Version2.0 2020-01-23T07:50:57Z 10.1021/jm300687e Gaussian16 RevisionB.01 PWARBURT 18-Nov-2019 #N HF/6-31G(d) OPT=(MaxStep=1) FREQ IOp(6/10=2,6/11=2,6/12=2) DUDE c1ccc(cc1)CN2[C@H](NN=C2c3ccco3)S[C@H](c4ccccc4)C(=O)C5=c6ccccc6=[NH+]C5 C39945157 RHF 6-31G(d) (6D,7F) c1ccc(cc1)CN2[C@H](NN=C2c3ccco3)S[C@H](c4ccccc4)C(=O)C5=c6ccccc6=[NH+]C5 C01[X(C29H25N4O2S1)] 177 C1 594 O=C(C1=c2ccccc2=[NH+]C1)[C@@H](c1ccccc1)S[C@H]1NN=C(N1Cc1ccccc1)c1ccco1 O=C(C1=c2ccccc2=[NH+]C1)[C@@H](c1ccccc1)S[C@H]1NN=C(N1Cc1ccccc1)c1ccco1 O=C([C@H](S[C@H]1NN=C(N1Cc2ccccc2)c3occc3)c4ccccc4)C5=C6C=CC=CC6=[NH+]C5 InChIKey=PAUZCMOVABCXHN-PXJZQJOASA-O InChI=1S/C29H24N4O2S/c34-26(23-18-30-24-15-8-7-14-22(23)24)27(21-12-5-2-6-13-21)36-29-32-31-28(25-16-9-17-35-25)33(29)19-20-10-3-1-4-11-20/h1-17,27,29,32H,18-19H2/p+1/t27-,29+/m1/s1 InChI=1/C29H24N4O2S/c34-26(23-18-30-24-15-8-7-14-22(23)24)27(21-12-5-2-6-13-21)36-29-32-31-28(25-16-9-17-35-25)33(29)19-20-10-3-1-4-11-20/h1-17,27,29,32H,18-19H2/p+1/t27-,29+/m1/s1/fC29H25N4O2S/h30H/q+1 c1ccc(cc1)CN2[C@H](NN=C2c3ccco3)S[C@H](c4ccccc4)C(=O)C5=c6ccccc6=[NH+]C5 C01[X(C29H25N4O2S1)] 177 C01 594 O=C(C1=c2ccccc2=[NH+]C1)[C@@H](c1ccccc1)S[C@H]1NN=C(N1Cc1ccccc1)c1ccco1 O=C([C@@H](c1ccccc1)S[C@H]1NN=C(N1Cc1ccccc1)c1ccco1)C1=C2C=CC=C[C@@H]2NC1 O=C([C@H](S[C@H]1NN=C(N1Cc2ccccc2)c3occc3)c4ccccc4)C5=C6C=CC=C[C@@H]6NC5 InChIKey=ZHNSPNYWFBZJLF-HWUUJZMBSA-N InChI=1S/C29H26N4O2S/c34-26(23-18-30-24-15-8-7-14-22(23)24)27(21-12-5-2-6-13-21)36-29-32-31-28(25-16-9-17-35-25)33(29)19-20-10-3-1-4-11-20/h1-17,24,27,29-30,32H,18-19H2/t24-,27+,29-/m0/s1 InChI=1/C29H26N4O2S/c34-26(23-18-30-24-15-8-7-14-22(23)24)27(21-12-5-2-6-13-21)36-29-32-31-28(25-16-9-17-35-25)33(29)19-20-10-3-1-4-11-20/h1-17,24,27,29-30,32H,18-19H2/t24-,27+,29-/m0/s1 3937.1427782622 -1877.4881232 1-A 18699.4874 129 465 594 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|36.858105| |13.724335|36.858105| |7.933118|13.775769|36.858105| |6.830489|7.901201|13.679811|36.858105| |7.938331|6.889207|7.960632|13.725802|36.858105| |13.775586|7.949652|6.882322|7.894966|13.724345|36.858105| |4.423230|5.004927|7.520899|12.550491|7.556589|5.008846|36.858105| |3.738878|4.262370|5.961945|7.595415|5.436417|4.052583|13.001389|53.358707| |3.653074|3.946730|5.006425|6.204120|5.216661|4.042799|7.575318|17.913944|36.858105| |4.371201|4.613090|5.697382|7.115199|6.314722|4.916816|7.053371|12.355944|17.565066|0.500000| |3.087519|3.409233|4.145204|4.527535|3.843709|3.232483|5.240289|11.516334|13.073533|0.247985|53.358707| |3.006214|3.479277|4.358669|4.461747|3.574123|3.036530|5.302674|11.652941|8.164429|0.176141|18.335398|53.358707| |3.317918|3.935052|5.327681|5.616926|4.154294|3.381131|7.523587|18.911542|8.437587|0.180888|12.046954|20.444597|36.858105| |3.059053|3.714724|4.945934|4.810805|3.590712|3.024115|6.114938|10.332550|5.178807|0.124232|7.279993|10.912042|13.005841|36.858105| |2.812592|3.450337|4.306444|3.898757|3.041419|2.688018|4.426186|6.927179|3.995841|0.101031|5.888161|8.504095|7.461930|14.181704|36.858105| |2.542356|3.060113