Version2.4 2021-05-29T06:52:29Z 10.1021/jm300687e Gaussian16 RevisionB.01 CFLINN 03-Dec-2020 #N HF/6-31G(d) OPT=(MaxStep=1) FREQ IOp(6/10=2,6/11=2,6/12=2) DUDE c1ccc(cc1)CC2CCN(CC2)c3ccc(cc3C(=O)[O-])NS(=O)(=O)c4ccc(cc4)F C33253337 RHF 6-31G(d) (6D,7F) c1ccc(cc1)CC2CCN(CC2)c3ccc(cc3C(=O)[O-])NS(=O)(=O)c4ccc(cc4)F C01[X(C25H24F1N2O4S1)] 165 C1 547 Fc1ccc(cc1)S(=O)(=O)Nc1ccc(c(c1)C(=O)[O-])N1CCC(CC1)Cc1ccccc1 Fc1ccc(cc1)S(=O)(=O)Nc1ccc(c(c1)C(=O)[O-])N1CCC(CC1)Cc1ccccc1 [O-]C(=O)c1cc(N[S](=O)(=O)c2ccc(F)cc2)ccc1N3CCC(CC3)Cc4ccccc4 InChIKey=YYKBJSAXQPHUQU-UHFFFAOYSA-M InChI=1S/C25H25FN2O4S/c26-20-6-9-22(10-7-20)33(31,32)27-21-8-11-24(23(17-21)25(29)30)28-14-12-19(13-15-28)16-18-4-2-1-3-5-18/h1-11,17,19,27H,12-16H2,(H,29,30)/p-1 InChI=1/C25H25FN2O4S/c26-20-6-9-22(10-7-20)33(31,32)27-21-8-11-24(23(17-21)25(29)30)28-14-12-19(13-15-28)16-18-4-2-1-3-5-18/h1-11,17,19,27H,12-16H2,(H,29,30)/p-1/fC25H24FN2O4S/q-1 c1ccc(cc1)CC2CCN(CC2)c3ccc(cc3C(=O)[O-])NS(=O)(=O)c4ccc(cc4)F C01[X(C25H24F1N2O4S1)] 165 C01 547 Fc1ccc(cc1)S(=O)(=O)Nc1ccc(c(c1)C(=O)[O-])N1CCC(CC1)Cc1ccccc1 F[C]1[CH][CH][C]([CH][CH]1)S(=O)(=O)N[C]1[CH][CH][C]([C]([CH]1)[C]([O])[O])[N@@]1CC[C@H](CC1)C[C]1[CH][CH][CH][CH][CH]1 [O][C]([O])[C]1[CH][C]([CH][CH][C]1N2CCC(CC2)C[C]3[CH][CH][CH][CH][CH]3)N[S](=O)(=O)[C]4[CH][CH][C](F)[CH][CH]4 InChIKey=JTGZGIWNWCRSJQ-UHFFFAOYSA-N InChI=1S/C25H24FN2O4S/c26-20-6-9-22(10-7-20)33(31,32)27-21-8-11-24(23(17-21)25(29)30)28-14-12-19(13-15-28)16-18-4-2-1-3-5-18/h1-11,17,19,27H,12-16H2 InChI=1/C25H24FN2O4S/c26-20-6-9-22(10-7-20)33(31,32)27-21-8-11-24(23(17-21)25(29)30)28-14-12-19(13-15-28)16-18-4-2-1-3-5-18/h1-11,17,19,27H,12-16H2 3414.4239722200 -1865.9511568 1-A 24633.2696 123 424 547 |A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A| -92.12180 -26.24667 -20.46759 -20.46581 -20.31397 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1407.20 1463.02 1480.66 1494.34 1507.77 1515.78 1543.68 1545.49 1562.23 1567.04 1570.71 1577.28 1592.07 1604.97 1605.51 1627.91 1634.19 1672.17 1702.72 1711.33 1712.29 1721.15 1730.33 1752.30 1765.98 1794.09 1818.05 1838.45 1846.77 1854.94 1869.29 1870.35 1872.14 1898.86 1901.81 1923.52 1941.17 1975.08 1999.49 2002.78 2035.24 2043.22 2058.92 2068.01 2080.42 2112.94 2137.56 2145.76 2166.14 2172.75 2192.82 2196.67 2207.32 2230.14 2246.21 2279.87 2302.90 2329.41 2336.71 2348.11 2359.79 2368.84 2383.87 2392.62 2403.26 2421.65 2541.02 2565.46 2574.10 2585.83 2600.24 2604.91 2748.45 4401.68 4426.32 4534.66 4568.79 4590.65 4620.25 4644.23 4657.56 4679.74 4696.52 4803.79 4817.87 4833.20 4845.62 4847.22 4849.94 4862.77 4878.10 4889.20 4891.00 4904.90 4921.55 4929.80 5485.07 0.484952 0.511728 0.512672 0.421763 -1865.466204 -1865.439429 -1865.438484 -1865.529394 3.049136D-04 MUNgauss RevisionA2.1 retrievium 29-May-2021 DUDE c1ccc(cc1)CC2CCN(CC2)c3ccc(cc3C(=O)[O-])NS(=O)(=O)c4ccc(cc4)F C33253337 RHF 6-31G(d) (6D,10F) C1 467.144083 |X|Y|Z| 144.859322 49.405960 34.757224 62.891259 