Version2.4 2021-06-06T23:53:59Z 10.1021/jm300687e Gaussian16 RevisionB.01 CFLINN 04-Feb-2020 #N HF/6-31G(d) OPT=(MaxStep=1) FREQ IOp(6/10=2,6/11=2,6/12=2) DUDE c1ccc(cc1)c2cc(nc(n2)n3c(cc(n3)c4ccco4)NC(=O)c5cc(ccc5[N+](=O)[O-])Cl)[O-] C12009195 RHF 6-31G(d) (6D,7F) c1ccc(cc1)c2cc(nc(n2)n3c(cc(n3)c4ccco4)NC(=O)c5cc(ccc5[N+](=O)[O-])Cl)[O-] C01[X(C24H14Cl1N6O5)] 144 C1 572 [O-]c1nc(nc(c1)c1ccccc1)n1nc(cc1NC(=O)c1cc(Cl)ccc1[N+](=O)[O-])c1ccco1 [O-]c1nc(nc(c1)c1ccccc1)n1nc(cc1NC(=O)c1cc(Cl)ccc1[N+](=O)[O-])c1ccco1 [O-]c1cc(nc(n1)n2nc(cc2NC(=O)c3cc(Cl)ccc3[N+]([O-])=O)c4occc4)c5ccccc5 InChIKey=XHIRYVMHFSHFRL-UHFFFAOYSA-M InChI=1S/C24H15ClN6O5/c25-15-8-9-19(31(34)35)16(11-15)23(33)27-21-12-18(20-7-4-10-36-20)29-30(21)24-26-17(13-22(32)28-24)14-5-2-1-3-6-14/h1-13H,(H,27,33)(H,26,28,32)/p-1 InChI=1/C24H15ClN6O5/c25-15-8-9-19(31(34)35)16(11-15)23(33)27-21-12-18(20-7-4-10-36-20)29-30(21)24-26-17(13-22(32)28-24)14-5-2-1-3-6-14/h1-13H,(H,27,33)(H,26,28,32)/p-1/fC24H14ClN6O5/h27H/q-1 c1ccc(cc1)c2cc(nc(n2)n3c(cc(n3)c4ccco4)NC(=O)c5cc(ccc5[N+](=O)[O-])Cl)[O-] C01[X(C24H14Cl1N6O5)] 144 C01 572 [O-]c1nc(nc(c1)c1ccccc1)n1nc(cc1NC(=O)c1cc(Cl)ccc1[N+](=O)[O-])c1ccco1 Cl[C]1[CH][CH][C]([C]([CH]1)C(=O)NC1=[CH][C]([N][N]1[C]1[N][C](=O)[CH][C]([N]1)[C]1[CH][CH][CH][CH][CH]1)C1=[CH][CH]=CO1)[N]([O])[O] [O]N([O])[C]1[CH][CH][C](Cl)[CH][C]1C(=O)NC2=C[C]([N]N2[C]3[N][C]([CH]C(=O)[N]3)[C]4[CH][CH][CH][CH][CH]4)c5occc5 InChIKey=WRPKPGVKGYTVND-UHFFFAOYSA-N InChI=1S/C24H14ClN6O5/c25-15-8-9-19(31(34)35)16(11-15)23(33)27-21-12-18(20-7-4-10-36-20)29-30(21)24-26-17(13-22(32)28-24)14-5-2-1-3-6-14/h1-13H,(H,27,33) InChI=1/C24H14ClN6O5/c25-15-8-9-19(31(34)35)16(11-15)23(33)27-21-12-18(20-7-4-10-36-20)29-30(21)24-26-17(13-22(32)28-24)14-5-2-1-3-6-14/h1-13H,(H,27,33)/f/h27H 3711.9360674604 -2077.4054416 1-A 22690.0178 129 443 572 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353.1075 380.3931 402.6616 424.4767 454.3238 458.3644 470.0349 480.4070 506.3818 534.3746 561.5760 592.2207 613.1111 642.4135 647.5858 658.7246 679.3538 708.0118 712.4787 720.7399 730.9054 745.4275 753.3099 775.6651 779.8011 799.7538 805.8031 809.2093 845.7971 854.4732 858.9068 870.7574 878.1012 884.4772 898.4154 914.1980 921.4470 940.9726 944.6872 958.7707 959.0178 967.7572 972.8738 986.9764 994.3315 1022.9371 1028.1426 1047.5916 1052.1831 1070.9365 1089.8175 1092.6950 1100.6032 1102.4832 1115.4033 1122.3702 1132.6171 1168.4629 1182.4816 1185.2519 1195.4243 1206.1036 1210.8403 1215.4015 1246.6612 1265.9547 1282.5126 1289.8531 1297.8987 1299.9689 1309.5358 1329.8034 1333.4827 1364.1698 1371.5547 1398.3559 1415.7533 1437.1230 1454.1092 1471.6679 1520.4036 1542.6732 1546.8157 