|3.706661|3.406317|2.731716|2.438015|3.859821|5.550794|3.236484|0.082848|4.566016|5.954467|5.195632|8.590930|13.270886|36.858105| |2.585499|3.058965|3.797384|3.676180|2.927698|2.544924|4.427733|6.098958|3.394161|0.085507|4.578988|5.767483|5.370248|8.800331|8.606287|14.208622|36.858105| |2.874841|3.400037|4.455770|4.555099|3.477932|2.898830|6.120476|8.759479|4.389618|0.106436|5.743299|7.389251|7.866776|14.126648|8.613327|8.618807|14.184910|73.516695| |3.034040|3.074415|3.637440|4.575781|4.440177|3.512121|5.534764|9.390269|10.408278|0.225439|9.465425|6.766230|5.048479|3.729262|3.014381|2.609059|2.800762|6.198419|388.023441| |2.439131|2.538742|2.986155|3.505003|3.252378|2.694451|4.373620|7.781883|6.895063|0.143828|9.000692|6.990600|4.931328|3.774516|3.071760|2.678273|2.879721|6.331205|74.409809|36.858105| |2.477595|2.638670|3.180551|3.709504|3.294476|2.700592|4.900658|9.244685|7.057573|0.141025|9.495398|8.235718|6.070170|4.587630|3.586220|3.106024|3.399053|7.742999|57.288675|17.646232|0.500000| |2.139699|2.188620|2.516719|2.937743|2.819223|2.377569|3.579435|5.690436|4.604272|0.106219|5.887182|5.022360|3.672472|3.061903|2.567680|2.332636|2.539422|5.399672|48.852031|12.498220|0.249238|36.858105| |2.015903|2.076275|2.396595|2.779292|2.636311|2.225170|3.451225|5.264602|3.889501|0.091004|4.971026|4.564909|3.469475|3.046207|2.555494|2.389054|2.662642|5.618841|36.179018|7.570272|0.207504|13.708104|36.858105| |1.801917|1.835675|2.077489|2.377799|2.303319|1.985053|2.846559|4.157011|3.067677|0.074806|3.941621|3.670720|2.781911|2.525210|2.179617|2.079993|2.306639|4.706109|27.657211|5.014892|0.134538|7.905118|13.752962|36.858105| |1.708309|1.717968|1.912189|2.176987|2.155181|1.886994|2.521995|3.661027|2.797765|0.069859|3.607951|3.291382|2.448613|2.207626|1.935568|1.837517|2.002857|4.036807|25.749996|4.422188|0.111571|6.843120|7.941930|13.756790|36.858105| |1.781619|1.779765|1.971290|2.250629|2.251979|1.977410|2.570815|3.795012|3.030719|0.076061|3.914269|3.449329|2.516037|2.212851|1.940108|1.810905|1.948371|3.952393|29.329761|4.995245|0.116866|7.917613|6.889870|7.948929|13.745310|36.858105| |1.986959|1.995735|2.236650|2.580632|2.558873|2.213572|2.988231|4.578267|3.812322|0.093238|4.913935|4.156921|2.988896|2.537625|2.190346|2.003412|2.148280|4.446344|40.135117|7.488800|0.155608|13.691829|7.942230|6.870719|7.926126|13.758546|36.858105| |2.243112|2.341086|2.682957|3.001915|2.800886|2.416648|3.506538|6.196712|5.709372|0.127581|9.191460|6.902197|4.358017|3.397885|2.904489|2.498372|2.586983|5.481561|48.961750|12.499780|0.247118|7.641062|5.289909|4.010880|3.776120|4.403483|6.300431|36.858105| |2.191560|2.249277|2.515635|2.792054|2.681782|2.364318|3.117229|5.270703|5.008266|0.121009|7.796757|5.787174|3.666716|2.919348|2.560333|2.216808|2.269628|4.711822|43.863294|7.940038|0.164188|6.058367|4.301264|3.508029|3.496363|4.262229|5.989885|16.046793|73.516695| |2.036337|2.163740|2.472923|2.670869|2.439957|2.140226|3.109365|5.455943|4.539392|0.103886|7.935148|6.975364|4.227784|3.466598|3.055182