27 6 7 16 24 2 1 |36.858105| |13.760716|36.858105| |7.927336|13.739581|36.858105| |6.798435|7.879600|13.701966|36.858105| |7.933225|6.903576|7.987219|13.680545|36.858105| |13.742814|7.967480|6.896815|7.874634|13.761253|36.858105| |4.412642|4.995543|7.513247|12.573655|7.543095|5.005231|36.858105| |3.696355|4.044276|5.431255|7.397720|5.738308|4.167397|12.364764|36.858105| |2.884466|3.105101|3.924660|4.883683|4.131055|3.205234|7.545741|12.421530|36.858105| |2.495537|2.647599|3.183291|3.731353|3.332990|2.732534|4.895087|7.516245|12.468558|36.858105| |2.477109|2.686001|3.214056|3.567710|3.113172|2.626483|4.433291|6.573497|7.849026|13.194491|53.358707| |2.881517|3.154056|3.790924|4.152973|3.580385|3.029658|4.869720|7.525735|6.595874|7.908477|17.826182|36.858105| |3.570863|4.083510|5.362997|6.021529|4.659653|3.745771|7.432474|12.426778|7.606085|6.580590|10.629825|12.502482|36.858105| |2.119466|2.274168|2.626334|2.829629|2.544108|2.220279|3.333377|4.419868|5.112524|7.776902|18.263556|7.828505|5.122488|36.858105| |1.945489|2.041369|2.308917|2.512670|2.337342|2.061208|2.898692|3.744490|4.330028|6.570009|10.624041|5.665779|4.027950|13.653213|36.858105| |1.716942|1.794828|1.994266|2.131694|2.002478|1.800997|2.401092|2.950012|3.318752|4.489074|6.969460|4.154731|3.171341|7.837631|13.775447|36.858105| |1.635996|1.727981|1.913558|2.005156|1.863450|1.690880|2.241213|2.686722|2.973461|3.798144|6.164323|3.783529|2.965090|6.834726|8.009393|13.784594|36.858105| |1.732985|1.859745|2.080083|2.153010|1.960960|1.773106|2.422925|2.904069|3.195003|3.999563|7.003796|4.259572|3.325384|7.960660|6.966851|7.959041|13.762808|36.858105| |1.970194|2.140150|2.445947|2.546564|2.271110|2.020012|2.932180|3.641147|4.040897|5.211101|10.575153|5.915407|4.350801|13.575949|7.893747|6.770383|7.842928|13.711889|36.858105| |2.046009|2.277321|2.624278|2.647707|2.300057|2.055404|3.032292|3.608893|3.850750|4.411813|8.529347|5.443481|4.500759|7.224908|4.900008|4.365806|5.004410|7.624713|12.251840|36.858105| |1.847839|2.050312|2.334905|2.338967|2.049044|1.848340|2.658566|3.035090|3.285851|3.650645|6.353343|4.059596|3.579799|5.340447|4.068846|3.866634|4.619370|6.875957|8.160787|15.496187|73.516695| |2.309797|2.621538|3.057110|3.020548|2.567254|2.292258|3.416313|4.074130|4.059483|4.412815|8.694629|6.479025|5.564644|6.255108|4.340138|3.746760|4.042742|5.455032|8.020334|15.491033|15.201138|73.516695| |1.461969|1.535292|1.676870|1.742941|1.636381|1.504082|1.917128|2.234312|2.435451|2.969202|4.594384|2.961089|2.430187|4.509450|5.152354|7.810741|13.253608|7.780274|5.096979|3.857582|6.741801|5.737014|53.358707| |1.335754|1.397291|1.522823|1.587447|1.497528|1.377745|1.750821|2.002460|2.215006|2.641403|3.892577|2.487583|2.117906|3.601574|4.081964|5.586841|7.077913|5.262534|3.919485|3.175650|5.782643|4.777296|15.828177|388.023441| |1.233253|1.286372|1.387782|1.435198|1.361410|1.265331|1.561081|1.760477|1.910134|2.221843|3.264161|2.155389|1.865389