Version2.2 2021-02-07T16:28:53Z 10.1021/jm300687e Gaussian16 RevisionB.01 CFLINN 22-Dec-2020 #N HF/6-31G(d) OPT=(MaxStep=1) FREQ IOp(6/10=2,6/11=2,6/12=2) DUDE c1ccc(cc1)C2=c3ccccc3=[NH+][C@@H]2C(=O)NNC(=S)Nc4cccc(c4)C(F)(F)F C63582073 RHF 6-31G(d) (6D,7F) c1ccc(cc1)C2=c3ccccc3=[NH+][C@@H]2C(=O)NNC(=S)Nc4cccc(c4)C(F)(F)F C01[X(C23H18F3N4O1S1)] 144 C1 520 S=C(Nc1cccc(c1)C(F)(F)F)NNC(=O)[C@H]1[NH+]=c2c(=C1c1ccccc1)cccc2 S=C(Nc1cccc(c1)C(F)(F)F)NNC(=O)[C@H]1[NH+]=c2c(=C1c1ccccc1)cccc2 FC(F)(F)c1cccc(NC(=S)NNC(=O)[C@H]2[NH+]=C3C=CC=CC3=C2c4ccccc4)c1 InChIKey=UPCSKCOAFLNDJW-FQEVSTJZSA-O InChI=1S/C23H17F3N4OS/c24-23(25,26)15-9-6-10-16(13-15)27-22(32)30-29-21(31)20-19(14-7-2-1-3-8-14)17-11-4-5-12-18(17)28-20/h1-13,20H,(H,29,31)(H2,27,30,32)/p+1/t20-/m0/s1 InChI=1/C23H17F3N4OS/c24-23(25,26)15-9-6-10-16(13-15)27-22(32)30-29-21(31)20-19(14-7-2-1-3-8-14)17-11-4-5-12-18(17)28-20/h1-13,20H,(H,29,31)(H2,27,30,32)/p+1/t20-/m0/s1/fC23H18F3N4OS/h27-30H/q+1 c1ccc(cc1)C2=c3ccccc3=[NH+][C@@H]2C(=O)NNC(=S)Nc4cccc(c4)C(F)(F)F C01[X(C23H18F3N4O1S1)] 144 C01 520 S=C(Nc1cccc(c1)C(F)(F)F)NNC(=O)[C@H]1[NH+]=c2c(=C1c1ccccc1)cccc2 S[C]([NH][C]1[CH][CH][CH][C]([CH]1)C(F)(F)F)NNC(=O)[C@H]1[NH][C]2[C](=C1[C]1[CH][CH][CH][CH][CH]1)[CH]=[CH][CH]=[CH]2 FC(F)(F)[C]1[CH][CH][CH][C]([CH]1)N[C](S)NNC(=O)[C@H]2N[C]3C=CC=CC3=C2[C]4[CH][CH][CH][CH][CH]4 InChIKey=NFCJHUWJAHJROC-FQEVSTJZSA-N InChI=1S/C23H19F3N4OS/c24-23(25,26)15-9-6-10-16(13-15)27-22(32)30-29-21(31)20-19(14-7-2-1-3-8-14)17-11-4-5-12-18(17)28-20/h1-13,20,27-28,30,32H,(H,29,31)/t20-/m0/s1 InChI=1/C23H19F3N4OS/c24-23(25,26)15-9-6-10-16(13-15)27-22(32)30-29-21(31)20-19(14-7-2-1-3-8-14)17-11-4-5-12-18(17)28-20/h1-13,20,27-28,30,32H,(H,29,31)/t20-/m0/s1/f/h29H 3165.2285738003 -1869.7311895 1-A 21092.8115 117 403 520 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441.9435 450.0419 450.7890 494.6743 496.9795 507.8717 519.0555 530.8409 539.5613 546.9707 564.4925 570.0208 581.3642 616.8204 635.9072 642.9431 655.2827 669.2163 678.8142 683.7467 709.1875 722.4001 742.1776 767.0282 772.0511 777.9236 790.8720 817.4721 828.8306 833.7875 855.2917 862.0705 890.9147 912.9739 926.8595 954.6760 963.7911 969.3703 1011.4463 1023.7604 1048.6227 1056.5711 1060.8463 1066.0397 1067.0218 1086.9588 1093.5872 1118.9280 1124.0163 1128.2360 1128.8368 1138.3595 1154.5853 1158.6466 1168.1277 1181.5256 1198.9904 1210.3892 1220.1245 1233.3053 1237.5635 1251.3668 1281.6588 1283.5269 1306.6397 1319.4768 1324.4903 1335.5153 1349.2067 1354.4006 1361.8127 1387.1490 1393.1602 1425.0891 1433.7370 1459.8209 1473.9726 1482.0948 1490.8385 1497.3685 1531.5442 1571.0778 1596.3620 1599.1792 1606.7315 1613.5250 1665.3244 1670.5694 1687.6519 1690.6981 1718.6179 1732.8489 1756.7588 1771.7887 1790.5006 1801.7833 1826.8751 1833.9026 2018.4119 3256.3214 3363.5796 3382.3106 3387.5917 3389.0515 3391.1686 3393.1499 