1561.2046 1599.0448 1615.4630 1642.6308 1655.4908 1671.0350 1680.1973 1691.9405 1712.3268 1756.8051 1766.7490 1771.0748 1786.5547 1797.6381 1809.2801 1819.1159 1820.8610 1859.9096 1872.8894 1950.8162 3337.6982 3352.3733 3368.0272 3389.1333 3403.2509 3404.8385 3410.4161 3417.4452 3422.5067 3429.0648 3460.2747 3476.0112 3509.9233 3573.9007 11.2271 9.2535 6.8304 4.9057 6.1526 5.8008 6.2293 8.9942 8.9833 8.1078 8.0936 8.2031 7.7249 5.8030 8.2195 7.7980 9.8505 7.7383 7.0617 8.7798 7.4021 9.5794 6.5720 8.7071 8.0256 6.7764 16.9979 7.9427 8.2692 6.9695 7.1391 7.2793 2.9990 7.3846 3.8804 6.4721 4.7693 8.7143 6.2767 9.4343 6.5081 4.4348 3.0497 6.3780 7.4587 6.9740 6.4219 6.3211 5.4500 4.7574 2.1107 3.5235 7.9001 3.2448 2.8121 1.3095 2.2530 5.2890 3.3545 2.4503 3.0030 1.9858 1.6087 6.9900 1.4353 2.4545 1.2802 1.7076 9.3430 6.3641 5.8538 1.3776 4.6500 5.7735 1.5461 1.4857 5.0742 6.0350 1.3690 1.4941 1.3500 6.6157 1.4255 2.2729 2.5938 2.7418 1.9719 1.8030 3.1805 3.4654 2.4154 3.3739 3.6424 2.0314 2.7422 1.7903 1.6539 3.0521 2.0349 2.0805 2.0592 2.2665 5.1566 1.9312 1.8460 3.4129 1.6398 6.7319 3.1512 2.7439 4.9172 2.9893 3.0652 3.5191 5.2833 2.8568 4.9588 5.7997 5.6540 4.4330 5.0925 6.5647 4.8035 6.1082 5.0691 5.8915 6.3032 12.7981 7.3935 10.6417 1.0859 1.0914 1.0964 1.0944 1.0917 1.0948 1.0920 1.0936 1.0961 1.0926 1.0990 1.1055 1.0992 1.0837 0.0007 0.0018 0.0033 0.0030 0.0044 0.0049 0.0088 0.0179 0.0323 0.0384 0.0409 0.0468 0.0582 0.0605 0.1016 0.1422 0.1933 0.1704 0.1884 0.3091 0.2782 0.3877 0.2804 0.3887 0.3785 0.3744 1.1223 0.5835 0.7050 0.6658 0.7579 0.8853 0.3712 0.9613 0.5277 0.9778 0.8024 1.6192 1.2970 2.0895 1.5825 1.0958 0.7797 1.7343 2.2029 2.0858 1.9655 1.9896 1.7843 1.5906 0.7482 1.2624 2.9771 1.2413 1.0849 0.5520 0.9692 2.2989 1.4986 1.1132 1.3841 0.9444 0.7921 3.4968 0.7488 1.2906 0.6934 0.9253 5.1555 3.5490 3.3597 0.8025 2.8668 3.5958 0.9997 0.9691 3.4288 4.2232 0.9631 1.0663 0.9668 4.8494 1.0580 1.7179 2.0865 2.2588 1.6322 1.5180 2.7260 2.9935 2.1022 3.0894 3.4393 1.9686 2.6880 1.7769 1.6467 3.0838 2.1202 2.1797 2.2577 2.5121 5.9409 2.2806 2.2463 4.2518 2.0924 9.1686 4.4185 3.8680 7.0613 4.5034 4.7130 5.5945 8.5312 4.7000 8.2479 9.7820 9.7675 8.0611 9.3655 12.1323 9.0332 11.6297 9.7767 11.4868 12.3130 26.0843 15.2800 23.8612 7.1275 7.2265 7.3279 7.4063 7.4499 7.4778 7.4834 7.5252 7.5645 7.5692 7.7531 7.8700 7.9783 8.1557 0.1479 3.3430 1.0501 1.5266 2.1487 0.0734 0.2032 0.6102 1.7529 1.3030 0.9596 1.5336 7.0248 0.9708 6.6335 2.1053 2.6784 5.8783 4.4449 0.6273 0.7032 1.1855 0.5966 0.3685 5.5950 1.9912 0.5488 7.2779 21.9382 1.8065 2.6611 4.0986 0.0240 5.4086 3.9662 2.8709 3.5010 19.3869 1.3468 2.8434 17.9948 12.1565 