|2.912070|3.214716|4.138268|5.008596|4.082312|3.172898|2.705001|4.962688|4.173714|10.612664|94.428116|73.516695| |1.345915|1.397950|1.526589|1.611390|1.531614|1.401947|1.788385|2.055065|2.309401|2.790182|3.957297|2.491098|2.124547|3.609513|4.339267|5.946566|6.190304|4.527996|3.655481|2.921910|5.193439|4.478317|10.437001|94.755037|13.597930|73.516695| |1.330785|1.404807|1.541136|1.598264|1.490283|1.366007|1.779397|2.008930|2.250825|2.626818|3.872487|2.435640|2.121340|3.502885|3.673555|4.504165|5.738025|5.216422|3.995362|3.419768|6.633259|4.999366|9.403812|76.505154|13.091502|13.098581|36.858105| |1.248813|1.320909|1.439316|1.476949|1.376966|1.272221|1.627225|1.807294|1.990964|2.260242|3.339522|2.159505|1.917289|2.920795|2.969374|3.488873|4.348312|4.241696|3.373495|3.080057|6.150027|4.580825|7.114112|49.567075|11.705389|8.968965|13.737833|36.858105| |1.229716|1.306760|1.426242|1.456731|1.351041|1.248165|1.608208|1.762210|1.944422|2.160415|3.171128|2.054692|1.861958|2.694074|2.657158|2.976755|3.577085|3.698170|3.116144|2.992608|6.179864|4.471734|5.366447|33.669844|7.928784|6.883887|7.949070|13.772145|36.858105| |1.287821|1.373501|1.512012|1.551092|1.429401|1.310679|1.734083|1.896004|2.128675|2.352279|3.418159|2.171680|1.985388|2.869473|2.781705|3.023167|3.539967|3.756496|3.299083|3.207700|6.736823|4.744819|4.959137|30.096772|6.625970|6.612304|6.976690|8.026353|13.821139|36.858105| |1.377912|1.468283|1.631055|1.692895|1.556778|1.413424|1.921206|2.131171|2.453370|2.769271|3.988003|2.449110|2.212540|3.403665|3.321082|3.594800|4.150647|4.358466|3.858330|3.589000|7.371851|5.207308|5.532503|33.632259|6.803424|7.774792|7.947812|6.844580|7.874465|13.814561|36.858105| |1.403661|1.486997|1.648915|1.722933|1.595192|1.447299|1.951422|2.209162|2.544740|2.983706|4.330048|2.627947|2.303543|3.888993|3.991562|4.616185|5.505661|5.318519|4.369134|3.733407|7.302503|5.371059|7.500267|49.405023|8.774476|11.262345|13.710102|7.896092|6.843724|8.027866|13.790328|36.858105| |1.252680|1.339775|1.472905|1.502616|1.381458|1.269816|1.675813|1.801027|2.011084|2.165219|3.116072|2.006154|1.875261|2.531714|2.417449|2.551078|2.900739|3.122969|2.871968|2.910077|6.142957|4.410708|3.984011|23.242570|5.292752|5.282222|4.694617|5.321184|8.189333|14.351803|8.178372|5.320043|97.533100| |17.705124|8.901599|5.636734|4.912231|5.639837|8.896052|3.532293|3.074786|2.486541|2.202502|2.992583|2.532626|3.022847|1.918766|1.778020|1.588180|1.519582|1.602369|1.799503|1.865609|3.019633|3.716616|1.865071|8.925436|2.073614|2.244066|1.247439|1.176163|1.157997|1.207044|1.284132|1.307931|2.645455|0.500000| |8.913315|17.704068|8.925487|5.625121|4.966855|5.654306|4.080184|3.443688|2.747956|2.395525|3.366442|2.881761|3.614244|2.134458|1.913354|1.702132|1.657319|1.792189|2.046390|2.207444|3.565414|4.529227|2.018152|9.599443|2.221765|2.384670|1.361565|1.289309|1.279420|1.340461|1.422052|1.434331|2.952923|0.214445|0.500000| |5.646761|8.930261|17.707632