3400.9061 3408.0364 3410.4627 3411.1635 3414.1423 3416.3385 3425.5826 3837.6230 3841.8867 3855.1962 3863.9632 7.1803 17.2050 9.0303 5.9735 7.9516 7.2604 8.6343 7.9610 4.1901 6.7789 4.8864 6.1810 5.3863 8.0160 7.0521 5.6573 5.1909 7.3738 6.4008 5.9786 4.9094 4.8623 7.3796 5.8997 6.3222 4.2930 7.6977 5.0388 3.1655 3.4124 4.1872 2.4574 2.3244 2.4913 1.8303 2.6922 2.8999 6.3594 2.2147 1.8791 4.3718 11.2114 5.7463 3.6580 4.8479 3.3396 3.9855 6.9237 7.0894 5.8767 6.3135 2.1821 2.2091 4.3512 6.5504 3.0993 3.8929 1.6872 1.5462 6.1018 1.4989 5.0491 1.5645 1.2841 4.4052 6.4376 1.6054 4.6421 2.6818 2.6376 1.6372 1.4042 5.9293 5.9731 1.3686 2.7415 1.3572 1.3050 2.4905 1.3599 1.3996 3.2846 2.4127 1.8214 1.7503 3.2020 2.3271 3.1740 2.0473 1.3231 2.1780 1.1813 1.4163 1.4853 1.7569 10.7532 1.8128 3.0417 1.9219 5.5320 2.4838 2.3639 1.3684 1.4588 3.3405 2.5541 2.0977 2.4829 3.2136 1.7613 3.3441 2.5705 2.4632 2.2005 2.5372 1.5477 1.3981 1.9695 5.8590 4.0618 4.9815 4.9036 5.6470 5.4537 5.7687 10.7801 1.0851 1.0906 1.0899 1.0907 1.0928 1.0925 1.0912 1.0959 1.0911 1.0991 1.0937 1.0975 1.0973 1.0995 1.0799 1.0788 1.0811 1.0759 0.0002 0.0008 0.0006 0.0017 0.0051 0.0071 0.0143 0.0179 0.0106 0.0254 0.0261 0.0410 0.0518 0.0940 0.1509 0.1274 0.1608 0.2487 0.2584 0.2549 0.2304 0.2965 0.5340 0.4506 0.4886 0.3653 0.7155 0.5798 0.3777 0.4086 0.6037 0.3576 0.3532 0.3955 0.3039 0.4618 0.5112 1.1939 0.4240 0.3742 0.9800 2.6712 1.3995 0.9254 1.2792 0.9067 1.0978 2.0517 2.1798 1.9072 2.1885 0.7663 0.7877 1.6035 2.5791 1.2544 1.5945 0.7272 0.6770 2.8535 0.7361 2.5556 0.8401 0.7028 2.4389 3.8802 0.9914 3.0075 1.7639 1.7489 1.0962 0.9419 4.1275 4.2088 1.0096 2.0407 1.0179 0.9798 1.9015 1.0681 1.1070 2.6407 1.9845 1.5428 1.5109 2.8085 2.0855 2.8641 1.8888 1.2806 2.1141 1.1882 1.4528 1.5352 1.8462 11.5331 1.9593 3.3235 2.1788 6.3261 2.9720 2.8630 1.7182 1.8673 4.3232 3.3446 2.7711 3.4313 4.6734 2.6445 5.0388 3.9097 3.7783 3.5955 4.1719 2.5972 2.3546 3.4274 10.3657 7.3856 9.2138 9.2623 10.8013 10.7240 11.4310 25.8757 6.7791 7.2697 7.3465 7.3747 7.3948 7.4026 7.4019 7.4679 7.4669 7.5322 7.4984 7.5371 7.5455 7.6019 9.3702 9.3817 9.4674 9.4646 0.0996 0.1330 0.6693 0.5599 3.3842 1.2183 2.9785 3.3836 3.2813 1.0542 1.3610 5.4001 1.1827 0.3083 0.4454 0.3422 2.3595 10.2471 4.1634 2.7902 7.1651 18.6066 4.1124 5.9322 1.5364 24.1716 8.5787 10.0308 14.8905 8.3864 10.8241 9.2706 26.5190 5.9388 170.7640 22.6088 30.0311 12.7456 47.4284 30.2983 25.0981 1.9682 28.4137 90.9465 0.1225 41.6516 89.6649 12.2247 48.8108 12.6992 10.0546 33.0304 28.4313 23.1011 17.8124 36.8869 31.3309 10.2758 88.1817 5.4563 27.9382 48.9936 7.3823 4.5694 12.8162 11.8279 7.7398 22.7864 32.0715 16.2813 8.1079 6.1405 8.1647 1.8092 1.3710 5.6218 0.1630 0.1074 3.7137 0.2807 2.3099 16.9240 47.5437 1.3473 20.2188 82.4077 3.8337 9.9328 25.0184 128.6438 350.4009 15.5667 28.2047 5.0999 57.3210 