|2.625905|2.669722|5.532398|33.209126|7.299318|0.198417|5.562166|4.586816|3.616229|3.325821|3.644014|4.641972|12.567456|14.615239|36.858105| |1.824358|1.928098|2.154804|2.280446|2.112836|1.896818|2.567580|4.311847|3.543707|0.085603|6.031891|5.506858|3.371069|2.896416|2.664480|2.326191|2.322397|4.649967|25.714625|4.930166|0.131876|4.241915|3.646764|3.084931|2.941604|3.225808|3.885607|7.474957|11.841771|14.091443|36.858105| |1.709219|1.780594|1.950984|2.058423|1.949235|1.778408|2.256230|3.672942|3.072726|0.077107|5.015404|4.466845|2.796296|2.426352|2.262006|1.998465|1.989488|3.931677|22.926019|4.057273|0.103767|3.679730|3.130942|2.763706|2.753680|3.102679|3.652380|5.898981|11.341379|7.405649|13.154631|36.858105| |1.547746|1.613048|1.748495|1.819822|1.726740|1.595222|1.970870|3.142084|2.561054|0.065445|4.107232|3.807176|2.418201|2.161160|2.060146|1.843732|1.818708|3.523963|18.712042|3.176435|0.083629|2.964785|2.631574|2.391703|2.391594|2.631487|2.962131|4.187819|7.857148|5.138673|7.960083|14.215031|36.858105| |1.480075|1.557250|1.691698|1.742128|1.635332|1.512283|1.893988|3.009267|2.380346|0.060622|3.829213|3.714295|2.369027|2.171879|2.106353|1.899768|1.857483|3.547674|16.922395|2.874632|0.078543|2.685963|2.472601|2.255725|2.209560|2.356150|2.606892|3.608349|6.374125|4.650438|6.868363|7.840549|13.145116|36.858105| |1.539455|1.637246|1.799169|1.848775|1.710570|1.568885|2.038912|3.277288|2.539100|0.063635|4.146825|4.162415|2.639662|2.446584|2.380687|2.142821|2.088272|3.983093|17.690037|3.078317|0.086877|2.834161|2.659359|2.387828|2.277554|2.382755|2.652376|3.803804|6.346996|5.289017|7.617678|6.581247|7.704325|14.075039|36.858105| |1.710653|1.828170|2.042197|2.123131|1.943963|1.755750|2.390995|3.959124|3.085258|0.075167|5.196269|5.187661|3.215823|2.901390|2.748919|2.428116|2.390962|4.674104|21.447354|3.948776|0.113101|3.503347|3.235019|2.795519|2.612017|2.745169|3.157415|5.097899|7.967484|8.428417|13.117824|7.615352|6.825192|8.087632|13.441733|36.858105| |1.799574|1.947248|2.212107|2.299999|2.065827|1.844174|2.652226|4.459886|3.334511|0.079458|5.636781|5.999997|3.747370|3.442433|3.235326|2.848668|2.816365|5.539908|22.514165|4.230731|0.129821|3.677114|3.521511|2.968088|2.672601|2.736809|3.151689|5.050826|7.384861|8.305107|8.442629|5.288373|4.666937|5.271445|7.734939|14.558115|53.358707| |1.728534|1.881552|2.132695|2.190495|1.957965|1.757307|2.515695|4.144857|3.003802|0.072546|4.952129|5.502477|3.539189|3.417207|3.310337|2.974912|2.907019|5.561111|19.970000|3.597870|0.111922|3.202105|3.170393|2.729410|2.444485|2.457327|2.763913|4.050020|6.089326|5.841794|5.917078|4.231120|3.958410|4.654295|6.835071|9.302257|26.005086|0.500000| |2.030701|2.201305|2.557685|2.725611|2.418663|2.109423|3.259676|5.769904|4.331269|0.098001|7.496831|7.802321|4.820809|4.141900|3.639419|3.124765|3.180998|6.604871|29.233025|6.068327|0.200691|4.816997|4.488983|3.524363|3.084414|3.182825|3.838081|7.119140|9.165219|12.738570|8.198804|5.066084|4.103845|4.152982|5.193219|8.358369|17.907597|0.244255|36.858