|8.922509|5.664737|4.963633|6.970987|5.256613|3.956302|3.218263|4.547703|3.901118|5.590339|2.732077|2.353529|2.037537|1.981104|2.188571|2.596641|2.874317|4.554541|6.063139|2.356773|11.165294|2.540146|2.777230|1.605471|1.504575|1.499476|1.595626|1.717346|1.723085|3.511057|0.124133|0.216086|0.500000| |5.647418|4.965675|5.664318|8.913469|17.689198|8.937289|7.018021|5.781323|4.360098|3.510552|4.281696|3.516408|4.375918|2.572540|2.406973|2.052379|1.884561|1.958930|2.257879|2.239626|3.554385|4.364468|2.251112|10.818293|2.450441|2.793707|1.507085|1.384504|1.354261|1.434944|1.572032|1.618258|3.110693|0.124148|0.107722|0.124326|0.500000| |8.906874|5.654642|4.962928|5.620528|8.925785|17.698744|4.088666|3.579670|2.873317|2.509446|3.254452|2.716153|3.214412|2.055946|1.942113|1.711053|1.599710|1.659469|1.867845|1.877794|3.020077|3.674528|1.950802|9.377058|2.161173|2.395378|1.300030|1.211332|1.185570|1.240833|1.336161|1.372174|2.702400|0.214359|0.124138|0.107680|0.216082|0.500000| |3.991416|4.255652|5.750655|8.954709|7.067655|4.716602|17.507354|8.852517|7.164037|4.622592|5.359613|4.078001|5.470364|3.054143|2.737096|2.287274|2.118595|2.254520|2.675638|2.713765|4.314003|5.262490|2.488072|12.039303|2.684437|3.106617|1.721908|1.572532|1.556922|1.684661|1.871814|1.896886|3.674004|0.090802|0.098101|0.146257|0.208369|0.111657|0.500000| |3.973577|4.746398|7.214581|8.913989|5.632554|4.199341|17.536553|8.857654|6.820577|4.560562|5.879608|4.587398|6.886920|3.296271|2.804999|2.350232|2.236664|2.461432|2.994717|3.217364|5.071416|6.492771|2.608631|12.491513|2.784868|3.162395|1.813571|1.668333|1.665051|1.808238|1.997295|2.000401|3.964418|0.090448|0.112851|0.218782|0.142429|0.096668|0.303827|0.500000| |3.801610|3.926808|4.945794|6.917296|6.292599|4.509620|8.885238|17.456056|8.919485|6.821921|7.829410|6.806043|8.898320|4.114241|3.690604|2.915463|2.599835|2.733432|3.332402|3.186629|4.805141|6.280137|2.966515|13.880048|3.065073|3.594043|1.922103|1.726120|1.668574|1.778296|1.992987|2.090467|3.783233|0.088180|0.091819|0.125283|0.190207|0.110115|0.210983|0.174318|0.500000| |2.788906|2.922660|3.609538|4.599832|4.117794|3.174914|6.867046|8.797515|17.482844|8.848690|7.700838|4.926325|5.514890|4.178797|3.803383|3.012350|2.677951|2.800750|3.383969|3.197187|5.017118|5.871054|3.052497|14.804799|3.209851|3.915660|2.109790|1.870365|1.830376|2.004986|2.306989|2.385189|4.285279|0.067118|0.071517|0.098427|0.126932|0.080500|0.214995|0.166104|0.216669|0.500000| |2.736351|3.019257|3.848176|4.542775|3.712864|2.952977|6.988315|8.839958|17.529519|8.923312|9.656584|5.767765|6.802555|4.900040|4.000056|3.164820|2.935796|3.243639|4.135989|4.163955|6.433548|7.744691|3.288835|15.769084|3.398308|4.061871|2.313666|2.060043|2.041494|2.267511|2.618289|2.653243|4.869978|0.065891|0.075528|0.112686|0.105229|0.073149|0.181845|0.207215|0.174331|0.301387|0.500000| |2.498440|2.583582|3.036537|3.609714|3.382780|2.787916|4.497684|6.758516|8.866140|17.358569