301.3601 30.7679 69.9816 76.6705 220.9574 65.4939 165.8995 22.1415 35.1911 499.9666 68.9807 77.0406 60.3102 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1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 8185.4157 34911.6788 37320.6361 0.99996 -0.00632 -0.00627 0.00628 0.99996 -0.00570 0.00630 0.00566 0.99996 1 0.01058 0.00248 0.00232 0.22048 0.05169 0.04836 8.77 12.65 14.84 32.06 47.64 58.47 76.23 89.00 94.06 114.74 137.01 152.69 183.85 202.93 274.22 281.27 329.92 344.25 376.60 387.07 406.09 462.85 504.21 518.04 521.07 546.75 571.49 635.86 647.51 648.58 711.73 715.04 730.71 746.81 763.76 776.31 786.97 812.18 820.13 836.45 887.47 914.93 925.05 942.81 962.85 976.66 983.76 1020.36 1039.37 1067.83 1103.58 1110.81 1119.26 1137.89 1176.16 1192.50 1199.63 1230.57 1240.33 1281.83 1313.57 1333.54 1373.57 1386.68 1394.71 1455.25 1472.96 1508.73 1520.17 1526.32 1533.79 1535.21 1563.89 1573.43 1609.89 1617.21 1623.28 1624.14 1637.85 1661.19 1667.03 1680.68 1699.95 1725.08 1741.48 1755.49 1774.45 1780.58 1800.44 1844.02 1846.71 1879.96 1898.43 1905.65 1921.51 1941.21 1948.68 1959.34 1995.80 2004.45 2050.39 2062.83 2100.36 2120.72 2132.40 2144.98 2154.38 2203.55 2260.43 2296.81 2300.86 2311.73 2321.50 2396.03 2403.58 2428.15 2432.54 2472.71 2493.18 2527.58 2549.21 2576.13 2592.36 2628.47 2638.58 2904.04 4685.12 4839.44 4866.39 4873.99 4876.09 4879.14 4881.99 4893.15 4903.40 4906.90 4907.90 4912.19 4915.35 4928.65 5521.48 5527.62 5546.77 5559.38 0.406712 0.432333 0.433277 0.343096 -1869.324477 -1869.298857 -1869.297913 -1869.388093 3.024652D-04 MUNgauss RevisionA2.1 retrievium 07-Feb-2021 DUDE c1ccc(cc1)C2=c3ccccc3=[NH+][C@@H]2C(=O)NNC(=S)Nc4cccc(c4)C(F)(F)F C63582073 RHF 6-31G(d) (6D,10F) C1 455.115343 |X|Y|Z| 54.634959 40.354230 128.370529 65.656088 26 6 7 22 4 |36.858105| |13.743963|36.858105| |7.938235|13.768802|36.858105| |6.858455|7.913887|13.654523|36.858105| |7.941786|6.860993|7.894904|13.623458|36.858105| |13.721614|7.919574|6.855285|7.906941|13.786794|36.858105| |4.488599|5.079570|7.675993|12.990083|7.667975|5.077922|36.858105| |3.655865|4.229639|6.030472|7.466382|5.184712|3.908253|14.018747|36.858105| |3.468611|4.129321|5.615483|5.839872|4.294768|3.516564|7.423416|13.202906|36.858105| |2.794006|3.231201|4.062897|4.159786|3.321044|2.822927|5.135279|7.962668|14.197433|36.858105| |2.442784|2.747056|3.386472|3.606001|2.980253|2.519160|4.649401|6.890830|7.865265|13.178505|36.858105| |2.476637|2.741462|3.412722|3.822207|3.178679|2.617340|5.292259|7.665367|6.608397|7.707353|14.037714|36.858105| |2.945421|3.267895|4.262687|5.140630|4.086867|3.188067|8.412794|13.213990|7.647333|6.824585|8.088437|13.496344|36.858105| |2.947780|3.163589|4.027929|5.117805|4.317037|3.297129|8.246420|8.421816|5.285987|4.654272|5.258523|7.729324|14.433925|53.358707| |2.598633|2.757002|3.384203|4.112020|3.627557|