.386311|4.391668|3.828472|6.233880|5.373410|7.586077|13.832231|10.965508|7.368405|6.565728|0.149056|7.911330|13.072303|0.250714|53.358707| |1.632046|1.547217|1.632226|1.850031|2.003740|1.849184|3.196642|2.608306|4.330549|3.264801|3.879345|5.169639|6.187230|4.704488|4.923031|0.123431|7.595847|12.753111|0.253509|10.703016|36.858105| |1.503378|1.428391|1.497904|1.677939|1.806048|1.685214|2.829051|2.288009|3.857666|2.764314|3.219268|3.985414|4.865780|3.920071|3.827031|0.101846|5.199879|7.356170|0.195597|7.358084|14.201815|36.858105| |1.379463|1.314072|1.372041|1.522429|1.629150|1.532276|2.517275|2.020298|3.440213|2.385450|2.742907|3.274476|4.044095|3.354485|3.163245|0.083100|4.168826|5.142948|0.130472|5.792833|8.569914|13.227866|36.858105| |1.413683|1.346451|1.408596|1.567697|1.679213|1.574378|2.605645|2.093549|3.550352|2.490095|2.872484|3.472011|4.282044|3.514638|3.355070|0.085005|4.555226|5.332820|0.124470|6.232995|8.786171|8.610700|14.232520|36.858105| |1.561745|1.483516|1.561549|1.759524|1.897451|1.759311|2.998686|2.431046|4.062600|2.987585|3.507373|4.496766|5.463249|4.276016|4.318758|0.104834|6.441349|7.827196|0.160169|8.724938|14.152818|8.641574|8.627001|14.175782|73.516695| |2.148653|2.108709|2.370188|2.839479|2.943693|2.477782|4.928921|3.599330|5.317366|4.607416|4.192450|5.248022|10.556035|8.785684|12.486138|0.251518|7.604630|4.949127|0.124987|6.284073|3.813033|3.089759|2.709130|2.934698|6.471947|36.858105| |2.362468|2.358878|2.727592|3.340222|3.354143|2.725141|5.608580|3.825888|5.510933|4.632263|3.891237|4.461910|8.793839|9.090184|8.041466|0.209355|5.178396|3.893586|0.103820|5.130360|3.093057|2.614462|2.310354|2.452721|5.212373|14.494861|97.533100| |1.887704|1.872014|2.092104|2.438206|2.476498|2.128871|3.975315|2.886655|4.409918|3.515801|3.325252|4.080172|7.218666|6.141388|8.203069|0.202828|6.959838|4.486861|0.114819|5.315966|3.711975|3.080189|2.746849|2.970457|6.398221|14.346228|20.180702|97.533100| |2.147060|2.092233|2.326905|2.767280|2.902262|2.476415|4.824471|3.585996|5.377179|4.528935|4.224623|5.143164|9.256163|7.963307|8.070753|0.163398|6.454362|4.536934|0.109309|6.226723|3.659786|2.936409|2.655489|2.968834|6.586024|14.458578|20.095822|20.064818|97.533100| |4.098013|4.612799|6.745777|9.994549|6.611569|4.571974|8.400569|4.326442|6.325155|3.863076|3.008310|2.858040|4.589712|5.834832|3.149531|0.089381|2.516446|2.295634|0.064220|3.259627|1.951180|1.758750|1.590500|1.641809|3.295090|3.408392|9.749300|6.589974|7.222057|2539.412838| |17.719956|8.919710|5.669333|4.988993|5.641251|8.984078|5.670383|3.781290|7.310321|2.917632|2.542870|2.199642|3.051832|3.580539|1.971838|0.054228|1.743385|1.738181|0.048556|2.599584|1.545623|1.432816|1.321376|1.351604|2.636783|1.946973|4.740391|3.884017|4.398609|113.254493|0.500000| |8.883394|17.730787|8.930211|5.656599|4.906867|5.627395|4.910708|3.051716|5.399743|2.502491|2.158429|1.946960|2.791019|3.260716|1.866975|0.051973|1.638301|1.595648|0.044662|2.324008|1.423119|1.322385|1.223492|1.251517|2.434058|1.895822|4.733802|3.838541|4.237878|130.799645|0.213807|0.500000| |5.664212|8.905066|17.753368|8.972055|5.622903|4.959156|5.716699|3.275084|5.364467|2.767588|2.307631|2.134482|3.187562|3.802383|2.172889|0.061111|1.854850|1.758454|0.049260|2.520654|1.547455|1.425692|1.310901|1.344869|2.638803|2.269064|5.913178|4.576596|4.988237|224.647490|0.124226|0.214332|0.500000| |8.939188|5.644032|4.965519|5.675310|8.941336|17.838136|9.644104|7.006024|15.434984|4.531396|3.757674|3.033881|4.147884|5.097046|2.533328|0.068710|2.195004|2.213657|0.061650|3.426542|1.917198|1.747001|1.587184|1.630171|3.239674|2.435520|5.883318|4.699683|5.518360|129.355644|0.216988|0.124050|0.107788|0.500000| |4.271234|4.039369|4.848573|7.469659|9.300429|5.734414|26.004656|9.550959|10.883555|7.867493|4.974300|4.389775|7.247446|11.565197|4.292530|0.116961|3.251173|3.030192|0.084194|4.553468|2.457611|2.157462|1.910954|1.983032|4.087905|4.280770|11.597070|7.564388|9.167062|255.952782|0.097971|0.091683|0.115175|0.144159|0.500000| |2.698265|2.369734|2.424120|2.858927|3.505853|3.339811|6.079268|6.435021|11.869933|8.542848|17.840206|8.662764|8.023773|7.913287|4.139290|0.103530|3.832668|4.429616|0.117677|8.728261|3.581868|3.063030|2.655990|2.764959|5.844975|3.417829|7.202297|6.358931|7.870750|91.242600|0.070786|0.058352|0.060303|0.104978|0.115740|0.500000| |1.834002|1.758648|1.898802|2.199284|2.356273|2.099290|3.856208|3.058433|4.825785|3.981680|4.353973|6.171492|9.091970|6.357586|8.825165|0.174259|17.607204|8.940630|0.174598|9.879486|6.969065|4.757371|4.124606|4.852177|12.735612|7.314688|11.002833|15.275436|16.753503|82.224155|0.047395|0.044503|0.050124|0.059354|0.085729|0.102817|0.500000| |1.741133|1.687094|1.831643|2.109110|2.221204|1.973185|3.584445|2.775006|4.377151|3.512498|3.701993|5.003384|7.767010|5.719510|8.875332|0.222481|17.622930|8.840779|0.212912|7.731757|6.961777|5.245048|4.243014|4.497024|10.514119|6.656028|10.756239|16.530595|12.174740|80.382632|0.044958|0.042879|0.048789|0.055275|0.080410|0.088415|0.302015|0.500000| |1.977813|1.821464|1.897101|2.183757|2.474259|2.308622|4.079901|3.605173|6.115169|4.796492|7.021783|9.555531|8.107174|6.162796|4.942668|0.120138|5.742947|9.163192|0.211024|25.994500|7.271169|5.513640|4.370374|4.558273|10.587022|3.723312|7.138807|7.309080|8.360493|75.019557|0.052101|0.045931|0.048855|0.068522|0.084291|0.187978|0.150182|0.126759|0.500000| 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