|12.205010|7.042336|5.755731|6.538064|6.498678|4.466013|3.617468|3.627201|4.457460|3.713620|5.552576|6.656764|3.918445|18.199004|3.860325|4.884955|2.467682|2.125340|2.009296|2.154575|2.508850|2.741856|4.451561|0.061541|0.064534|0.082937|0.101658|0.072286|0.120828|0.111255|0.200963|0.216699|0.174399|0.500000| |2.211836|2.338228|2.765671|3.176597|2.874951|2.403718|4.080572|5.491902|8.857006|17.574520|12.532180|5.706269|4.916039|7.366015|6.739644|4.753865|3.997110|4.128649|5.170645|4.273007|6.561366|7.162932|4.254352|20.316973|4.193982|5.475789|2.886382|2.439688|2.334920|2.583705|3.126771|3.385580|5.312562|0.054865|0.059483|0.078288|0.084318|0.062011|0.111349|0.109490|0.140027|0.212715|0.217655|0.301633|0.500000| |2.894611|3.060107|3.561147|3.984904|3.636458|3.107841|4.455755|6.732551|5.770002|7.110563|12.308851|17.337054|8.810980|6.650065|5.653023|4.158098|3.629369|3.852250|4.934039|4.318449|6.029321|8.644684|3.929383|17.234932|3.759821|4.375425|2.309612|2.044103|1.925200|2.012938|2.260978|2.456801|4.171386|0.071136|0.077012|0.097789|0.101375|0.078752|0.107081|0.111346|0.199291|0.129232|0.132906|0.210961|0.144790|0.500000| |2.715924|3.008432|3.523209|3.648516|3.157470|2.770686|4.067573|5.518853|4.952951|5.736294|12.582647|17.719949|8.928594|7.485806|5.298894|4.136896|3.973065|4.678016|6.600580|6.443069|8.098387|15.025544|4.235043|18.145450|3.963077|4.427213|2.499661|2.239309|2.125446|2.222003|2.471456|2.651050|4.606984|0.067319|0.078395|0.103083|0.084521|0.069243|0.095449|0.110763|0.139890|0.108597|0.129838|0.143920|0.128471|0.298769|0.500000| |3.343134|3.969156|5.290335|5.466031|4.099184|3.384547|6.853852|8.803187|6.783594|5.750033|9.641574|9.011667|17.555440|4.922888|3.751809|3.034053|2.932893|3.397338|4.507252|5.115247|7.222557|11.900659|3.286806|15.055192|3.317820|3.729398|2.168282|1.976147|1.943011|2.088858|2.318162|2.371250|4.477037|0.079376|0.100669|0.168760|0.105299|0.080631|0.141659|0.208333|0.173758|0.138651|0.198251|0.132581|0.128550|0.174592|0.222457|0.500000| |4.180071|4.859323|6.289177|6.619909|5.155832|4.275082|6.707604|8.799951|5.517605|4.927597|7.682849|8.879869|17.530173|4.195780|3.469759|2.832519|2.670851|2.957793|3.708529|3.870675|5.609132|8.574567|3.046186|13.866481|3.099380|3.460164|1.936002|1.769690|1.717103|1.810663|1.988295|2.068383|3.864202|0.097044|0.118014|0.174950|0.127682|0.099765|0.137749|0.167844|0.216191|0.123377|0.138995|0.129255|0.108167|0.215155|0.213231|0.301468|0.500000| |2.004389|2.074520|2.343341|2.604299|2.466472|2.158962|3.010342|3.946218|4.603709|7.246036|9.773599|5.489815|4.022172|8.908678|17.722480|8.990194|5.690851|5.000982|5.625746|3.995604|6.021055|6.616787|5.692426|25.060703|5.083685|6.925910|3.164175|2.606159|2.359373|2.474884|2.927133|3.437152|4.919846|0.050770|0.053468|0.065280|0.071821|0.056904|0.080154|0.078983|0.112338|0.115782|0.112389|0.231046|0.202060|0.164378|0.133772|0.100492|0.096809|0.500000| |1.618199|1.673451|1.840656|1.973395