2.882539|5.843359|5.943744|4.246109|3.962796|4.659340|6.854445|9.319058|25.985820|0.500000| |3.647887|3.869381|5.074557|7.270557|6.035553|4.243666|12.558952|8.178875|5.065400|4.099873|4.157106|5.214265|8.381613|18.017185|0.247141|36.858105| |3.629989|3.640503|4.498145|6.524493|6.447457|4.461378|8.792269|6.138725|4.252313|3.528669|3.564661|4.338808|6.232457|12.393025|0.202011|17.556286|0.500000| |3.481069|3.735561|4.710338|5.880579|5.008174|3.871387|7.522610|5.643153|4.037995|3.411101|3.472714|4.201377|5.789238|10.615743|0.195369|12.269188|0.242471|36.858105| |2.982259|3.267598|4.045533|4.620391|3.899363|3.184658|5.846977|5.105931|3.832675|3.386034|3.564279|4.363442|5.636103|9.689916|0.198266|7.994167|0.166708|16.080275|73.516695| |3.815016|3.908157|4.609280|5.638527|5.372729|4.326998|5.891241|4.364212|3.372915|2.856360|2.831302|3.265486|4.211116|7.106334|0.135006|7.750064|0.202272|13.979266|14.996422|53.358707| |3.448332|3.560596|3.971987|4.360535|4.163761|3.684721|4.346102|3.502530|2.875735|2.499990|2.477157|2.788257|3.396928|5.401300|0.106750|5.096384|0.132770|8.056889|12.389092|18.854180|53.358707| |2.793105|2.836939|3.086736|3.353806|3.285281|2.980473|3.427879|2.908443|2.441886|2.187538|2.211993|2.495848|2.934297|4.680566|0.096867|4.087270|0.110164|5.880251|10.138833|10.762185|18.788810|36.858105| |2.435578|2.506201|2.659901|2.751586|2.661249|2.501553|2.776742|2.456138|2.140853|1.954064|1.972215|2.177555|2.469083|3.768365|0.078270|3.124167|0.083021|4.156939|7.719884|6.665910|9.933867|11.480557|388.023441| |2.594347|2.577261|2.805463|3.149408|3.183627|2.853444|3.287259|2.800731|2.334581|2.108353|2.160859|2.470338|2.898187|4.764577|0.101109|4.098054|0.116384|5.506753|9.167668|9.618725|11.335646|14.276846|50.480275|53.358707| |2.191595|2.165049|2.318872|2.560415|2.606716|2.388174|2.672214|2.355831|2.011435|1.852628|1.915187|2.172263|2.468500|3.974893|0.085938|3.237563|0.092817|3.996619|6.957190|6.312034|7.085844|7.719612|42.462232|18.161798|36.858105| |1.949692|1.956824|2.106507|2.291548|2.281188|2.090545|2.432893|2.207754|1.905772|1.785065|1.869721|2.121832|2.355426|3.742645|0.082620|2.916610|0.081535|3.560294|6.573981|5.219895|5.821566|5.986472|39.316685|10.587687|13.731431|36.858105| |1.724729|1.721069|1.831838|1.977294|1.983755|1.842105|2.084458|1.919604|1.685004|1.594552|1.671760|1.877259|2.045507|3.191676|0.070275|2.443772|0.068904|2.848885|5.223175|4.116877|4.474502|4.240034|29.673196|6.997644|7.966386|13.795359|36.858105| |1.678194|1.651046|1.736304|1.878015|1.919446|1.802926|1.951544|1.788528|1.579318|1.490449|1.550724|1.728016|1.884940|2.926537|0.063620|2.263293|0.065023|2.570251|4.578048|3.783697|4.048601|3.711813|25.470195|6.181649|6.882118|7.926094|13.727669|36.858105| |1.825592|1.771107|1.850599|2.019033|2.102694|1.984186|2.070604|1.866326|1.639251|1.530410|1.577895|1.756863|1.