105| |17.723503|8.903442|5.644506|4.930372|5.643942|8.918650|3.539811|4.222998|3.081855|0.100509|3.663701|3.569421|2.827467|2.646065|2.490731|2.279112|2.293438|4.437984|18.765832|2.166762|0.060736|1.926446|1.818163|1.643955|1.571494|1.639755|1.811979|2.024030|3.551620|1.851878|1.681499|1.591470|1.453203|1.390771|1.438359|1.582229|2.248499|0.044206|1.839367|0.500000| |8.906253|17.719652|8.932551|5.631550|4.960620|5.651032|4.084078|4.981871|3.404083|0.107345|4.208056|4.400014|3.568869|3.496834|3.411721|3.051097|2.958550|5.643707|19.097677|2.293312|0.066398|1.990409|1.898139|1.689890|1.584688|1.636913|1.823456|2.155083|3.691084|2.029470|1.831907|1.696928|1.552385|1.509495|1.587661|1.756505|2.542600|0.050526|2.078216|0.214705|0.500000| |5.649172|8.950466|17.698952|8.884186|5.649095|4.955543|6.961607|8.269385|4.799591|0.141684|5.778963|6.585425|6.130023|6.218440|5.536469|4.605867|4.575799|9.469534|24.340165|2.958935|0.089681|2.479980|2.388041|2.061668|1.880158|1.923659|2.179709|2.687210|4.415844|2.545137|2.217809|1.982984|1.784720|1.746778|1.878331|2.136225|3.193659|0.063467|2.701787|0.124285|0.216372|0.500000| |5.650856|4.958858|5.650219|8.911645|17.696843|8.925276|7.017769|7.058082|5.150651|0.165603|5.063289|4.579702|3.862528|3.311260|2.782321|2.529665|2.751262|5.835653|35.153794|3.477794|0.095939|3.082062|2.870868|2.515066|2.363841|2.478346|2.815022|2.912549|4.968017|2.483678|2.139407|1.980740|1.744904|1.641498|1.710710|1.949224|2.808581|0.054017|2.432166|0.124232|0.107628|0.124014|0.500000| |8.918186|5.647875|4.957270|5.631249|8.915889|17.722551|4.090739|4.670953|3.518350|0.116521|3.902796|3.618545|2.897788|2.606008|2.340488|2.148588|2.243436|4.487929|23.134401|2.508421|0.068758|2.261792|2.113276|1.912381|1.841864|1.937987|2.147205|2.264193|3.992090|1.996478|1.785861|1.694477|1.525156|1.439319|1.481845|1.647189|2.333797|0.045332|1.946546|0.214769|0.124139|0.107575|0.215820|0.500000| |3.986984|4.189609|5.591275|8.897789|7.334141|4.785374|17.614142|12.595628|6.831996|0.175049|6.359046|6.056028|5.747856|4.787884|3.634164|3.288622|3.809597|8.960217|43.915307|4.661193|0.140986|3.969819|3.855935|3.175700|2.801350|2.844866|3.300556|3.557629|5.639257|3.065451|2.525614|2.237838|1.946777|1.855919|1.983939|2.323980|3.476689|0.066871|3.147989|0.090729|0.096297|0.140537|0.225688|0.113920|0.500000| |3.970705|4.631381|6.828308|8.853701|5.819800|4.271185|17.680529|12.566834|5.620876|0.143431|6.046610|6.626868|7.104147|6.999613|4.948165|4.533865|5.573146|14.426808|31.251706|3.838892|0.122966|3.258562|3.276352|2.742605|2.397094|2.390115|2.717515|3.139627|4.930247|2.898942|2.421792|2.116132|1.871421|1.824802|1.982539|2.310554|3.540443|0.069795|3.148342|0.090419|0.109343|0.196446|0.149811|0.098804|0.304792|0.500000| |3.103244|3.399926|3.961033|4.154898|3.645007|3.190960|4.421786|8.522271|9.234137|0.230986|25.924656|13.059583|6.589742|4.503966|3.902684|3.050444|2.983749|6.379442|41.070353|5.264408|0.145298|3.717945|3.142380|2.574965|2.412590|2.644208|3.269516|5.856072|9.836350|5.167131