|1.882599|1.705020|2.198556|2.657787|2.965585|3.889246|5.655564|3.521609|2.787018|5.595168|8.880542|17.744950|8.928445|5.656221|4.900642|3.504197|5.673506|5.513708|9.769557|40.438340|7.634148|11.970523|4.235632|3.305918|2.793128|2.798176|3.280725|4.209212|5.337940|0.041810|0.044073|0.051784|0.053985|0.045416|0.058895|0.059329|0.074303|0.076862|0.077860|0.111869|0.114850|0.100947|0.096168|0.073498|0.070340|0.215734|0.500000| |1.640999|1.768700|1.964238|2.003649|1.821840|1.662505|2.230166|2.599833|2.817352|3.357559|5.692992|3.630470|2.976557|5.678370|5.003333|5.652889|8.902862|17.732736|9.031091|7.325175|13.814878|9.225589|9.690034|36.526912|7.447241|7.375671|5.521657|4.791186|4.205217|4.153850|4.576798|5.347275|7.705249|0.042372|0.047804|0.057830|0.050212|0.043225|0.057683|0.063670|0.067653|0.069293|0.080830|0.084724|0.096093|0.091024|0.112297|0.086254|0.074787|0.108388|0.124204|0.500000| |1.429980|1.506307|1.636133|1.682540|1.576864|1.459671|1.832636|2.114190|2.264776|2.698979|4.227323|2.806210|2.328885|4.028595|4.329887|5.877460|9.200958|7.172104|4.747982|3.812081|6.781799|5.709115|25.931908|61.707611|13.544271|10.171409|6.184414|5.273021|3.982464|3.551787|3.771529|4.803243|6.493208|0.037366|0.040667|0.047103|0.043969|0.038602|0.048295|0.051130|0.057124|0.057771|0.062798|0.072425|0.077612|0.075602|0.083629|0.064795|0.060240|0.099540|0.149588|0.208102|0.500000| |1.198145|1.263293|1.366878|1.397737|1.309930|1.217919|1.524941|1.689186|1.836117|2.075992|3.070947|2.024293|1.797759|2.669512|2.739361|3.243315|4.013162|3.834189|3.054765|2.799750|5.489211|4.247072|6.930231|47.464201|13.708666|8.350816|8.933383|17.763001|8.913229|5.681532|4.940905|5.636001|9.615233|0.031472|0.034341|0.039571|0.036543|0.032306|0.040894|0.043252|0.045119|0.048015|0.052357|0.054850|0.061436|0.053728|0.058630|0.051195|0.046546|0.067375|0.087003|0.120257|0.150670|0.500000| |1.169139|1.242276|1.348102|1.368491|1.271484|1.181515|1.498483|1.625899|1.773419|1.943298|2.847212|1.877036|1.719435|2.377371|2.333065|2.581163|3.051555|3.172564|2.731625|2.687838|5.536866|4.098965|4.577529|27.738180|6.923904|5.778071|5.634352|8.856834|17.747428|8.958832|5.634468|4.939601|16.763728|0.030695|0.033937|0.039393|0.035299|0.031211|0.040295|0.043163|0.042829|0.046508|0.051709|0.050440|0.057708|0.048986|0.054124|0.049925|0.044416|0.058182|0.067815|0.100411|0.096592|0.212407|0.500000| |1.422642|1.519605|1.699893|1.772408|1.621805|1.463090|2.035239|2.242916|2.628335|2.921926|4.121329|2.500053|2.295874|3.407275|3.263778|3.379726|3.732071|3.983470|3.761353|3.577917|7.294371|5.252330|4.767040|27.709911|5.692404|6.748317|5.635566|4.941048|5.634867|8.955211|17.758929|8.871653|16.724587|0.036694|0.040764|0.049838|0.045571|0.038326|0.055409|0.059189|0.057748|0.068992|0.079235|0.072475|0.093163|0.063622|0.069128|0.067279|0.056831|0.081169|0.085460|0.112771|0.090044|0.107382|0.124544|0.500000| 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