943576|3.037500|0.065192|2.406530|0.070409|2.723963|4.707755|4.147193|4.412815|4.036117|26.270955|7.029222|7.959830|6.875814|7.958851|13.786093|36.858105| |2.101571|2.033428|2.136843|2.358636|2.469420|2.308057|2.411272|2.127520|1.840223|1.696044|1.740280|1.951176|2.202333|3.498134|0.074603|2.853375|0.084038|3.325901|5.625268|5.288992|5.701682|5.470375|32.392618|10.742511|13.807301|7.931689|6.885645|7.931367|13.725298|36.858105| |1.724540|1.652330|1.704362|1.853738|1.959351|1.877735|1.876654|1.697266|1.507497|1.409282|1.444073|1.591879|1.751062|2.702076|0.057352|2.139099|0.063234|2.346678|4.005670|3.562220|3.714147|3.210125|21.125491|5.291566|5.064715|4.457213|5.037518|7.583947|12.664313|7.651189|36.858105| |1.547262|1.491173|1.533383|1.649515|1.727864|1.665216|1.671775|1.531433|1.374735|1.295466|1.329550|1.456216|1.582044|2.410930|0.051244|1.881566|0.054999|2.051848|3.553080|3.057835|3.203342|2.738540|18.771343|4.330926|4.030962|3.852046|4.619370|6.944252|8.125389|5.299494|14.445912|97.533100| |1.713168|1.632741|1.690093|1.858552|1.981593|1.887331|1.892155|1.714183|1.519733|1.422699|1.462201|1.616612|1.777361|2.754780|0.058577|2.167962|0.065083|2.319634|3.920724|3.477293|3.503450|2.934127|18.729175|4.880659|4.422696|3.899878|4.268423|5.818030|8.146870|6.206119|14.362150|20.126360|97.533100| |1.811792|1.716632|1.747701|1.891120|2.023122|1.971068|1.879022|1.685051|1.502542|1.394973|1.414395|1.547754|1.711962|2.623446|0.054898|2.111063|0.062541|2.315017|3.901472|3.591511|3.782412|3.218826|21.277215|5.144644|4.602556|3.870026|4.077787|5.393593|8.140384|6.821634|14.394961|20.082735|20.171968|97.533100| |17.736057|8.920928|5.649590|4.945898|5.652047|8.915569|3.582062|3.039802|2.944628|2.449244|2.161391|2.176934|2.526919|3.443726|0.063087|3.038878|0.084702|2.953512|4.602760|4.427816|4.148409|2.542178|16.143081|3.222454|2.036649|1.818149|1.625195|1.592963|1.734035|1.977107|1.655010|3.359860|3.689573|3.942719|0.500000| |8.911040|17.739167|8.939143|5.637752|4.947562|5.637977|4.131600|3.660864|3.728332|3.023457|2.566385|2.517659|2.909088|3.786847|0.068511|3.273131|0.085051|3.241525|5.228207|4.574213|4.345248|2.604504|16.902111|3.194268|2.000850|1.829880|1.620901|1.553349|1.654399|1.880480|1.546899|3.167056|3.421330|3.617705|0.214984|0.500000| |5.650516|8.936868|17.730115|8.875561|5.620986|4.944133|7.067910|6.398489|6.393774|4.595812|3.731457|3.668100|4.478312|5.494597|0.094753|4.781280|0.112939|4.572499|7.403024|5.771084|5.136472|2.979413|18.699201|3.645822|2.232569|2.065129|1.797174|1.687203|1.775951|2.034456|1.626432|3.315719|3.614954|3.725425|0.124325|0.216038|0.500000| |5.654103|4.945259|5.615216|8.841594|17.703807|8.959616|7.040484|4.909712|3.957510|3.161992|2.931676|3.204031|4.136064|6.242843|0.107792|6.454930|0.220527|5.023938|6.858317|7.295924|5.475476|3.279670|18.543883|4.509620|2.728995|2.367596