|4.247142|3.701331|3.062141|2.822330|2.991490|3.641699|5.152706|0.092996|4.676568|0.076157|0.086817|0.111380|0.096639|0.079203|0.110263|0.105401|0.500000| |2.760614|3.389398|4.067071|3.589669|2.867108|2.595313|3.871074|6.151938|3.818715|0.098718|5.894649|8.522945|6.476680|8.838463|17.810476|8.440657|5.854791|10.446621|20.370143|2.905469|0.091922|2.418079|2.363704|2.029882|1.828745|1.852772|2.095544|2.847018|4.534219|3.026901|2.695417|2.306784|2.116537|2.171696|2.447714|2.794823|4.401383|0.091841|3.535726|0.068738|0.095324|0.142875|0.072490|0.063061|0.089616|0.114184|0.113256|0.500000| |2.322885|2.767130|3.218759|2.927943|2.416566|2.205624|3.201862|4.533102|2.758455|0.071810|3.911443|4.922888|4.070394|5.850991|8.457498|17.810403|8.824570|10.446219|16.210168|2.340817|0.073988|2.073519|2.125307|1.881766|1.677908|1.651547|1.808450|2.218652|3.546795|2.346105|2.123597|1.847219|1.727056|1.793436|2.016166|2.239661|3.530403|0.076144|2.757328|0.058799|0.078259|0.108506|0.062310|0.054558|0.077581|0.101998|0.074208|0.192813|0.500000| |2.401629|2.778511|3.361891|3.320992|2.726959|2.385399|3.959807|5.224705|2.989580|0.076017|3.961917|4.756023|4.287530|6.045234|5.818776|8.611360|17.838284|16.519533|18.315207|2.652040|0.085907|2.410039|2.578356|2.275749|1.969210|1.890815|2.053216|2.365334|3.713233|2.426696|2.130176|1.842818|1.694088|1.730748|1.935273|2.192974|3.482862|0.073565|2.856281|0.059682|0.074574|0.108133|0.072204|0.059108|0.098693|0.138602|0.072295|0.123089|0.195115|0.500000| |2.084089|2.179562|2.557470|2.960112|2.730396|2.282317|3.809133|5.848503|4.052407|0.093159|5.192061|4.984355|3.909064|3.497972|2.875721|2.709217|3.088775|6.639199|34.633435|7.041977|0.231243|8.894257|17.695157|8.938672|5.652613|4.959273|5.641136|4.921369|6.950893|4.536314|3.555439|2.969272|2.526072|2.428654|2.670443|3.274659|5.068595|0.094804|4.857281|0.051900|0.055390|0.071795|0.081509|0.059454|0.116923|0.103207|0.089319|0.072457|0.066131|0.083222|0.500000| |1.714606|1.752903|1.980099|2.245720|2.164691|1.876325|2.682626|3.839486|2.752582|0.067752|3.550495|3.398031|2.607408|2.435675|2.120374|2.061679|2.306790|4.633840|23.596822|4.096781|0.115243|5.634728|8.926579|17.724046|8.911116|5.648322|4.951367|3.373876|5.280933|3.170094|2.756916|2.468645|2.182568|2.097949|2.237387|2.580924|3.776583|0.072469|3.214745|0.043578|0.045045|0.054910|0.065196|0.050187|0.082582|0.073434|0.064713|0.054516|0.052084|0.064221|0.216148|0.500000| |1.577208|1.580318|1.742048|1.964469|1.956591|1.734662|2.240574|3.200019|2.423390|0.061480|3.138736|2.901124|2.161763|1.981583|1.759896|1.687851|1.834565|3.640873|21.545796|3.539273|0.091305|4.937184|5.647276|8.915022|17.726556|8.910701|5.641583|3.130765|5.258748|2.836611|2.580414|2.456407|2.182854|2.033336|2.082302|2.336502|3.235469|0.061232|2.667696|0.040579|0.040697|0.047587|0.059386|0.047329|0.068691|0.059730|0.059005|0.046304|0.043171|0.050511|0.124298|0.214698|0.500000| |1.683485|1.668347|1.823392|2.063085|2.089825|1.864493|2.302305|3.362380|2.704673|0.069409|3.514153|3.098752|2.