9.8942 0.2202 12.1621 24.2053 5.0837 1.6507 1.2239 0.5330 25.4061 11.4729 31.0274 6.0512 5.0731 48.0093 26.2827 16.1061 62.6699 22.2789 8.7380 31.9007 96.9960 43.8319 5.2495 76.5047 0.1026 27.8472 57.3609 10.6704 56.4287 0.7977 66.6255 5.0092 42.8936 5.0017 9.4725 0.1488 1.9457 28.0474 1.2053 28.9773 2.8724 3.0380 23.2707 3.2765 3.1598 7.5866 25.2178 33.3904 0.6429 12.4503 45.8499 15.7099 13.4967 20.4751 7.3837 7.5430 41.8572 47.7455 34.2173 2.8792 50.5559 15.3605 11.4618 187.7674 89.7450 581.9074 14.6275 10.3328 86.3897 284.1927 65.5174 61.8811 1246.0878 25.0456 8.9670 210.8036 102.5154 456.3731 364.7907 80.9248 7.6889 325.8970 28.0476 36.6950 72.3685 481.1426 1476.3452 249.1995 0.0622 40.5079 81.0247 6.9987 4.7672 11.6208 20.7336 2.5473 2.0012 16.5172 1.3415 8.7677 4.4986 665.9111 1.0406 4.2045 1.3463 3.4780 1.3263 5.5420 1.4249 0.5114 1.0038 2.5724 2.8210 0.3855 1.0382 4.3302 2.9566 2.5636 2.0774 1.0779 1.2375 2.6314 3.6496 2.5281 3.7388 2.1109 1.1881 3.7618 4.8186 2.6754 2.6228 0.1507 1.1030 2.5132 0.7578 2.4335 0.4431 0.0324 0.4165 0.2822 0.2383 2.9449 0.8451 2.2666 2.2608 5.3465 5.1988 1.6406 1.3442 7.6251 0.6329 1.3600 3.5280 4.0125 3.3313 3.3068 0.4347 2.2816 7.1538 3.4574 1.9996 1.2210 4.2081 5.4140 3.4212 1.5483 3.6151 3.9319 2.7226 2.0144 16.7909 7.8571 4.8756 8.6071 3.2277 4.3537 3.9919 2.0779 30.0071 52.7310 0.9865 21.8442 0.8852 24.1464 3.0632 10.5774 4.6460 5.6315 1.7633 19.5939 3.6820 6.6907 10.5306 18.9930 7.5580 4.5994 10.5387 1.5092 2.6639 12.5777 11.6555 27.1420 28.9767 38.0334 14.9032 35.6459 20.3499 43.6463 13.1340 41.7549 2.0614 51.1919 24.6257 30.5553 19.5651 32.0762 58.5390 18.8524 42.3489 95.3604 675.0089 77.4975 30.0552 15.2654 27.9984 62.9970 174.5060 272.9610 487.7346 8.9095 32.8959 64.0194 61.2360 130.1528 218.7069 51.9380 78.3962 75.5481 100.3115 83.0040 167.7185 132.6457 29.1564 164.0428 36.7512 165.9764 0.7493 0.7486 0.7473 0.7498 0.7410 0.7496 0.7306 0.6311 0.7442 0.7428 0.6708 0.6953 0.7304 0.7347 0.3928 0.7152 0.6599 0.7173 0.7493 0.3579 0.7499 0.7322 0.6113 0.7176 0.4501 0.6893 0.2914 0.1285 0.5030 0.7325 0.1014 0.6851 0.7242 0.7485 0.5482 0.7360 0.3755 0.4466 0.1886 0.3228 0.6930 0.3980 0.7499 0.7454 0.0899 0.3811 0.4983 0.3671 0.7444 0.7495 0.4074 0.5389 0.6691 0.6886 0.4866 0.7498 0.2031 0.4925 0.2214 0.7443 0.3564 0.5191 0.6896 0.4025 0.7497 0.6353 0.5188 0.7329 0.1074 0.6487 0.2733 0.7498 0.7357 0.1899 0.6028 0.7139 0.1964 0.1537 0.6297 0.4407 0.2810 0.1212 0.3051 0.1481 0.4288 0.1811 0.2703 0.3472 0.6062 0.7494 0.7457 0.2607 0.3378 0.6660 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0.7995 0.4997 0.5787 0.7362 0.3895 0.8448 0.5449 0.2859 0.2756 0.6009 0.3069 0.6659 