|2.063227|2.009758|2.218383|2.612299|2.074514|4.083645|4.789445|4.793968|0.124436|0.107422|0.123452|0.500000| |8.902143|5.638432|4.944522|5.632676|8.940543|17.738045|4.129520|3.305743|2.999842|2.486134|2.258500|2.353261|2.810955|4.009870|0.073028|3.688289|0.111483|3.395263|5.032419|5.236168|4.551361|2.801176|16.808748|3.730626|2.335929|2.031686|1.808850|1.794361|1.994082|2.308199|1.916088|3.814441|4.362083|4.568916|0.214876|0.124029|0.107402|0.216648|0.500000| |3.925947|4.842565|6.555886|6.166137|4.521446|3.835604|6.569214|8.715982|17.762445|9.019321|5.586850|4.816816|5.501902|5.834957|0.098374|4.415106|0.106946|3.657719|6.073114|4.362669|3.777515|2.342961|14.734640|3.025496|1.917893|1.805265|1.602631|1.512736|1.578308|1.770936|1.461576|3.002015|3.307711|3.304532|0.091976|0.122027|0.208455|0.111037|0.089434|0.500000| |2.606715|3.008190|3.626679|3.571025|2.939886|2.584701|4.102945|5.629952|9.047351|17.757517|8.773379|5.585525|4.932709|5.020064|0.090169|3.352921|0.082491|2.888570|5.116019|3.393783|3.033157|1.969747|12.712943|2.579405|1.683309|1.627653|1.466842|1.377014|1.411332|1.552520|1.307848|2.720015|2.967445|2.919933|0.064552|0.080119|0.113857|0.077365|0.063846|0.215371|0.500000| |2.159704|2.404653|2.871642|3.001217|2.554890|2.211534|3.683656|4.962774|5.656405|8.800710|17.724043|9.086247|5.709329|5.716929|0.108837|3.402727|0.083399|2.951328|5.452645|3.354031|2.995573|2.000016|12.883238|2.667888|1.764085|1.739621|1.571964|1.459565|1.475321|1.610422|1.355267|2.826748|3.088257|2.978921|0.053881|0.063356|0.087396|0.070102|0.055796|0.124009|0.215645|0.500000| |2.209050|2.405527|2.910860|3.243685|2.797894|2.341597|4.294971|5.500962|4.816254|5.520137|8.938784|17.757104|8.772090|9.259428|0.193742|4.562791|0.109438|3.860145|7.324300|4.136016|3.587588|2.422331|15.132041|3.309452|2.174380|2.156563|1.920558|1.758867|1.770579|1.948704|1.599741|3.305576|3.665107|3.467577|0.054601|0.061843|0.085796|0.079516|0.059404|0.105254|0.123130|0.216559|0.500000| |4.539059|4.440427|5.127580|6.622626|6.978110|5.459565|6.170963|4.351631|3.404318|2.828681|2.739758|3.097935|3.996873|6.535245|0.120203|7.359666|0.212131|9.317942|10.880345|25.991347|12.948892|6.157819|29.715295|7.872966|4.081680|3.349892|2.734036|2.584580|2.881439|3.638109|2.548093|4.910864|5.654608|5.886796|0.105086|0.102408|0.123191|0.192640|0.133226|0.092009|0.069007|0.066169|0.079142|0.500000| |3.502614|3.765138|4.207556|4.346320|3.959206|3.573879|4.270355|3.524235|2.953075|2.565780|2.514848|2.785423|3.351963|5.112765|0.099982|4.674972|0.116916|7.115226|12.070049|12.826778|25.989613|9.521371|51.281966|8.233642|4.286664|3.753445|2.967212|2.672001|2.847078|3.526212|2.431691|4.816778|5.147904|5.579211|0.086164|0.095732|0.114516|0.102438|0.088495|0.079758|0.063829|0.062128|0.072551|0.204583|0.500000| 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