245532|1.988259|1.765907|1.651530|1.761548|3.532249|25.487245|4.076403|0.096530|5.641142|4.961460|5.650293|8.913034|17.726076|8.938875|3.805409|6.881274|3.202853|2.940691|2.935852|2.532909|2.246946|2.229784|2.511109|3.345731|0.061688|2.782202|0.043390|0.042791|0.049241|0.063724|0.051257|0.070189|0.059484|0.067277|0.047209|0.042148|0.047552|0.107644|0.124137|0.214792|0.500000| |2.025998|2.020484|2.240736|2.570542|2.579179|2.257088|2.897701|4.471293|3.897221|0.097445|5.077490|4.158102|2.924892|2.451509|2.134888|1.931989|2.043234|4.211630|41.469995|6.928024|0.140235|8.893807|5.644479|4.952115|5.645968|8.933162|17.733478|6.680091|12.998455|4.643697|3.989527|3.925180|3.130148|2.674998|2.662903|3.141829|4.152945|0.073877|3.659948|0.051516|0.051296|0.060256|0.078489|0.061142|0.087656|0.072223|0.096428|0.057457|0.048602|0.053858|0.123940|0.107519|0.124215|0.216118|0.500000| |1.758208|1.811478|1.975054|2.104081|2.020660|1.845614|2.288206|3.700190|3.181228|0.080742|5.064676|4.331287|2.740879|2.345289|2.165015|1.913112|1.917234|3.814216|24.651174|4.245570|0.103823|3.878671|3.182316|2.819123|2.877210|3.358683|4.030414|6.297545|14.002492|6.564046|8.731457|17.802074|8.999202|5.571917|4.805058|5.492722|5.843543|0.098192|4.426907|0.045502|0.047667|0.055088|0.057472|0.049153|0.063650|0.058875|0.105089|0.061111|0.049013|0.049466|0.082007|0.068971|0.070967|0.089602|0.126479|0.500000| |1.471374|1.521737|1.632783|1.696611|1.626903|1.516371|1.815347|2.849849|2.327898|0.060461|3.652057|3.367528|2.167938|1.947399|1.863830|1.679510|1.657235|3.193835|17.154601|2.816788|0.073504|2.674520|2.378884|2.200653|2.238410|2.477706|2.741307|3.599086|6.976020|4.102999|5.628788|9.062956|17.755183|8.771314|5.588274|4.932900|5.030132|0.090094|3.355673|0.038609|0.040758|0.046016|0.045733|0.040540|0.049999|0.047821|0.076489|0.053245|0.043938|0.043101|0.062990|0.055949|0.057409|0.067574|0.081460|0.214789|0.500000| |1.375748|1.443903|1.555597|1.592447|1.501804|1.400006|1.715341|2.684704|2.106197|0.054294|3.330045|3.257938|2.107371|1.959559|1.921396|1.751602|1.706623|3.222027|14.942751|2.474762|0.067775|2.343927|2.185617|2.026825|1.998003|2.115357|2.298069|3.004108|5.359121|3.684113|4.951180|5.648349|8.790607|17.722047|9.099143|5.706564|5.724349|0.108697|3.398312|0.036116|0.039076|0.044590|0.041806|0.037146|0.046702|0.046120|0.068585|0.055169|0.046372|0.044421|0.059713|0.052879|0.051723|0.056642|0.065442|0.123792|0.215820|0.500000| |1.467773|1.567285|1.718262|1.750967|1.614736|1.486843|1.926291|3.059060|2.320707|0.058506|3.738047|3.858639|2.486643|2.366666|2.344646|2.140149|2.070120|3.880471|15.976269|2.728352|0.078306|2.536099|2.437578|2.213105|2.096224|2.156420|2.362456|3.225212|5.350530|4.293658|5.476505|4.801583|5.516241|8.945280|17.754230|8.751575|9.250461|0.193277|4.541776|0.038196|0.042472|0.050144|0.044680|0.038981|0.051866|0.052624|0.074704|0.067066|0.056557|0.053498|0.068901|0.058514|0.053767|0.056149|0.065239|0.105046|0.123145|0.216625|0.500000| 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