0.6230 0.7555 0.5791 0.7808 0.7351 0.4412 0.8524 0.4134 0.8395 0.7787 0.2077 0.2638 0.5779 0.3096 0.8561 0.6408 0.5294 0.7940 0.8158 0.6810 0.7365 0.3426 0.7630 0.5183 0.4083 0.8397 0.8471 0.2727 0.3352 0.5694 0.5588 0.3678 0.3265 0.3452 0.6899 0.4806 0.3006 0.4682 0.3371 298.150 1.00000 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 6 6 6 6 6 6 6 6 6 7 6 7 7 6 6 6 7 6 6 6 6 8 7 6 8 6 6 6 6 6 6 7 8 8 17 8 1 1 1 1 1 1 1 1 1 1 1 1 1 1 12.00000 12.00000 12.00000 12.00000 12.00000 12.00000 12.00000 12.00000 12.00000 14.00307 12.00000 14.00307 14.00307 12.00000 12.00000 12.00000 14.00307 12.00000 12.00000 12.00000 12.00000 15.99491 14.00307 12.00000 15.99491 12.00000 12.00000 12.00000 12.00000 12.00000 12.00000 14.00307 15.99491 15.99491 34.96885 15.99491 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 1.00783 15785.9220 27297.4640 41769.6905 0.99997 -0.00785 -0.00010 0.00785 0.99995 -0.00562 0.00015 0.00562 0.99998 1 0.00549 0.00317 0.00207 0.11433 0.06611 0.04321 14.55 25.93 41.42 46.65 50.00 54.41 70.44 83.69 112.32 129.03 133.32 141.55 162.68 191.46 208.38 253.16 262.56 278.19 306.13 351.71 363.39 377.09 387.18 396.06 407.04 440.60 481.65 508.04 547.30 579.34 610.73 653.67 659.48 676.28 691.20 728.57 768.85 807.98 852.07 882.13 924.29 931.73 947.76 977.44 1018.67 1025.10 1036.98 1051.61 1072.50 1083.84 1116.01 1121.96 1150.67 1159.37 1164.27 1216.91 1229.40 1235.78 1252.83 1263.39 1272.57 1292.62 1315.33 1325.76 1353.85 1359.19 1379.46 1379.81 1392.39 1399.75 1420.04 1430.62 1471.78 1479.27 1507.25 1513.86 1540.84 1568.00 1572.14 1583.52 1586.23 1604.82 1614.84 1629.58 1681.16 1701.33 1705.31 1719.95 1735.31 1742.13 1748.69 1793.67 1821.43 1845.25 1855.81 1867.39 1870.37 1884.13 1913.29 1918.58 1962.74 1973.36 2011.92 2036.95 2067.70 2092.14 2117.40 2187.52 2219.56 2225.52 2246.23 2300.67 2324.29 2363.38 2381.88 2404.25 2417.43 2434.33 2463.66 2527.65 2541.96 2548.18 2570.45 2586.40 2603.15 2617.30 2619.81 2676.00 2694.67 2806.79 4802.20 4823.32 4845.84 4876.21 4896.52 4898.80 4906.83 4916.94 4924.22 4933.66 4978.56 5001.20 5050.00 5142.05 0.380862 0.407852 0.408796 0.317637 -2077.024579 -2076.997590 -2076.996646 -2077.087805 3.057488D-04 MUNgauss RevisionA2.1 retrievium 06-Jun-2021 DUDE c1ccc(cc1)c2cc(nc(n2)n3c(cc(n3)c4ccco4)NC(=O)c5cc(ccc5[N+](=O)[O-])Cl)[O-] C12009195 RHF 6-31G(d) (6D,10F) C1 501.071420 |X|Y|Z| 89.891508 118.784196 22.357851 62.034859 30 6 7 8 24 5 1 |36.858105| |13.747285|36.858105| |7.924279|13.759245|36.858105| |6.808940|7.890575|13.675037|36.858105| |7.932360|6.897788|7.964786|13.681088|36.858105| |13.753091|7.964272|6.887836|7.883562|13.755959|36.858105| |4.437771|5.044037|7.628126|12.741286|7.540861|5.016247|36.858105| |3.693688|3.897855|5.126579|7.622086|6.358164|4.361995|14.056056|36.858105| |2.904102|3.088565|3.891543|4.987316|4.299246|3.279948|7.873452|13.146675|36.858105| |2.727296|3.001634|3.824544|4.545664|3.726597|2.953061|7.059442|7.992904|13.897706|53.358707| |3.037990|3.492524|4.675391|5.325992|4.026345|3.195228|8.537438|7.251634|8.258854|19.806737|36.858105| |3.807234|4.576060|6.831916|7.927875|5.191317|3.969598|14.035127|7.997365|6.799613|10.995867|14.670392|53.358707| |2.635110|3.053092|3.884215|4.037651|3.191921|2.680604|5.381687|4.698828|5.325787|11.274704|13.343997|11.194796|53.358707| |2.218627|2.505026|3.040179|3.163050|2.635924|2.263942|4.011905|3.796751|4.538354|9.169684|7.554285|7.150284|18.964082|36.858105| |2.064401|2.344818|2.775196|2.776457|2.339918|2.064232|3.318517|3.071376|3.460191|6.265197|5.290800|5.786872|11.766980|14.007232|36.858105| |2.297286|2.680983|3.204883|3.081278|2.534142|2.250260|3.593410|3.148482|3.354519|5.902589|5.500385|6.560336|12.312008|8.745663|13.449447|36.858105| |2.701459|3.225747|4.056620|3.897409|3.060672|2.652867|4.713719|3.899385|4.048300|7.323780|7.914853|9.654319|19.288988|8.548480|8.448649|14.712764|53.358707| |2.169044|2.536990|2.920331|2.713320|2.276387|2.080279|2.991576|2.619762|2.704260|4.470135|3.991811|5.167068|7.400875|5.280638|7.389224|13.045203|10.848660|36.858105| |2.281526|2.708392|3.048398|2.727730|2.293930|2.138179|2.882032|2.478737|2.474570|3.947505|3.529889|4.870369|5.983920|4.019143|4.932429|7.409050|8.559884|14.164883|36.858105| |1.980893|2.298204|2.506759|2.269237|1.962876|1.857891|2.367372|2.090370|2.098593|3.280571|2.811212|3.836920|4.606971|3.268181|4.014085|5.188429|5.921860|8.575389|13.253000|36.858105| |1.804373|2.061601|2.264728|2.103270|1.832309|1.719705|2.239789|2.018265|2.071526|3.271005|2.745784|3.619095|4.601136|3.454633|4.472457|5.387078|5.685313|8.775123|8.597651|14.219930|36.858105| |1.880735|2.152840|2.421562|2.284310|1.966437|1.814236|2.501950|2.259063|2.363523|3.840548|3.251625|4.142903|5.774145|4.512494|6.494690|7.950792|7.245742|14.130695|8.628984|8.635730|14.183159|73.516695| |2.060544|2.268173|2.712611|2.917149|2.508398|2.144559|3.728943|3.805478|4.928930|9.880880|6.402025|6.092462|10.833400|13.752163|7.614425|5.363190|7.337161|3.843760|3.112798|2.656079|2.817760|6.232184|53.358707| |1.802717|1.961314|2.285398|2.429399|2.143867|1.869549|2.975325|3.076341|3.857940|6.780722|4.431626|4.644722|7.111675|7.856161|6.197393|4.349166|5.577470|3.372273|2.753710|2.442372|2.653447|5.801210|19.295103|36.858105| |1.678636|1.831746|2.106575|2.191813|1.941029|1.719684|2.608131|2.636607|3.156127|5.348428|3.721058|4.081820|6.167540|6.669899|6.435919|4.364679|5.242783|3.512657|2.821451|2.560212|2.864985|6.342765|11.438931|15.889437|73.516695| |1.701749|1.818242|2.094766|2.266398|2.049825|1.788486|2.754742|2.972326|3.805037|6.148196|3.767507|4.084269|5.443129|5.101616|4.175184|3.274849|4.377818|2.670706|2.273956|2.048073|2.191151|4.606002|10.794139|12.575229|14.396784|36.858105| |1.781605|1.889219|2.184818|2.409642|2.194744|1.895377|2.967438|3.341414|4.468384|6.822946|3.908878|4.252630|5.237477|4.511177|3.605821|2.991477|4.168705|2.454319|2.135992|1.911645|2.006570|4.150609|8.945250|7.533041|9.638796|13.719240|36.858105| |1.641044|1.715163|1.949783|2.152028|2.008304|1.754353|2.576273|2.931945|3.753680|5.285287|3.132106|3.577938|4.120259|3.397221|2.860772|2.456323|3.420273|2.082509|1.848735|1.678664|1.754718|3.557155|6.069179|5.018078|7.267038|7.926009|13.729860|36.858105| |1.477908|1.539140|1.727280|1.882712|1.771895|1.570301|2.202942|2.449917|3.004325|4.256571|2.637278|3.075001|3.558456|2.960132|2.591995|2.223891|3.036303|1.922616|1.711347|1.576496|1.660509|3.341872|5.118026|4.424053|6.833812|6.805095|7.895051|13.809940|36.858105| |1.431320|1.499806|1.681484|1.812035|1.693269|1.508060|2.111800|2.293581|2.777528|4.078083|2.592368|3.009216|3.619566|3.108084|2.778705|2.331458|3.112594|2.019846|1.778597|1.649157|1.759117|3.562930|5.402051|5.011807|8.030278|7.860374|6.864638|7.998178|13.768925|36.858105| |1.522139|1.612300|1.825739|1.958886|1.801627|1.595548|2.313302|2.477019|3.037500|4.679194|2.986229|3.380207|4.309870|3.894147|3.444598|2.772815|3.644481|2.352145|2.028726|1.867186|2.011608|4.156612|7.155190|7.541564|11.688022|13.694063|8.002487|6.975731|7.992544|13.840829|36.858105| |1.438400|1.527222|1.716061|1.815604|1.670213|1.494628|2.109190|2.204116|2.616743|4.058106|2.708367|3.118807|4.032834|3.678086|3.456452|2.760725|3.522568|2.389697|2.049865|1.915080|2.095982|4.331135|6.281379|6.455421|11.911492|7.640306|5.095099|4.549320|5.167590|7.923190|13.032776|53.358707| |1.326355|1.404695|1.563221|1.640748|1.518425|1.371906|1.877387|1.952771|2.273712|3.461812|2.345867|2.756599|3.478130|3.093725|3.001976|2.456009|3.115379|2.182453|1.892209|1.795938|1.974304|4.018185|5.014601|4.877940|9.553815|5.529111|4.138913|3.920772|4.619956|6.886024|8.390251|21.686115|73.516695| |1.487741|1.583516|1.783503|1.884780|1.727972|1.544314|2.191850|2.264782|2.672719|4.207058|2.852279|3.277431|4.317240|3.976929|3.771682|2.985285|3.779518|2.570786|2.189309|2.037999|2.236292|4.656679|6.667927|6.461566|11.798065|6.593028|4.548048|3.939767|4.224921|5.722830|8.393812|21.816527|15.988664|73.516695| 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